{"id":"https://openalex.org/W1980910482","doi":"https://doi.org/10.1021/am1008612","title":"Influence of the Polymer Backbone Structure on the Properties of Aromatic Ionomers with Pendant Sulfobenzoyl Side Chains for Use As Proton-Exchange Membranes","display_name":"Influence of the Polymer Backbone Structure on the Properties of Aromatic Ionomers with Pendant Sulfobenzoyl Side Chains for Use As Proton-Exchange Membranes","publication_year":2010,"publication_date":"2010-12-07","ids":{"openalex":"https://openalex.org/W1980910482","doi":"https://doi.org/10.1021/am1008612","mag":"1980910482","pmid":"https://pubmed.ncbi.nlm.nih.gov/21138250"},"language":"en","primary_location":{"id":"doi:10.1021/am1008612","doi":"https://doi.org/10.1021/am1008612","is_oa":false,"landing_page_url":"https://doi.org/10.1021/am1008612","pdf_url":null,"source":{"id":"https://openalex.org/S164001016","display_name":"ACS Applied Materials & Interfaces","issn_l":"1944-8244","issn":["1944-8244","1944-8252"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-1","medline","norway-1","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Applied Materials & Interfaces","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5082170396","display_name":"Elin Persson Jutemar","orcid":"https://orcid.org/0000-0002-9076-1385","observed_orcids":["https://orcid.org/0000-0002-9076-1385"]},"institutions":[{"id":"https://openalex.org/I187531555","display_name":"Lund University","ror":"https://ror.org/012a77v79","country_code":"SE","type":"education","lineage":["https://openalex.org/I187531555"]}],"countries":["SE"],"is_corresponding":false,"raw_author_name":"Elin Persson Jutemar","raw_affiliation_strings":["Polymer & Materials Chemistry, Department of Chemistry, Lund University, P.O. Box 124, SE-221 00 Lund, Sweden"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Polymer & Materials Chemistry, Department of Chemistry, Lund University, P.O. Box 124, SE-221 00 Lund, Sweden","institution_ids":["https://openalex.org/I187531555"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5083291915","display_name":"Patric Jannasch","orcid":"https://orcid.org/0000-0002-9649-7781","observed_orcids":["https://orcid.org/0000-0002-9649-7781","https://orcid.org/0000-0002-1102-3959"]},"institutions":[{"id":"https://openalex.org/I187531555","display_name":"Lund University","ror":"https://ror.org/012a77v79","country_code":"SE","type":"education","lineage":["https://openalex.org/I187531555"]}],"countries":["SE"],"is_corresponding":true,"raw_author_name":"Patric Jannasch","raw_affiliation_strings":["Polymer & Materials Chemistry, Department of Chemistry, Lund University, P.O. Box 124, SE-221 00 Lund, Sweden"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Polymer & Materials Chemistry, Department of Chemistry, Lund University, P.O. Box 124, SE-221 00 Lund, Sweden","institution_ids":["https://openalex.org/I187531555"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5083291915"],"corresponding_institution_ids":["https://openalex.org/I187531555"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":1.4301,"has_fulltext":false,"cited_by_count":33,"citation_normalized_percentile":{"value":0.81528234,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":87,"max":98},"biblio":{"volume":"2","issue":"12","first_page":"3718","last_page":"3725"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10409","display_name":"Fuel Cells and Related Materials","score":1.0,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10409","display_name":"Fuel Cells and Related Materials","score":1.0,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12074","display_name":"Membrane-based Ion Separation Techniques","score":0.0,"subfield":{"id":"https://openalex.org/subfields/1506","display_name":"Filtration and Separation"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10281","display_name":"Advanced Battery Materials and Technologies","score":0.0,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/proton-exchange-membranes","display_name":"proton exchange membranes","score":0.9020000100135803},{"id":"https://openalex.org/keywords/polymer-backbone","display_name":"polymer backbone","score":0.8240000009536743},{"id":"https://openalex.org/keywords/nucleophilic-aromatic-substitution","display_name":"nucleophilic aromatic substitution","score":0.8659999966621399},{"id":"https://openalex.org/keywords/poly-arylene-ether-s","display_name":"poly(arylene ether)s","score":0.8389999866485596},{"id":"https://openalex.org/keywords/glass-transition-temperature","display_name":"glass transition temperature","score":0.8989999890327454},{"id":"https://openalex.org/keywords/proton-conductivity","display_name":"proton conductivity","score":0.8370000123977661},{"id":"https://openalex.org/keywords/ion-exchange-capacity","display_name":"ion