{"id":"https://openalex.org/W1978670163","doi":"https://doi.org/10.1021/cg500441g","title":"Revealing the Roles of Desolvation and Molecular Self-Assembly in Crystal Nucleation from Solution: Benzoic and p -Aminobenzoic Acids","display_name":"Revealing the Roles of Desolvation and Molecular Self-Assembly in Crystal Nucleation from Solution: Benzoic and p -Aminobenzoic Acids","publication_year":2014,"publication_date":"2014-04-03","ids":{"openalex":"https://openalex.org/W1978670163","doi":"https://doi.org/10.1021/cg500441g","mag":"1978670163"},"language":"en","primary_location":{"id":"doi:10.1021/cg500441g","doi":"https://doi.org/10.1021/cg500441g","is_oa":false,"landing_page_url":"https://doi.org/10.1021/cg500441g","pdf_url":null,"source":{"id":"https://openalex.org/S16561315","display_name":"Crystal Growth & Design","issn_l":"1528-7483","issn":["1528-7483","1528-7505"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-2","norway-2","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Crystal Growth & Design","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5110196289","display_name":"R. A. L. Sullivan","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I28407311","display_name":"University of Manchester","ror":"https://ror.org/027m9bs27","country_code":"GB","type":"education","lineage":["https://openalex.org/I28407311"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"R. A. Sullivan","raw_affiliation_strings":["School of Chemical Engineering and Analytical\rScience, University of Manchester, Manchester M13 9PL, U.K"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemical Engineering and Analytical\rScience, University of Manchester, Manchester M13 9PL, U.K","institution_ids":["https://openalex.org/I28407311"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5022470737","display_name":"Roger J. Davey","orcid":"https://orcid.org/0000-0002-4690-1774","observed_orcids":["https://orcid.org/0000-0002-4690-1774"]},"institutions":[{"id":"https://openalex.org/I28407311","display_name":"University of Manchester","ror":"https://ror.org/027m9bs27","country_code":"GB","type":"education","lineage":["https://openalex.org/I28407311"]}],"countries":["GB"],"is_corresponding":true,"raw_author_name":"R. J. Davey","raw_affiliation_strings":["School of Chemical Engineering and Analytical\rScience, University of Manchester, Manchester M13 9PL, U.K"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemical Engineering and Analytical\rScience, University of Manchester, Manchester M13 9PL, U.K","institution_ids":["https://openalex.org/I28407311"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5015048686","display_name":"G. Sadiq","orcid":"https://orcid.org/0000-0001-6638-8464","observed_orcids":["https://orcid.org/0000-0001-6638-8464"]},"institutions":[{"id":"https://openalex.org/I28407311","display_name":"University of Manchester","ror":"https://ror.org/027m9bs27","country_code":"GB","type":"education","lineage":["https://openalex.org/I28407311"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"G. Sadiq","raw_affiliation_strings":["School of Chemical Engineering and Analytical\rScience, University of Manchester, Manchester M13 9PL, U.K"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemical Engineering and Analytical\rScience, University of Manchester, Manchester M13 9PL, U.K","institution_ids":["https://openalex.org/I28407311"]}]},{"author_position":"middle","author":{"id":null,"display_name":"G. Dent","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I28407311","display_name":"University of Manchester","ror":"https://ror.org/027m9bs27","country_code":"GB","type":"education","lineage":["https://openalex.org/I28407311"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"G. Dent","raw_affiliation_strings":["School of Chemical Engineering and Analytical\rScience, University of Manchester, Manchester M13 9PL, U.K"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemical Engineering and Analytical\rScience, University of Manchester, Manchester M13 9PL, U.K","institution_ids":["https://openalex.org/I28407311"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5055891385","display_name":"Kevin Back","orcid":"https://orcid.org/0000-0001-7666-4100","observed_orcids":["https://orcid.org/0000-0001-7666-4100"]},"institutions":[{"id":"https://openalex.org/I28407311","display_name":"University of Manchester","ror":"https://ror.org/027m9bs27","country_code":"GB","type":"education","lineage":["https://openalex.org/I28407311"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"K. R. Back","raw_affiliation_strings":["School of Chemical Engineering and Analytical\rScience, University