{"id":"https://openalex.org/W1982902018","doi":"https://doi.org/10.1039/c2dt12031c","title":"Exploring hypervalency and three-centre, four-electron bonding interactions: Reactions of acenaphthene chalcogen donors and dihalogen acceptors","display_name":"Exploring hypervalency and three-centre, four-electron bonding interactions: Reactions of acenaphthene chalcogen donors and dihalogen acceptors","publication_year":2012,"publication_date":"2012-01-01","ids":{"openalex":"https://openalex.org/W1982902018","doi":"https://doi.org/10.1039/c2dt12031c","mag":"1982902018","pmid":"https://pubmed.ncbi.nlm.nih.gov/22290272"},"language":"en","primary_location":{"id":"doi:10.1039/c2dt12031c","doi":"https://doi.org/10.1039/c2dt12031c","is_oa":false,"landing_page_url":"https://doi.org/10.1039/c2dt12031c","pdf_url":null,"source":{"id":"https://openalex.org/S166159787","display_name":"Dalton Transactions","issn_l":"1477-9226","issn":["1477-9226","1477-9234"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","ki-jl-1","medline","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Dalton Transactions","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5046596426","display_name":"Fergus R. Knight","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I16835326","display_name":"University of St Andrews","ror":"https://ror.org/02wn5qz54","country_code":"GB","type":"education","lineage":["https://openalex.org/I16835326"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"Fergus R. Knight","raw_affiliation_strings":["EaSTCHEM School of Chemistry, University of St Andrews, St Andrews, Fife, UK","EaSTCHEM School of Chemistry, University of St Andrews,St Andrews,U.K"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"EaSTCHEM School of Chemistry, University of St Andrews, St Andrews, Fife, UK","institution_ids":["https://openalex.org/I16835326"]},{"raw_affiliation_string":"EaSTCHEM School of Chemistry, University of St Andrews,St Andrews,U.K","institution_ids":["https://openalex.org/I16835326"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5000926504","display_name":"Kasun S. Athukorala Arachchige","orcid":"https://orcid.org/0000-0002-2169-2718","observed_orcids":["https://orcid.org/0000-0002-2169-2718"]},"institutions":[{"id":"https://openalex.org/I16835326","display_name":"University of St Andrews","ror":"https://ror.org/02wn5qz54","country_code":"GB","type":"education","lineage":["https://openalex.org/I16835326"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"Kasun S. Athukorala Arachchige","raw_affiliation_strings":["EaSTCHEM School of Chemistry, University of St Andrews, St Andrews, Fife, U.K","EaSTCHEM School of Chemistry, University of St Andrews,St Andrews,U.K"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"EaSTCHEM School of Chemistry, University of St Andrews, St Andrews, Fife, U.K","institution_ids":["https://openalex.org/I16835326"]},{"raw_affiliation_string":"EaSTCHEM School of Chemistry, University of St Andrews,St Andrews,U.K","institution_ids":["https://openalex.org/I16835326"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5048832266","display_name":"Rebecca A. M. Randall","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I16835326","display_name":"University of St Andrews","ror":"https://ror.org/02wn5qz54","country_code":"GB","type":"education","lineage":["https://openalex.org/I16835326"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"Rebecca A. M. Randall","raw_affiliation_strings":["EaSTCHEM School of Chemistry, University of St Andrews, St Andrews, Fife, U.K","EaSTCHEM School of Chemistry, University of St Andrews,St Andrews,U.K"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"EaSTCHEM School of Chemistry, University of St Andrews, St Andrews, Fife, U.K","institution_ids":["https://openalex.org/I16835326"]},{"raw_affiliation_string":"EaSTCHEM School of Chemistry, University of St Andrews,St Andrews,U.K","institution_ids":["https://openalex.org/I16835326"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5108948526","display_name":"Mich\u00e6l