exchange capacity","score":0.9020000100135803},{"id":"https://openalex.org/keywords/mechanical-toughness","display_name":"mechanical toughness","score":0.5839999914169312},{"id":"https://openalex.org/keywords/thermal-stability","display_name":"thermal stability","score":0.5759999752044678}],"concepts":[{"id":"https://openalex.org/C2779843779","wikidata":"https://www.wikidata.org/wiki/Q4802706","display_name":"Arylene","level":4,"score":0.965933084487915},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.7295860052108765},{"id":"https://openalex.org/C122865956","wikidata":"https://www.wikidata.org/wiki/Q825643","display_name":"Glass transition","level":3,"score":0.7278700470924377},{"id":"https://openalex.org/C2780407432","wikidata":"https://www.wikidata.org/wiki/Q103230","display_name":"Ether","level":2,"score":0.6895773410797119},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.656702995300293},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.5806286334991455},{"id":"https://openalex.org/C2776171763","wikidata":"https://www.wikidata.org/wiki/Q290308","display_name":"Ionomer","level":4,"score":0.5410913228988647},{"id":"https://openalex.org/C204921945","wikidata":"https://www.wikidata.org/wiki/Q899689","display_name":"Side chain","level":3,"score":0.5353527665138245},{"id":"https://openalex.org/C41625074","wikidata":"https://www.wikidata.org/wiki/Q176088","display_name":"Membrane","level":2,"score":0.5256448984146118},{"id":"https://openalex.org/C2182769","wikidata":"https://www.wikidata.org/wiki/Q62500","display_name":"Ionic bonding","level":3,"score":0.42736077308654785},{"id":"https://openalex.org/C138679309","wikidata":"https://www.wikidata.org/wiki/Q6063658","display_name":"Ionic conductivity","level":4,"score":0.4263090193271637},{"id":"https://openalex.org/C160434732","wikidata":"https://www.wikidata.org/wiki/Q2611095","display_name":"Thermal decomposition","level":2,"score":0.4204106628894806},{"id":"https://openalex.org/C15920480","wikidata":"https://www.wikidata.org/wiki/Q421281","display_name":"Copolymer","level":3,"score":0.23367682099342346},{"id":"https://openalex.org/C68801617","wikidata":"https://www.wikidata.org/wiki/Q162908","display_name":"Electrolyte","level":3,"score":0.21529805660247803},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.1859295666217804},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.18331077694892883},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.14527907967567444},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.1127084493637085},{"id":"https://openalex.org/C2781076698","wikidata":"https://www.wikidata.org/wiki/Q718074","display_name":"Aryl","level":3,"score":0.08840537071228027},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.08824148774147034},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.07957428693771362},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C17525397","wikidata":"https://www.wikidata.org/wiki/Q176140","display_name":"Electrode","level":2,"score":0.0}],"mesh":[{"descriptor_ui":"D003460","descriptor_name":"Crystallization","qualifier_ui":"Q000379","qualifier_name":"methods","is_major_topic":true},{"descriptor_ui":"D006841","descriptor_name":"Hydrocarbons, Aromatic","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D008422","descriptor_name":"Materials Testing","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D008567","descriptor_name":"Membranes, Artificial","qualifier_ui":null,"qualifier_name":null,"is_major_topic":true},{"descriptor_ui":"D011522","descriptor_name":"Protons","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D036103","descriptor_name":"Nanotechnology","qualifier_ui":"Q000379","qualifier_name":"methods","is_major_topic":true}],"locations_count":3,"locations":[{"id":"doi:10.1021/am1008612","doi":"https://doi.org/10.1021/am1008612","is_oa":false,"landing_page_url":"https://doi.org/10.1021/am1008612","pdf_url":null,"source":{"id":"https://openalex.org/S164001016","display_name":"ACS Applied Materials & Interfaces","issn_l":"1944-8244","issn":["1944-8244","1944-8252"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-1","medline","norway-1","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Applied Materials & Interfaces","raw_type":"journal-article"},{"id":"pmid:21138250","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/21138250","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS applied materials & interfaces","raw_type":"Journal Article"},{"id":"pmh:oai:lup.lub.lu.se:93a60fbf-222a-425c-9b70-b7f5f2461ba4","doi":null,"is_oa":false,"landing_page_url":"https://lup.lub.lu.se/record/1734508","pdf_url":null,"source":{"id":"https://openalex.org/S4306400536","display_name":"Lund