{"id":"https://openalex.org/W1982221978","doi":"https://doi.org/10.1080/03086647708070731","title":"\u00dcBER DIE ADDITION VON HALOGENEN UND INTERHALOGENVERBINDUNGEN AN VINYLPHOSPHONS\u00c4UREDIISOPROPYLESTER","display_name":"\u00dcBER DIE ADDITION VON HALOGENEN UND INTERHALOGENVERBINDUNGEN AN VINYLPHOSPHONS\u00c4UREDIISOPROPYLESTER","publication_year":1977,"publication_date":"1977-01-01","ids":{"openalex":"https://openalex.org/W1982221978","doi":"https://doi.org/10.1080/03086647708070731","mag":"1982221978"},"language":"de","primary_location":{"id":"doi:10.1080/03086647708070731","doi":"https://doi.org/10.1080/03086647708070731","is_oa":false,"landing_page_url":"https://doi.org/10.1080/03086647708070731","pdf_url":null,"source":{"id":"https://openalex.org/S4210229243","display_name":"Phosphorous and Sulfur and the Related Elements","issn_l":"0308-664X","issn":["0308-664X"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320547","host_organization_name":"Taylor & Francis","host_organization_lineage":["https://openalex.org/P4310320547","https://openalex.org/P4310320449"],"host_organization_lineage_names":["Taylor & Francis","Informa"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Phosphorous and Sulfur and the Related Elements","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5010072630","display_name":"Gerhard H\u00e4gele","orcid":"https://orcid.org/0000-0001-9815-2181","observed_orcids":["https://orcid.org/0000-0001-9815-2181"]},"institutions":[{"id":"https://openalex.org/I44260953","display_name":"Heinrich Heine University D\u00fcsseldorf","ror":"https://ror.org/024z2rq82","country_code":"DE","type":"education","lineage":["https://openalex.org/I44260953"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Gerhard H\u00e4gele","raw_affiliation_strings":["Institut f\u00fcr Anorganische und Strukturchemie, Universit\u00e4t D\u00fcsseldorf"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institut f\u00fcr Anorganische und Strukturchemie, Universit\u00e4t D\u00fcsseldorf","institution_ids":["https://openalex.org/I44260953"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5031686284","display_name":"Hans Dolhaine","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I44260953","display_name":"Heinrich Heine University D\u00fcsseldorf","ror":"https://ror.org/024z2rq82","country_code":"DE","type":"education","lineage":["https://openalex.org/I44260953"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Hans Dolhaine","raw_affiliation_strings":["Institut f\u00fcr Anorganische und Strukturchemie, Universit\u00e4t D\u00fcsseldorf"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institut f\u00fcr Anorganische und Strukturchemie, Universit\u00e4t D\u00fcsseldorf","institution_ids":["https://openalex.org/I44260953"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I44260953"],"apc_list":null,"apc_paid":null,"fwci":1.2141,"has_fulltext":false,"cited_by_count":8,"citation_normalized_percentile":{"value":0.70651948,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":93,"max":95},"biblio":{"volume":"3","issue":"1","first_page":"47","last_page":"50"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11748","display_name":"Organophosphorus compounds synthesis","score":0.9945999979972839,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11748","display_name":"Organophosphorus compounds synthesis","score":0.9945999979972839,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12191","display_name":"Physical Organic Chemistry and Reaction Kinetics","score":0.003000000026077032,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13239","display_name":"Phosphorus compounds and reactions","score":0.0007999999797903001,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/halogen-addition","display_name":"halogen addition","score":0.8970000147819519},{"id":"https://openalex.org/keywords/interhalogen-compounds","display_name":"interhalogen compounds","score":0.9890000224113464},{"id":"https://openalex.org/keywords/dehydrohalogenation","display_name":"dehydrohalogenation","score":0.9879999756813049},{"id":"https://openalex.org/keywords/1h-nmr-spectra","display_name":"1H NMR spectrum","score":0.6790000200271606}],"concepts":[{"id":"https://openalex.org/C2779506367","wikidata":"https://www.wikidata.org/wiki/Q3045102","display_name":"Dehydrohalogenation","level":3,"score":0.7195792198181152},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.4889780282974243},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.05759814381599426},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1080/03086647708070731","doi":"https://doi.org/10.1080/03086647708070731","is_oa":false,"landing_page_url":"https://doi.org/10.1080/03086647708070731","pdf_url":null,"source":{"id":"https://openalex.org/S4210229243","display_name":"Phosphorous and Sulfur and the Related Elements","issn_l":"0308-664X","issn":["0308-664X"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320547","host_organization_name":"Taylor & Francis","host_organization_lineage":["https://openalex.org/P4310320547","https://openalex.org/P4310320449"],"host_organization_lineage_names":["Taylor & Francis","Informa"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Phosphorous and Sulfur and the Related Elements","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":8,"referenced_works":["https://openalex.org/W561466323","https://openalex.org/W2057763974","https://openalex.org/W2062529240","https://openalex.org/W2066465339","https://openalex.org/W2069142685","https://openalex.org/W2118822502","https://openalex.org/W2329125051","https://openalex.org/W4237685946"],"related_works":["https://openalex.org/W2312255287","https://openalex.org/W2605235891","https://openalex.org/W2315734206","https://openalex.org/W2607364002","https://openalex.org/W2343948648","https://openalex.org/W2325837996","https://openalex.org/W2338464387","https://openalex.org/W2012043421","https://openalex.org/W2340371814","https://openalex.org/W2313205915"],"abstract_inverted_index":{"Halogene":[0],"(Cl2,":[1,38],"Br2)":[2,39],"und":[3,27],"Interhalogenverbindungen":[4],"(ClBr,":[5,43],"ClJ,":[6,44],"BrJ)":[7,45],"addieren":[8],"an":[9],"Vinylphosphons\u00e4urediisopropylester":[10],"zu":[11],"den":[12],"1,2-Dihalogen\u00e4thanphosphons\u00e4urediisopropylestern.":[13],"Anti-Markovnikoff":[14],"Addition":[15,35,56],"wird":[16],"nachgewiesen.":[17],"Durch":[18],"Dehydrohalogenierung":[19],"der":[20],"1,2-Dihalogenaddukte":[21],"entstehen":[22],"1-Halogenvinylphosphons\u00e4urediisopropylester.":[23],"Ergebnisse":[24],"von":[25],"60":[26,71],"270":[28,73],"MHz":[29,74],"1H":[30,75],"NMR":[31],"Spektralanalysen":[32],"werden":[33],"mitgeteilt.":[34],"of":[36,62,70],"halogens":[37],"and":[40,72],"interhalogen":[41],"compounds":[42],"to":[46,51],"vinylphosphonic":[47],"acid":[48,54,67],"diisopropylester":[49],"leads":[50],"1,2-dihalogenoethane":[52],"phosphonic":[53,66],"diisopropylesters.":[55,68],"in":[57],"anti-Markovnikoff-sense":[58],"is":[59],"derived.":[60],"Dehydrohalogenation":[61],"1,2-dihalogenoadducts":[63],"yields":[64],"1-halogenovinyl":[65],"Results":[69],"nmr":[76],"spectral":[77],"analysis":[78],"are":[79],"given.":[80]},"counts_by_year":[{"year":2014,"cited_by_count":2}],"updated_date":"2026-08-15T07:11:24.734988","created_date":"2016-06-24T00:00:00"}