B\u00fchl","orcid":"https://orcid.org/0000-0002-1095-7143","observed_orcids":["https://orcid.org/0000-0002-1095-7143"]},"institutions":[{"id":"https://openalex.org/I16835326","display_name":"University of St Andrews","ror":"https://ror.org/02wn5qz54","country_code":"GB","type":"education","lineage":["https://openalex.org/I16835326"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"Michael B\u00fchl","raw_affiliation_strings":["EaSTCHEM School of Chemistry, University of St Andrews, St Andrews, Fife, U.K","EaSTCHEM School of Chemistry, University of St Andrews,St Andrews,U.K"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"EaSTCHEM School of Chemistry, University of St Andrews, St Andrews, Fife, U.K","institution_ids":["https://openalex.org/I16835326"]},{"raw_affiliation_string":"EaSTCHEM School of Chemistry, University of St Andrews,St Andrews,U.K","institution_ids":["https://openalex.org/I16835326"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5049970193","display_name":"Alexandra M. Z. Slawin","orcid":"https://orcid.org/0000-0002-9527-6418","observed_orcids":["https://orcid.org/0000-0002-9527-6418"]},"institutions":[{"id":"https://openalex.org/I16835326","display_name":"University of St Andrews","ror":"https://ror.org/02wn5qz54","country_code":"GB","type":"education","lineage":["https://openalex.org/I16835326"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"Alexandra M. Z. Slawin","raw_affiliation_strings":["EaSTCHEM School of Chemistry, University of St Andrews, St Andrews, Fife, U.K","EaSTCHEM School of Chemistry, University of St Andrews,St Andrews,U.K"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"EaSTCHEM School of Chemistry, University of St Andrews, St Andrews, Fife, U.K","institution_ids":["https://openalex.org/I16835326"]},{"raw_affiliation_string":"EaSTCHEM School of Chemistry, University of St Andrews,St Andrews,U.K","institution_ids":["https://openalex.org/I16835326"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5082468565","display_name":"J. Derek Woollins","orcid":"https://orcid.org/0000-0002-1498-9652","observed_orcids":["https://orcid.org/0000-0002-1498-9652"]},"institutions":[{"id":"https://openalex.org/I16835326","display_name":"University of St Andrews","ror":"https://ror.org/02wn5qz54","country_code":"GB","type":"education","lineage":["https://openalex.org/I16835326"]}],"countries":["GB"],"is_corresponding":true,"raw_author_name":"J. Derek Woollins","raw_affiliation_strings":["EaSTCHEM School of Chemistry, University of St Andrews, St Andrews, Fife, U.K","EaSTCHEM School of Chemistry, University of St Andrews,St Andrews,U.K"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"EaSTCHEM School of Chemistry, University of St Andrews, St Andrews, Fife, U.K","institution_ids":["https://openalex.org/I16835326"]},{"raw_affiliation_string":"EaSTCHEM School of Chemistry, University of St Andrews,St Andrews,U.K","institution_ids":["https://openalex.org/I16835326"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5082468565"],"corresponding_institution_ids":["https://openalex.org/I16835326"],"apc_list":null,"apc_paid":null,"fwci":2.4602,"has_fulltext":false,"cited_by_count":36,"citation_normalized_percentile":{"value":0.88172272,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":87,"max":99},"biblio":{"volume":"41","issue":"11","first_page":"3154","last_page":"3154"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11931","display_name":"Organoselenium and organotellurium chemistry","score":0.9932000041007996,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11931","display_name":"Organoselenium and organotellurium chemistry","score":0.9932000041007996,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10798","display_name":"Crystallography and molecular interactions","score":0.0034000000450760126,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.0026000000070780516,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/hypervalent-bonding","display_name":"hypervalent