{"id":"https://openalex.org/W1982948872","doi":"https://doi.org/10.1021/om010413o","title":"Direct Acetoacetylation of Ferrocene and a 1,1\u2018-Diphosphaferrocene","display_name":"Direct Acetoacetylation of Ferrocene and a 1,1\u2018-Diphosphaferrocene","publication_year":2001,"publication_date":"2001-09-29","ids":{"openalex":"https://openalex.org/W1982948872","doi":"https://doi.org/10.1021/om010413o","mag":"1982948872"},"language":"en","primary_location":{"id":"doi:10.1021/om010413o","doi":"https://doi.org/10.1021/om010413o","is_oa":false,"landing_page_url":"https://doi.org/10.1021/om010413o","pdf_url":null,"source":{"id":"https://openalex.org/S4924609","display_name":"Organometallics","issn_l":"0276-7333","issn":["0276-7333","1520-6041"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-1","norway-2"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organometallics","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5055921737","display_name":"Damian Pla\u017cuk","orcid":"https://orcid.org/0000-0002-2898-6604","observed_orcids":["https://orcid.org/0000-0002-2898-6604"]},"institutions":[{"id":"https://openalex.org/I34250744","display_name":"University of \u0141\u00f3d\u017a","ror":"https://ror.org/05cq64r17","country_code":"PL","type":"education","lineage":["https://openalex.org/I34250744"]}],"countries":["PL"],"is_corresponding":false,"raw_author_name":"Damian Pla\u017cuk","raw_affiliation_strings":["Department of Organic Chemistry, University of \u0141\u00f3d\u017a, Narutowicza 68, 90-136 \u0141\u00f3d\u017a, Poland, and Department of Crystallography, University of \u0141\u00f3d\u017a, Pomorska 149/153, 90-236 \u0141\u00f3d\u017a, Poland"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Organic Chemistry, University of \u0141\u00f3d\u017a, Narutowicza 68, 90-136 \u0141\u00f3d\u017a, Poland, and Department of Crystallography, University of \u0141\u00f3d\u017a, Pomorska 149/153, 90-236 \u0141\u00f3d\u017a, Poland","institution_ids":["https://openalex.org/I34250744"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5089268895","display_name":"Arkadiusz K\u0142ys","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I34250744","display_name":"University of \u0141\u00f3d\u017a","ror":"https://ror.org/05cq64r17","country_code":"PL","type":"education","lineage":["https://openalex.org/I34250744"]}],"countries":["PL"],"is_corresponding":false,"raw_author_name":"Arkadiusz K\u0142ys","raw_affiliation_strings":["Department of Organic Chemistry, University of \u0141\u00f3d\u017a, Narutowicza 68, 90-136 \u0141\u00f3d\u017a, Poland, and Department of Crystallography, University of \u0141\u00f3d\u017a, Pomorska 149/153, 90-236 \u0141\u00f3d\u017a, Poland"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Organic Chemistry, University of \u0141\u00f3d\u017a, Narutowicza 68, 90-136 \u0141\u00f3d\u017a, Poland, and Department of Crystallography, University of \u0141\u00f3d\u017a, Pomorska 149/153, 90-236 \u0141\u00f3d\u017a, Poland","institution_ids":["https://openalex.org/I34250744"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5061827604","display_name":"Janusz Zakrzewski","orcid":"https://orcid.org/0000-0002-3403-1126","observed_orcids":["https://orcid.org/0000-0002-3403-1126"]},"institutions":[{"id":"https://openalex.org/I34250744","display_name":"University of \u0141\u00f3d\u017a","ror":"https://ror.org/05cq64r17","country_code":"PL","type":"education","lineage":["https://openalex.org/I34250744"]}],"countries":["PL"],"is_corresponding":false,"raw_author_name":"Janusz Zakrzewski","raw_affiliation_strings":["Department of Organic Chemistry, University of \u0141\u00f3d\u017a, Narutowicza 68, 90-136 \u0141\u00f3d\u017a, Poland, and Department of Crystallography, University of \u0141\u00f3d\u017a, Pomorska 149/153, 90-236 \u0141\u00f3d\u017a, Poland"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Organic Chemistry, University of \u0141\u00f3d\u017a, Narutowicza 68, 90-136 \u0141\u00f3d\u017a, Poland, and Department of Crystallography, University of \u0141\u00f3d\u017a, Pomorska 149/153, 90-236 \u0141\u00f3d\u017a, Poland","institution_ids":["https://openalex.org/I34250744"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5070590167","display_name":"Agnieszka