of Manchester, Manchester M13 9PL, U.K"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemical Engineering and Analytical\rScience, University of Manchester, Manchester M13 9PL, U.K","institution_ids":["https://openalex.org/I28407311"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5030403342","display_name":"Joop H. ter Horst","orcid":"https://orcid.org/0000-0003-0118-2160","observed_orcids":["https://orcid.org/0000-0003-0118-2160"]},"institutions":[{"id":"https://openalex.org/I181647926","display_name":"University of Strathclyde","ror":"https://ror.org/00n3w3b69","country_code":"GB","type":"education","lineage":["https://openalex.org/I181647926"]},{"id":"https://openalex.org/I98358874","display_name":"Delft University of Technology","ror":"https://ror.org/02e2c7k09","country_code":"NL","type":"education","lineage":["https://openalex.org/I98358874"]}],"countries":["GB","NL"],"is_corresponding":false,"raw_author_name":"J. H. ter Horst","raw_affiliation_strings":["Intensified Reaction & Separation Systems, Delft University of Technology, Delft, The Netherlands","Strathclyde Institute Of Pharmacy And Biomedical Sciences"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Intensified Reaction & Separation Systems, Delft University of Technology, Delft, The Netherlands","institution_ids":["https://openalex.org/I98358874"]},{"raw_affiliation_string":"Strathclyde Institute Of Pharmacy And Biomedical Sciences","institution_ids":["https://openalex.org/I181647926"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5022592093","display_name":"Dimitrios Toroz","orcid":"https://orcid.org/0000-0002-1261-251X","observed_orcids":["https://orcid.org/0000-0002-1261-251X"]},"institutions":[{"id":"https://openalex.org/I130828816","display_name":"University of Leeds","ror":"https://ror.org/024mrxd33","country_code":"GB","type":"education","lineage":["https://openalex.org/I130828816"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"D. Toroz","raw_affiliation_strings":["Institute of Particle\rScience and Engineering, University of Leeds, Leeds LS2 9J, U.K"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute of Particle\rScience and Engineering, University of Leeds, Leeds LS2 9J, U.K","institution_ids":["https://openalex.org/I130828816"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5101579619","display_name":"Robert B. Hammond","orcid":"https://orcid.org/0000-0003-0691-7779","observed_orcids":["https://orcid.org/0000-0003-0691-7779"]},"institutions":[{"id":"https://openalex.org/I130828816","display_name":"University of Leeds","ror":"https://ror.org/024mrxd33","country_code":"GB","type":"education","lineage":["https://openalex.org/I130828816"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"R. B. Hammond","raw_affiliation_strings":["Institute of Particle\rScience and Engineering, University of Leeds, Leeds LS2 9J, U.K","Pure And Applied Chemistry"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute of Particle\rScience and Engineering, University of Leeds, Leeds LS2 9J, U.K","institution_ids":["https://openalex.org/I130828816"]},{"raw_affiliation_string":"Pure And Applied Chemistry","institution_ids":[]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":4,"corresponding_author_ids":["https://openalex.org/A5022470737"],"corresponding_institution_ids":["https://openalex.org/I28407311"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":4.7145,"has_fulltext":false,"cited_by_count":123,"citation_normalized_percentile":{"value":0.96166596,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":93,"max":100},"biblio":{"volume":"14","issue":"5","first_page":"2689","last_page":"2696"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11881","display_name":"Crystallization and Solubility Studies","score":0.9990000128746033,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11881","display_name":"Crystallization and Solubility Studies","score":0.9990000128746033,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11278","display_name":"Calcium Carbonate Crystallization and Inhibition","score":0.0003000000142492354,"subfield":{"id":"https://openalex.org/subfields/2502","display_name":"Biomaterials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12202","display_name":"nanoparticles nucleation surface interactions","score":0.00019999999494757503,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/crystal-nucleation","display_name":"crystal nucleation","score":0.9129999876022339},{"id":"https://openalex.org/keywords/desolvation","display_name":"desolvation","score":0.8489999771118164},{"id":"https://openalex.org/keywords/molecular-self-assembly","display_name":"molecular