{"id":"https://openalex.org/W1983284728","doi":"https://doi.org/10.1021/ja00358a015","title":"Reactions of dihydrido(bicarbonato)bis(triisopropylphosphine)rhodium(III) with alkynes. Formation of tris(triisopropylphosphine)(diphenylacetylene)carbonatodihydrodirhodium [Rh2H2(OCO2)(PhC.tplbond.CPh)[P(CHMe2)3]3] and the stereoselective hydrogenation of alkynes to trans olefins","display_name":"Reactions of dihydrido(bicarbonato)bis(triisopropylphosphine)rhodium(III) with alkynes. Formation of tris(triisopropylphosphine)(diphenylacetylene)carbonatodihydrodirhodium [Rh2H2(OCO2)(PhC.tplbond.CPh)[P(CHMe2)3]3] and the stereoselective hydrogenation of alkynes to trans olefins","publication_year":1983,"publication_date":"1983-09-01","ids":{"openalex":"https://openalex.org/W1983284728","doi":"https://doi.org/10.1021/ja00358a015","mag":"1983284728"},"language":"en","primary_location":{"id":"doi:10.1021/ja00358a015","doi":"https://doi.org/10.1021/ja00358a015","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja00358a015","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5048877350","display_name":"Tomohiro Yoshida","orcid":"https://orcid.org/0000-0001-5876-6090","observed_orcids":["https://orcid.org/0000-0001-5876-6090"]},"institutions":[{"id":"https://openalex.org/I15807432","display_name":"Osaka Prefecture University","ror":"https://ror.org/02cf1je33","country_code":"JP","type":"education","lineage":["https://openalex.org/I15807432","https://openalex.org/I4387152983"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"T. Yoshida","raw_affiliation_strings":["Osaka  prefecture University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Osaka  prefecture University","institution_ids":["https://openalex.org/I15807432"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5044539076","display_name":"Wiley J. Youngs","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I111979921","display_name":"Northwestern University","ror":"https://ror.org/000e0be47","country_code":"US","type":"education","lineage":["https://openalex.org/I111979921"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Wiley J. Youngs","raw_affiliation_strings":["Northwestern University****"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Northwestern University****","institution_ids":["https://openalex.org/I111979921"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5056164964","display_name":"T. Sakaeda","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I98285908","display_name":"The University of Osaka","ror":"https://ror.org/035t8zc32","country_code":"JP","type":"education","lineage":["https://openalex.org/I98285908"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"T. Sakaeda","raw_affiliation_strings":["Osaka University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Osaka University","institution_ids":["https://openalex.org/I98285908"]}]},{"author_position":"middle","author":{"id":null,"display_name":"T. Ueda","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I15807432","display_name":"Osaka Prefecture University","ror":"https://ror.org/02cf1je33","country_code":"JP","type":"education","lineage":["https://openalex.org/I15807432","https://openalex.org/I4387152983"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"T. Ueda","raw_affiliation_strings":["Osaka  prefecture University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Osaka  prefecture University","institution_ids":["https://openalex.org/I15807432"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5113147789","display_name":"S. OTSUKA","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I98285908","display_name":"The University of Osaka","ror":"https://ror.org/035t8zc32","country_code":"JP","type":"education","lineage":["https://openalex.org/I98285908"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"S. Otsuka","raw_affiliation_strings":["Osaka University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Osaka University","institution_ids":["https://openalex.org/I98285908"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5015454414","display_name":"James A. Ibers","orcid":"https://orcid.org/0000-0002-5418-3645","observed_orcids":["https://orcid.org/0000-0002-5418-3645"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"James A. Ibers","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":3,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":4.0042,"has_fulltext":false,"cited_by_count":31,"citation_normalized_percentile":{"value":0.93404276,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":89,"max":97},"biblio":{"volume":"105","issue":"20","first_page":"6273","last_page":"6278"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.9092000126838684,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.9092000126838684,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10871","display_name":"Catalytic Alkyne Reactions","score":0.02710000053048134,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11281","display_name":"Asymmetric Hydrogenation and Catalysis","score":0.026200000196695328,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/rhodium-iii-complexes","display_name":"rhodium(III) complexes","score":0.7590000033378601},{"id":"https://openalex.org/keywords/triisopropylphosphine-ligands","display_name":"triisopropylphosphine ligands","score":0.8550000190734863},{"id":"https://openalex.org/keywords/alkynes","display_name":"alkynes","score":0.5640000104904175},{"id":"https://openalex.org/keywords/alkyne-hydrogenation","display_name":"alkyne hydrogenation","score":0.781000018119812},{"id":"https://openalex.org/keywords/stereoselective-hydrogenation","display_name":"stereoselective hydrogenation","score":0.9049999713897705},{"id":"https://openalex.org/keywords/trans-olefins","display_name":"trans-olefins","score":0.9449999928474426},{"id":"https://openalex.org/keywords/diphenylacetylene","display_name":"diphenylacetylene","score":0.8550000190734863},{"id":"https://openalex.org/keywords/carbonate-complexes","display_name":"carbonate