bonding","score":0.7850000262260437},{"id":"https://openalex.org/keywords/selenium","display_name":"selenium","score":0.4309999942779541},{"id":"https://openalex.org/keywords/tellurium","display_name":"tellurium","score":0.9990000128746033},{"id":"https://openalex.org/keywords/molecular-iodine","display_name":"molecular iodine","score":0.9990000128746033},{"id":"https://openalex.org/keywords/wiberg-bond-index","display_name":"Wiberg bond index","score":0.7919999957084656},{"id":"https://openalex.org/keywords/steric-strain","display_name":"steric strain","score":0.5619999766349792}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7987151741981506},{"id":"https://openalex.org/C201194858","wikidata":"https://www.wikidata.org/wiki/Q898238","display_name":"Steric effects","level":2,"score":0.7165161967277527},{"id":"https://openalex.org/C158733187","wikidata":"https://www.wikidata.org/wiki/Q104567","display_name":"Chalcogen","level":2,"score":0.7014243602752686},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.6111331582069397},{"id":"https://openalex.org/C108204754","wikidata":"https://www.wikidata.org/wiki/Q353392","display_name":"Adduct","level":2,"score":0.5903390049934387},{"id":"https://openalex.org/C538181303","wikidata":"https://www.wikidata.org/wiki/Q1100","display_name":"Tellurium","level":2,"score":0.574798047542572},{"id":"https://openalex.org/C2776128831","wikidata":"https://www.wikidata.org/wiki/Q415103","display_name":"Acenaphthene","level":3,"score":0.48968079686164856},{"id":"https://openalex.org/C553756173","wikidata":"https://www.wikidata.org/wiki/Q876","display_name":"Selenium","level":2,"score":0.45744794607162476},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.4505199193954468},{"id":"https://openalex.org/C96149497","wikidata":"https://www.wikidata.org/wiki/Q556957","display_name":"Hypervalent molecule","level":3,"score":0.4419702887535095},{"id":"https://openalex.org/C2779255514","wikidata":"https://www.wikidata.org/wiki/Q179724","display_name":"Naphthalene","level":2,"score":0.16839581727981567},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.16090479493141174},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.10551488399505615},{"id":"https://openalex.org/C40875361","wikidata":"https://www.wikidata.org/wiki/Q2356542","display_name":"Reagent","level":2,"score":0.0}],"mesh":[{"descriptor_ui":"D000073","descriptor_name":"Acenaphthenes","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D004583","descriptor_name":"Electrons","qualifier_ui":null,"qualifier_name":null,"is_major_topic":true},{"descriptor_ui":"D006219","descriptor_name":"Halogens","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D008958","descriptor_name":"Models, Molecular","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D015394","descriptor_name":"Molecular Structure","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D018011","descriptor_name":"Chalcogens","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true}],"locations_count":2,"locations":[{"id":"doi:10.1039/c2dt12031c","doi":"https://doi.org/10.1039/c2dt12031c","is_oa":false,"landing_page_url":"https://doi.org/10.1039/c2dt12031c","pdf_url":null,"source":{"id":"https://openalex.org/S166159787","display_name":"Dalton Transactions","issn_l":"1477-9226","issn":["1477-9226","1477-9234"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","ki-jl-1","medline","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Dalton Transactions","raw_type":"journal-article"},{"id":"pmid:22290272","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/22290272","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Dalton transactions (Cambridge, England : 