self-assembly","score":0.9959999918937683},{"id":"https://openalex.org/keywords/benzoic-acid","display_name":"benzoic acid","score":0.9419999718666077},{"id":"https://openalex.org/keywords/p-aminobenzoic-acid","display_name":"p-aminobenzoic acid","score":0.9990000128746033},{"id":"https://openalex.org/keywords/nucleation-kinetics","display_name":"nucleation kinetics","score":0.7829999923706055},{"id":"https://openalex.org/keywords/rate-limiting-step","display_name":"rate-determining step","score":0.8299999833106995},{"id":"https://openalex.org/keywords/polar-and-non-polar-solvents","display_name":"polar and non-polar solvents","score":0.8809999823570251},{"id":"https://openalex.org/keywords/crystal-growth-from-solution","display_name":"crystal growth from solution","score":0.4659999907016754}],"concepts":[{"id":"https://openalex.org/C61048295","wikidata":"https://www.wikidata.org/wiki/Q909022","display_name":"Nucleation","level":2,"score":0.9212961196899414},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7277655601501465},{"id":"https://openalex.org/C2778844314","wikidata":"https://www.wikidata.org/wiki/Q191700","display_name":"Benzoic acid","level":2,"score":0.5859160423278809},{"id":"https://openalex.org/C40869318","wikidata":"https://www.wikidata.org/wiki/Q899050","display_name":"Synthon","level":2,"score":0.5806390643119812},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.5202768445014954},{"id":"https://openalex.org/C44280652","wikidata":"https://www.wikidata.org/wiki/Q104837","display_name":"Phase (matter)","level":2,"score":0.5038220286369324},{"id":"https://openalex.org/C160892712","wikidata":"https://www.wikidata.org/wiki/Q901559","display_name":"Fourier transform infrared spectroscopy","level":2,"score":0.49151644110679626},{"id":"https://openalex.org/C2781285689","wikidata":"https://www.wikidata.org/wiki/Q21921428","display_name":"Crystal (programming language)","level":2,"score":0.48427098989486694},{"id":"https://openalex.org/C148898269","wikidata":"https://www.wikidata.org/wiki/Q1108792","display_name":"Kinetics","level":2,"score":0.4729209542274475},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.45378491282463074},{"id":"https://openalex.org/C29705727","wikidata":"https://www.wikidata.org/wiki/Q294562","display_name":"Polar","level":2,"score":0.4153374135494232},{"id":"https://openalex.org/C159467904","wikidata":"https://www.wikidata.org/wiki/Q2001702","display_name":"Chemical physics","level":1,"score":0.3411129415035248},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.3053179383277893},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.30357596278190613},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.0},{"id":"https://openalex.org/C199360897","wikidata":"https://www.wikidata.org/wiki/Q9143","display_name":"Programming language","level":1,"score":0.0},{"id":"https://openalex.org/C1276947","wikidata":"https://www.wikidata.org/wiki/Q333","display_name":"Astronomy","level":1,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1021/cg500441g","doi":"https://doi.org/10.1021/cg500441g","is_oa":false,"landing_page_url":"https://doi.org/10.1021/cg500441g","pdf_url":null,"source":{"id":"https://openalex.org/S16561315","display_name":"Crystal Growth & Design","issn_l":"1528-7483","issn":["1528-7483","1528-7505"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-2","norway-2","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Crystal Growth & Design","raw_type":"journal-article"},{"id":"pmh:oai:pure.atira.dk:openaire_cris_publications/9423a9de-4c1c-4a19-b869-dafe7c23fc3c","doi":null,"is_oa":false,"landing_page_url":"https://research.manchester.ac.uk/en/publications/9423a9de-4c1c-4a19-b869-dafe7c23fc3c","pdf_url":null,"source":{"id":"https://openalex.org/S4306400662","display_name":"Research Explorer (The University of Manchester)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I28407311","host_organization_name":"University of Manchester","host_organization_lineage":["https://openalex.org/I28407311"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Sullivan, R A, Davey, R J, Sadiq, G, Dent, G, Back, K R, Ter Horst, J H, Toroz, D & Hammond, R B 2014, 'Revealing the Roles of Desolvation and Molecular Self-Assembly in Crystal Nucleation from Solution: Benzoic and p\u2011Aminobenzoic Acids', Crystal Growth & Design, vol. 14, pp. 2689-2696. https://doi.org/10.1021/cg500441g","raw_type":"info:eu-repo/semantics/article"},{"id":"pmh:oai:eprints.whiterose.ac.uk:95548","doi":null,"is_oa":false,"landing_page_url":"http://eprints.whiterose.ac.uk/95548/1/DAVEYnucleationrevised.pdf","pdf_url":"http://eprints.whiterose.ac.uk/95548/1/DAVEYnucleationrevised.pdf","source":{"id":"https://openalex.org/S4306400854","display_name":"White