J. Rybarczyk\u2010Pirek","orcid":"https://orcid.org/0000-0001-7377-7011","observed_orcids":["https://orcid.org/0000-0001-7377-7011"]},"institutions":[{"id":"https://openalex.org/I34250744","display_name":"University of \u0141\u00f3d\u017a","ror":"https://ror.org/05cq64r17","country_code":"PL","type":"education","lineage":["https://openalex.org/I34250744"]}],"countries":["PL"],"is_corresponding":false,"raw_author_name":"Agnieszka Rybarczyk-Pirek","raw_affiliation_strings":["Department of Organic Chemistry, University of \u0141\u00f3d\u017a, Narutowicza 68, 90-136 \u0141\u00f3d\u017a, Poland, and Department of Crystallography, University of \u0141\u00f3d\u017a, Pomorska 149/153, 90-236 \u0141\u00f3d\u017a, Poland"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Organic Chemistry, University of \u0141\u00f3d\u017a, Narutowicza 68, 90-136 \u0141\u00f3d\u017a, Poland, and Department of Crystallography, University of \u0141\u00f3d\u017a, Pomorska 149/153, 90-236 \u0141\u00f3d\u017a, Poland","institution_ids":["https://openalex.org/I34250744"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5027924880","display_name":"T. A. Olszak","orcid":"https://orcid.org/0000-0001-6474-5448","observed_orcids":["https://orcid.org/0000-0001-6474-5448"]},"institutions":[{"id":"https://openalex.org/I34250744","display_name":"University of \u0141\u00f3d\u017a","ror":"https://ror.org/05cq64r17","country_code":"PL","type":"education","lineage":["https://openalex.org/I34250744"]}],"countries":["PL"],"is_corresponding":false,"raw_author_name":"Tomasz A. Olszak","raw_affiliation_strings":["Department of Organic Chemistry, University of \u0141\u00f3d\u017a, Narutowicza 68, 90-136 \u0141\u00f3d\u017a, Poland, and Department of Crystallography, University of \u0141\u00f3d\u017a, Pomorska 149/153, 90-236 \u0141\u00f3d\u017a, Poland"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Organic Chemistry, University of \u0141\u00f3d\u017a, Narutowicza 68, 90-136 \u0141\u00f3d\u017a, Poland, and Department of Crystallography, University of \u0141\u00f3d\u017a, Pomorska 149/153, 90-236 \u0141\u00f3d\u017a, Poland","institution_ids":["https://openalex.org/I34250744"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I34250744"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":1.3581,"has_fulltext":false,"cited_by_count":16,"citation_normalized_percentile":{"value":0.75386827,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":94},"biblio":{"volume":"20","issue":"22","first_page":"4448","last_page":"4450"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T13833","display_name":"Ferrocene Chemistry and Applications","score":0.9541000127792358,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T13833","display_name":"Ferrocene Chemistry and Applications","score":0.9541000127792358,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.01769999973475933,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.014299999922513962,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/acetoacetylation","display_name":"acetoacetylation","score":0.878000020980835},{"id":"https://openalex.org/keywords/ferrocene","display_name":"ferrocene","score":0.9900000095367432},{"id":"https://openalex.org/keywords/diketene","display_name":"diketene","score":0.8169999718666077},{"id":"https://openalex.org/keywords/boron-trifluoride-etherate","display_name":"boron trifluoride etherate","score":0.9039999842643738},{"id":"https://openalex.org/keywords/beta-diketones","display_name":"\u03b2-diketones","score":0.8709999918937683},{"id":"https://openalex.org/keywords/aluminum-chloride","display_name":"aluminum chloride","score":0.5910000205039978},{"id":"https://openalex.org/keywords/crystal-structure","display_name":"crystal structure","score":0.7829999923706055}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9544364213943481},{"id":"https://openalex.org/C2777237805","wikidata":"https://www.wikidata.org/wiki/Q211972","display_name":"Ferrocene","level":4,"score":0.9066624045372009},{"id":"https://openalex.org/C2780446808","wikidata":"https://www.wikidata.org/wiki/Q413676","display_name":"Metallocene","level":4,"score":0.8707312345504761},{"id":"https://openalex.org/C2778659974","wikidata":"https://www.wikidata.org/wiki/Q418541","display_name":"Diketene","level":2,"score":0.8676121234893799},{"id":"https://openalex.org/C197404232","wikidata":"https://www.wikidata.org/wiki/Q319827","display_name":"Chelation","level":2,"score":0.4613156318664551},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.4267193377017975},{"id":"https://openalex.org/C50515024","wikidata":"https://www.wikidata.org/wiki/Q826582","display_name":"X-ray