2003)","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":121,"referenced_works":["https://openalex.org/W162134388","https://openalex.org/W1900826422","https://openalex.org/W1945852875","https://openalex.org/W1964444319","https://openalex.org/W1964945694","https://openalex.org/W1967297440","https://openalex.org/W1970812660","https://openalex.org/W1973658771","https://openalex.org/W1973799438","https://openalex.org/W1973863427","https://openalex.org/W1974824902","https://openalex.org/W1977510754","https://openalex.org/W1978067391","https://openalex.org/W1979151615","https://openalex.org/W1982335521","https://openalex.org/W1982562580","https://openalex.org/W1984654745","https://openalex.org/W1984668482","https://openalex.org/W1985571493","https://openalex.org/W1986177982","https://openalex.org/W1987770659","https://openalex.org/W1988729986","https://openalex.org/W1990203506","https://openalex.org/W1990569987","https://openalex.org/W1991070554","https://openalex.org/W1994175879","https://openalex.org/W1995228030","https://openalex.org/W1996401486","https://openalex.org/W1999313605","https://openalex.org/W2001749504","https://openalex.org/W2003116260","https://openalex.org/W2003763615","https://openalex.org/W2004933104","https://openalex.org/W2005336091","https://openalex.org/W2005497868","https://openalex.org/W2008146837","https://openalex.org/W2009019260","https://openalex.org/W2009366610","https://openalex.org/W2009393624","https://openalex.org/W2009439183","https://openalex.org/W2013995815","https://openalex.org/W2015310109","https://openalex.org/W2018020144","https://openalex.org/W2021078844","https://openalex.org/W2021650034","https://openalex.org/W2023099385","https://openalex.org/W2028098603","https://openalex.org/W2029273195","https://openalex.org/W2029545139","https://openalex.org/W2030118137","https://openalex.org/W2030841140","https://openalex.org/W2034435531","https://openalex.org/W2038680649","https://openalex.org/W2038981672","https://openalex.org/W2039672697","https://openalex.org/W2040803994","https://openalex.org/W2042944554","https://openalex.org/W2045456897","https://openalex.org/W2046100015","https://openalex.org/W2046644676","https://openalex.org/W2049545783","https://openalex.org/W2051213861","https://openalex.org/W2055312596","https://openalex.org/W2055996695","https://openalex.org/W2058169540","https://openalex.org/W2059553910","https://openalex.org/W2063381084","https://openalex.org/W2065780566","https://openalex.org/W2065867563","https://openalex.org/W2065924010","https://openalex.org/W2066737753","https://openalex.org/W2068114737","https://openalex.org/W2070365098","https://openalex.org/W2070427579","https://openalex.org/W2072626970","https://openalex.org/W2073642300","https://openalex.org/W2076588878","https://openalex.org/W2077726405","https://openalex.org/W2082114678","https://openalex.org/W2084485474","https://openalex.org/W2086628380","https://openalex.org/W2089753285","https://openalex.org/W2089896027","https://openalex.org/W2090115806","https://openalex.org/W2092752317","https://openalex.org/W2096485346","https://openalex.org/W2108921478","https://openalex.org/W2109027906","https://openalex.org/W2113701650","https://openalex.org/W2113718502","https://openalex.org/W2122510276","https://openalex.org/W2136935009","https://openalex.org/W2138925811","https://openalex.org/W2142045013","https://openalex.org/W2145538332","https://openalex.org/W2155966708","https://openalex.org/W2156056161","https://openalex.org/W2161663929","https://openalex.org/W2165600904","https://openalex.org/W2166689829","https://openalex.org/W2167095537","https://openalex.org/W2169232950","https://openalex.org/W2176276889","https://openalex.org/W2228099403","https://openalex.org/W2288063349","https://openalex.org/W2315773301","https://openalex.org/W2317451970","https://openalex.org/W2325338962","https://openalex.org/W2328340213","https://openalex.org/W2489313534","https://openalex.org/W2493779723","https://openalex.org/W2512655410","https://openalex.org/W2798365353","https://openalex.org/W2949566951","https://openalex.org/W2951081612","https://openalex.org/W2951408343","https://openalex.org/W2951799660","https://openalex.org/W3138417038","https://openalex.org/W4237154396","https://openalex.org/W4240963113","https://openalex.org/W4242970978"],"related_works":["