Rose Research Online (University of Leeds, The University of Sheffield, University of York)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I2800616092","host_organization_name":"White Rose University Consortium","host_organization_lineage":["https://openalex.org/I2800616092"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":"","raw_type":"Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G1124720705","display_name":"Molecules, Clusters and Crystals: A Multi-Scale Approach to Understanding Kinetic Pathways in Crystal Nucleation from Solution","funder_award_id":"EP/I014446/1","funder_id":"https://openalex.org/F4320334627","funder_display_name":"Engineering and Physical Sciences Research Council"},{"id":"https://openalex.org/G8588629313","display_name":"Molecules, Clusters and Crystals: A Multi-Scale Approach to Understanding Kinetic Pathways in Crystal Nucleation from Solution","funder_award_id":"EP/I013563/1","funder_id":"https://openalex.org/F4320334627","funder_display_name":"Engineering and Physical Sciences Research Council"}],"funders":[{"id":"https://openalex.org/F4320334627","display_name":"Engineering and Physical Sciences Research Council","ror":"https://ror.org/0439y7842"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":25,"referenced_works":["https://openalex.org/W159835482","https://openalex.org/W648579614","https://openalex.org/W657034874","https://openalex.org/W1966078827","https://openalex.org/W1992169482","https://openalex.org/W2002230489","https://openalex.org/W2015688756","https://openalex.org/W2026830836","https://openalex.org/W2039856556","https://openalex.org/W2047602104","https://openalex.org/W2050457332","https://openalex.org/W2067813084","https://openalex.org/W2072066722","https://openalex.org/W2082023338","https://openalex.org/W2087668916","https://openalex.org/W2095291831","https://openalex.org/W2098432400","https://openalex.org/W2132030635","https://openalex.org/W2139418150","https://openalex.org/W2147993766","https://openalex.org/W2315422088","https://openalex.org/W2318525946","https://openalex.org/W2327825876","https://openalex.org/W2333565023","https://openalex.org/W2609724571"],"related_works":["https://openalex.org/W2987193514","https://openalex.org/W2973779242","https://openalex.org/W2286511819","https://openalex.org/W4394876826","https://openalex.org/W1458880409","https://openalex.org/W3111673670","https://openalex.org/W1983271536","https://openalex.org/W2064700231","https://openalex.org/W2521578385","https://openalex.org/W1992169482"],"abstract_inverted_index":{"There":[0],"has":[1,68],"been":[2,69],"much":[3],"recent":[4],"interest":[5],"in":[6,13,20,40,48,59,125],"the":[7,15,21,34,44,49,65,73,80,126],"role":[8],"of":[9,17,23,36,75,86],"solution":[10,66,87],"chemistry":[11],"and":[12,30,91,106,112,117],"particular":[14],"importance":[16],"molecular":[18],"self-assembly":[19],"nucleation":[22,94,128],"crystalline":[24],"phases.":[25],"Techniques":[26],"such":[27,97],"as":[28],"FTIR":[29],"NMR":[31],"have":[32],"highlighted":[33],"existence":[35],"solution-phase":[37],"dimers":[38],"which":[39,60],"many":[41],"cases":[42],"mirror":[43],"structural":[45],"synthons":[46],"found":[47,120],"resulting":[50],"macroscopic":[51],"crystals.":[52],"However,":[53],"there":[54],"are":[55,119],"no":[56],"reported":[57],"examples":[58],"this":[61],"new":[62],"insight":[63],"into":[64],"phase":[67],"linked":[70],"directly":[71],"to":[72,121],"kinetics":[74],"crystal":[76,93],"nucleation.":[77],"Here":[78],"for":[79,102],"first":[81],"time,":[82],"using":[83],"a":[84,98],"combination":[85],"FTIR,":[88],"computational":[89],"chemistry,":[90],"measured":[92],"rate":[95],"data,":[96],"link":[99],"is":[100],"demonstrated":[101],"p":[103],"-aminobenzoic":[104],"(PABA)":[105],"benzoic":[107],"acids":[108],"nucleating":[109],"from":[110],"polar":[111],"nonpolar":[113],"solvents.":[114],"Solute":[115],"dimerization":[116],"desolvation":[118],"be":[122],"rate-determining":[123],"processes":[124],"overall":[127],"pathway.":[129]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2025,"cited_by_count":4},{"year":2024,"cited_by_count":11},{"year":2023,"cited_by_count":5},{"year":2022,"cited_by_count":8},{"year":2021,"cited_by_count":18},{"year":2020,"cited_by_count":11},{"year":2019,"cited_by_count":14},{"year":2018,"cited_by_count":15},{"year":2017,"cited_by_count":13},{"year":2016,"cited_by_count":7},{"year":2015,"cited_by_count":13},{"year":2014,"cited_by_count":2}],"updated_date":"2026-11-08T12:12:28.789561","created_date":"2016-06-24T00:00:00"}