complexes","score":0.367000013589859},{"id":"https://openalex.org/keywords/rhodium-hydride-complexes","display_name":"rhodium hydride complexes","score":0.421999990940094},{"id":"https://openalex.org/keywords/phosphine-ligands","display_name":"phosphine ligands","score":0.4690000116825104},{"id":"https://openalex.org/keywords/alkene-synthesis","display_name":"olefin synthesis","score":0.4449999928474426},{"id":"https://openalex.org/keywords/organometallic-catalysis","display_name":"organometallic catalysis","score":0.5049999952316284}],"concepts":[{"id":"https://openalex.org/C2781019423","wikidata":"https://www.wikidata.org/wiki/Q902100","display_name":"Diphenylacetylene","level":3,"score":0.9634363651275635},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9633607864379883},{"id":"https://openalex.org/C521398313","wikidata":"https://www.wikidata.org/wiki/Q1087","display_name":"Rhodium","level":3,"score":0.8579902648925781},{"id":"https://openalex.org/C2781014771","wikidata":"https://www.wikidata.org/wiki/Q413961","display_name":"Tris","level":2,"score":0.618127167224884},{"id":"https://openalex.org/C2779012754","wikidata":"https://www.wikidata.org/wiki/Q159226","display_name":"Alkyne","level":3,"score":0.527105450630188},{"id":"https://openalex.org/C181647583","wikidata":"https://www.wikidata.org/wiki/Q903429","display_name":"Stereoselectivity","level":3,"score":0.5055670738220215},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.4990653991699219},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.3775637745857239},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.34197425842285156},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.3344523310661316},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.20902076363563538},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/ja00358a015","doi":"https://doi.org/10.1021/ja00358a015","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja00358a015","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"sustainable_development_goals_aurora":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2345808671","https://openalex.org/W2014599276","https://openalex.org/W1971705083","https://openalex.org/W2040104292","https://openalex.org/W2064328577","https://openalex.org/W2011618342","https://openalex.org/W1970452793","https://openalex.org/W244595200","https://openalex.org/W2953011684","https://openalex.org/W2028746038"],"abstract_inverted_index":{"ADVERTISEMENT":[0],"RETURN":[1],"TO":[2],"ISSUEPREVArticleNEXTReactions":[3],"of":[4,9,16,69,104,130],"dihydrido(bicarbonato)bis(triisopropylphosphine)rhodium(III)":[5],"with":[6,151,186],"alkynes.":[7],"Formation":[8],"tris(triisopropylphosphine)(diphenylacetylene)carbonatodihydrodirhodium":[10],"[Rh2H2(OCO2)(PhC.tplbond.CPh)[P(CHMe2)3]3]":[11],"and":[12,31,79,84,113,157,174,190,192],"the":[13,66,97,102,131,142,155,158,163,170,176],"stereoselective":[14],"hydrogenation":[15],"alkynes":[17],"to":[18,91,96],"trans":[19],"olefinsT.":[20],"Yoshida,":[21],"Wiley":[22],"J.":[23,36],"Youngs,":[24],"T.":[25,27],"Sakaeda,":[26],"Ueda,":[28],"S.":[29],"Otsuka,":[30],"James":[32],"A.":[33],"IbersCite":[34],"this:":[35],"Am.":[37],"Chem.":[38],"Soc.":[39],"1983,":[40],"105,":[41],"20,":[42],"6273\u20136278Publication":[43],"Date":[44],"(Print):September":[45],"1,":[46],"1983Publication":[47],"History":[48],"Published":[49],"online1":[50],"May":[51],"2002Published":[52],"inissue":[53],"1":[54],"September":[55],"1983https://pubs.acs.org/doi/10.1021/ja00358a015https://doi.org/10.1021/ja00358a015research-articleACS":[56],"PublicationsRequest":[57],"reuse":[58],"permissionsArticle":[59],"Views199Altmetric-Citations27LEARN":[60],"ABOUT":[61],"THESE":[62],"METRICSArticle":[63],"Views":[64],"are":[65,88,101],"COUNTER-compliant":[67],"sum":[68],"full":[70],"text":[71],"article":[72,136],"downloads":[73],"since":[74],"November":[75],"2008":[76],"(both":[77],"PDF":[78],"HTML)":[80],"across":[81],"all":[82],"institutions":[83],"individuals.":[85],"These":[86],"metrics":[87],"regularly":[89],"updated":[90,114],"reflect":[92],"usage":[93],"leading":[94],"up":[95],"last":[98],"few":[99],"days.Citations":[100],"number":[103],"other":[105],"articles":[106],"citing":[107],"this":[108],"article,":[109],"calculated":[110],"by":[111],"Crossref":[112,120],"daily.":[115],"Find":[116,166],"more":[117,167],"information":[118,168],"about":[119,154],"citation":[121],"counts.The":[122],"Altmetric":[123,171],"Attention":[124,172],"Score":[125,173],"is":[126,178],"a":[127,134,147],"quantitative":[128],"measure":[129],"attention":[132],"that":[133],"research":[135],"has":[137],"received":[138],"online.":[139],"Clicking":[140],"on":[141,169],"donut":[143],"icon":[144],"will":[145],"load":[146],"page":[148],"at":[149],"altmetric.com":[150],"additional":[152],"details":[153],"score":[156,177],"social":[159],"media":[160],"presence":[161],"for":[162],"given":[164],"article.":[165],"how":[175],"calculated.":[179],"Share":[180,195],"Add":[181],"toView":[182],"InAdd":[183],"Full":[184],"Text":[185],"ReferenceAdd":[187],"Description":[188],"ExportRISCitationCitation":[189],"abstractCitation":[191],"referencesMore":[193],"Options":[194],"onFacebookTwitterWechatLinked":[196],"InRedditEmail":[197],"Other":[198],"access":[199],"optionsGet":[200],"e-AlertscloseSupporting":[201],"Info":[202],"(1)\u00bbSupporting":[203],"Information":[204,206],"Supporting":[205],"Get":[207],"e-Alerts":[208]},"counts_by_year":[{"year":2025,"cited_by_count":1},{"year":2023,"cited_by_count":1},{"year":2018,"cited_by_count":3},{"year":2017,"cited_by_count":1},{"year":2014,"cited_by_count":1}],"updated_date":"2026-09-29T14:09:16.559479","created_date":"2016-06-24T00:00:00"}