https://openalex.org/W1995228030","https://openalex.org/W2076588878","https://openalex.org/W2111487152","https://openalex.org/W2053706008","https://openalex.org/W1574767375","https://openalex.org/W1976451632","https://openalex.org/W1973692383","https://openalex.org/W2084485474","https://openalex.org/W2048185195","https://openalex.org/W6959646875"],"abstract_inverted_index":{"Sterically":[0],"crowded":[1],"peri-substituted":[2],"selenium":[3,77],"and":[4,28,91,102,115,163,165,170,194,202,232],"tellurium":[5,240],"acenaphthene":[6],"donors":[7,51,78],"D1-D7":[8],"[Acenap(EPh)(Br)":[9],"E":[10,15,20],"=":[11,16,21,128],"Se,":[12,17,23,129],"Te;":[13],"Acenap(SePh)(EPh)":[14],"S;":[18],"Acenap(TePh)(EPh)":[19],"S,":[22],"Te]":[24],"react":[25,53],"with":[26,55,80,104,219,237],"dibromine":[27,105,220],"diiodine":[29,81],"acceptors":[30],"to":[31,45,58,153,210,221],"afford":[32,59,82,222],"a":[33,123,142,212,229,243],"group":[34],"of":[35,76,100,110,140,176,187,206],"structurally":[36],"diverse":[37],"addition":[38],"products":[39],"1-12,":[40],"comparable":[41],"in":[42,107,134,182,192],"some":[43],"cases":[44],"previously":[46],"reported":[47],"naphthalene":[48],"analogues.":[49],"Tellurium":[50],"D4-D6":[52],"conventionally":[54],"the":[56,108,154,200,204,238],"dihalogens":[57],"insertion":[60,225],"adducts":[61,88],"6-11":[62],"(X-R(2)Te-X)":[63],"exhibiting":[64,122],"molecular":[65,207,244],"see-saw":[66,245],"geometries,":[67],"characterised":[68],"by":[69],"hypervalent":[70,144],"X-Te-X":[71],"quasi-linear":[72,95,124,234],"fragments.":[73],"The":[74,132,185],"reactions":[75],"D1-D3":[79],"expected":[83],"neutral":[84],"charge-transfer":[85],"(CT)":[86],"spoke":[87],"1,":[89],"4":[90],"5":[92],"(R(2)Se-I-I)":[93],"containing":[94,117,228],"Se-I-I":[96],"alignments.":[97],"Conversely,":[98],"treatment":[99],"D2":[101],"D3":[103],"results":[106],"formation":[109,256],"two":[111,233],"tribromide":[112],"salts":[113],"2":[114,162,193],"3":[116,164,195],"bromoselanyl":[118],"cations":[119,168],"[R(2)Se-Br](+)\u00b7\u00b7\u00b7[Br-Br(2)](-),":[120],"each":[121],"three-body":[125],"Br-Se\u00b7\u00b7\u00b7E":[126],"(E":[127],"S)":[130],"fragment.":[131],"peri-bonding":[133],"these":[135,183],"species":[136],"can":[137],"be":[138],"thought":[139],"as":[141],"weak":[143],"G\u00b7\u00b7\u00b7Se-X":[145],"three-centre,":[146],"four-electron":[147],"(3c-4e)":[148],"type":[149],"interaction,":[150],"closely":[151],"related":[152],"T-shaped":[155],"3c-4e":[156,180],"interaction.":[157],"Density-functional":[158],"calculations":[159,249],"performed":[160],"on":[161],"their":[166],"bare":[167],"(2a":[169],"3a)":[171],"reveal":[172],"Wiberg":[173],"bond":[174],"indices":[175],"0.25-0.37,":[177],"suggesting":[178],"substantial":[179],"character":[181],"systems.":[184],"presence":[186],"such":[188],"an":[189,223],"interaction":[190],"operating":[191],"alleviates":[196],"steric":[197],"strain":[198],"within":[199],"peri-region":[201],"minimises":[203],"degree":[205],"distortion":[208],"required":[209],"achieve":[211],"relaxed":[213],"geometry.":[214,246],"Ditellurium":[215],"donor":[216],"D7":[217],"reacts":[218],"unorthodox":[224],"adduct":[226],"12":[227,251],"Te-O-Te":[230],"bridge":[231],"Br-Te-O":[235],"fragments,":[236],"central":[239],"atoms":[241],"assuming":[242],"Whilst":[247],"DFT":[248],"indicate":[250],"is":[252,257],"thermodynamically":[253],"unfavourable,":[254],"its":[255],"viable":[258],"under":[259],"experimental":[260],"conditions.":[261]},"counts_by_year":[{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":3},{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":2},{"year":2021,"cited_by_count":1},{"year":2020,"cited_by_count":1},{"year":2018,"cited_by_count":4},{"year":2017,"cited_by_count":1},{"year":2016,"cited_by_count":4},{"year":2015,"cited_by_count":1},{"year":2014,"cited_by_count":8},{"year":2013,"cited_by_count":4},{"year":2012,"cited_by_count":5}],"updated_date":"2026-10-31T12:09:11.096373","created_date":"2016-06-24T00:00:00"}