University Publications (Lund University)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I187531555","host_organization_name":"Lund University","host_organization_lineage":["https://openalex.org/I187531555"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"ISSN: 1944-8244","raw_type":"info:eu-repo/semantics/article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":42,"referenced_works":["https://openalex.org/W37786314","https://openalex.org/W60724374","https://openalex.org/W1569308213","https://openalex.org/W1964485243","https://openalex.org/W1978869094","https://openalex.org/W1981005677","https://openalex.org/W1988955292","https://openalex.org/W1992289686","https://openalex.org/W1997789964","https://openalex.org/W2003040835","https://openalex.org/W2003055001","https://openalex.org/W2009228491","https://openalex.org/W2013846855","https://openalex.org/W2016947316","https://openalex.org/W2022108768","https://openalex.org/W2022750249","https://openalex.org/W2030010476","https://openalex.org/W2032022179","https://openalex.org/W2032443462","https://openalex.org/W2033350506","https://openalex.org/W2040298266","https://openalex.org/W2044490808","https://openalex.org/W2051939800","https://openalex.org/W2056334432","https://openalex.org/W2059951861","https://openalex.org/W2067459833","https://openalex.org/W2070556110","https://openalex.org/W2070797584","https://openalex.org/W2075526320","https://openalex.org/W2079235679","https://openalex.org/W2087349968","https://openalex.org/W2087535770","https://openalex.org/W2109829618","https://openalex.org/W2123418645","https://openalex.org/W2129375929","https://openalex.org/W2140082839","https://openalex.org/W2145031930","https://openalex.org/W2158885140","https://openalex.org/W2159592871","https://openalex.org/W2159974326","https://openalex.org/W2168588253","https://openalex.org/W2169398350"],"related_works":["https://openalex.org/W2090758476","https://openalex.org/W2133021007","https://openalex.org/W2022750249","https://openalex.org/W2087535770","https://openalex.org/W2154000234","https://openalex.org/W2023391457","https://openalex.org/W2074806187","https://openalex.org/W2095858772","https://openalex.org/W1991683297","https://openalex.org/W2094414351"],"abstract_inverted_index":{"Six":[0],"different":[1],"ionomers":[2,83,115],"having":[3],"various":[4],"aromatic":[5,17],"polymer":[6,118],"backbones":[7,119],"with":[8,23,50,71,116],"pendant":[9],"2-sulfobenzoyl":[10],"side":[11],"chains":[12],"were":[13,62,79,94],"prepared":[14],"by":[15,103],"nucleophilic":[16],"substitution":[18],"reactions":[19],"of":[20,127],"lithium":[21],"2,6-difluoro-2'-sulfobenzophenone":[22],"4,4-biphenol,":[24],"2,7-dihydroxynaphthalene,":[25],"4,4-isopropylidenediphenol,":[26],"4,4-dihydroxydiphenyl":[27],"ether,":[28],"4,4'-thiodiphenol,":[29],"and":[30,42,68,89,120,141,144],"4,4'-thiobisbenzenethiol,":[31],"respectively,":[32],"to":[33,59,73,96,146],"produce":[34],"four":[35],"poly(arylene":[36,39,44],"ether)s,":[37],"one":[38,43],"ether":[40],"sulfide),":[41],"sulfide).":[45],"Mechanically":[46],"tough":[47],"proton-exchange":[48],"membranes":[49,129],"ion-exchange":[51],"capacities":[52],"in":[53,84],"the":[54,65,85,109,128,150],"narrow":[55],"range":[56],"from":[57,64],"1.9":[58],"2.3":[60],"mequiv/g":[61],"cast":[63],"high-molecular-weight":[66],"ionomers,":[67],"subsequently":[69],"investigated":[70],"respect":[72],"their":[74],"structure-property":[75],"relationships.":[76],"Glass":[77],"transitions":[78],"only":[80],"detected":[81],"for":[82,114],"sodium":[86],"salt":[87],"form,":[88],"increasing":[90],"glass-transition":[91],"temperatures":[92],"(Tg)":[93],"found":[95,138],"give":[97],"higher":[98],"thermal":[99],"decomposition":[100],"temperatures.":[101],"Analysis":[102],"small-angle":[104],"X-ray":[105],"scattering":[106],"indicated":[107],"that":[108],"ionic":[110],"clustering":[111],"was":[112,137],"promoted":[113],"flexible":[117],"low":[121],"Tg":[122],"values.":[123],"The":[124],"proton":[125],"conductivity":[126],"at":[130],"80":[131],"\u00b0C":[132],"under":[133],"fully":[134],"humidified":[135],"conditions":[136],"between":[139],"0.02":[140],"0.2":[142],"S/cm":[143],"appeared":[145],"depend":[147],"primarily":[148],"on":[149],"Tg.":[151]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2025,"cited_by_count":2},{"year":2024,"cited_by_count":2},{"year":2023,"cited_by_count":1},{"year":2020,"cited_by_count":3},{"year":2019,"cited_by_count":2},{"year":2018,"cited_by_count":1},{"year":2017,"cited_by_count":5},{"year":2016,"cited_by_count":2},{"year":2015,"cited_by_count":4},{"year":2014,"cited_by_count":3},{"year":2013,"cited_by_count":2},{"year":2012,"cited_by_count":4}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2016-06-24T00:00:00"}