crystallography","level":3,"score":0.42671093344688416},{"id":"https://openalex.org/C181458950","wikidata":"https://www.wikidata.org/wiki/Q2855060","display_name":"Cyclopentadienyl complex","level":3,"score":0.4162246584892273},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.40729886293411255},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.3929165303707123},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.37835457921028137},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.3458084762096405},{"id":"https://openalex.org/C207114421","wikidata":"https://www.wikidata.org/wiki/Q133900","display_name":"Diffraction","level":2,"score":0.3148078918457031},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.28950056433677673},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.17766940593719482},{"id":"https://openalex.org/C52859227","wikidata":"https://www.wikidata.org/wiki/Q7877","display_name":"Electrochemistry","level":3,"score":0.06772086024284363},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.062204450368881226},{"id":"https://openalex.org/C44228677","wikidata":"https://www.wikidata.org/wiki/Q181898","display_name":"Polymerization","level":3,"score":0.057877033948898315},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.0},{"id":"https://openalex.org/C17525397","wikidata":"https://www.wikidata.org/wiki/Q176140","display_name":"Electrode","level":2,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C120665830","wikidata":"https://www.wikidata.org/wiki/Q14620","display_name":"Optics","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/om010413o","doi":"https://doi.org/10.1021/om010413o","is_oa":false,"landing_page_url":"https://doi.org/10.1021/om010413o","pdf_url":null,"source":{"id":"https://openalex.org/S4924609","display_name":"Organometallics","issn_l":"0276-7333","issn":["0276-7333","1520-6041"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-1","norway-2"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organometallics","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"sustainable_development_goals_aurora":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":9,"referenced_works":["https://openalex.org/W294393791","https://openalex.org/W1967957680","https://openalex.org/W1969256464","https://openalex.org/W1970922505","https://openalex.org/W1972011026","https://openalex.org/W1986614131","https://openalex.org/W2332218254","https://openalex.org/W2482489350","https://openalex.org/W3151857665"],"related_works":["https://openalex.org/W2004154211","https://openalex.org/W2047411755","https://openalex.org/W2352565734","https://openalex.org/W3214013332","https://openalex.org/W4254699482","https://openalex.org/W2057536121","https://openalex.org/W1995306871","https://openalex.org/W2084533042","https://openalex.org/W1978477185","https://openalex.org/W2087387151"],"abstract_inverted_index":{"Reaction":[0],"of":[1,10,21,30,48],"ferrocene":[2],"and":[3],"3,3\u2018,4,4\u2018-tetramethyl-1,1\u2018-diphosphaferrocene":[4],"with":[5],"diketene":[6],"in":[7,45],"the":[8,17,40,46],"presence":[9,47],"BF":[11,18],"3":[12],"\u00b7Et":[13],"2":[14,19],"O":[15],"affords":[16],"chelates":[20],"acetoacetylated":[22],"metallocenes":[23],"2a,":[24],"b":[25,54],".":[26],"The":[27],"crystal":[28],"structures":[29],"these":[31],"complexes":[32],"have":[33],"been":[34],"determined":[35],"by":[36],"X-ray":[37],"diffraction.":[38],"When":[39],"reaction":[41],"is":[42],"carried":[43],"out":[44],"AlCl":[49],"3,":[50],"metallocene":[51],"1,3-diketones":[52],"3a,":[53],"are":[55],"formed.":[56]},"counts_by_year":[{"year":2023,"cited_by_count":1},{"year":2019,"cited_by_count":1},{"year":2012,"cited_by_count":1}],"updated_date":"2026-08-21T09:56:20.448147","created_date":"2025-10-10T00:00:00"}