{"id":"https://openalex.org/W1978405039","doi":"https://doi.org/10.1081/sim-100107212","title":"MECHANISTIC INVESTIGATIONS OF THE OXIDATION OF SUBSTITUTED PHENETHYL ALCOHOLS BY MANGANESE(III) SULFATE CATALYZED BY RUTHENIUM(III) IN ACID SOLUTION","display_name":"MECHANISTIC INVESTIGATIONS OF THE OXIDATION OF SUBSTITUTED PHENETHYL ALCOHOLS BY MANGANESE(III) SULFATE CATALYZED BY RUTHENIUM(III) IN ACID SOLUTION","publication_year":2001,"publication_date":"2001-09-30","ids":{"openalex":"https://openalex.org/W1978405039","doi":"https://doi.org/10.1081/sim-100107212","mag":"1978405039"},"language":"en","primary_location":{"id":"doi:10.1081/sim-100107212","doi":"https://doi.org/10.1081/sim-100107212","is_oa":false,"landing_page_url":"https://doi.org/10.1081/sim-100107212","pdf_url":null,"source":{"id":"https://openalex.org/S4210171602","display_name":"Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry","issn_l":"0094-5714","issn":["0094-5714","1532-2440"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320547","host_organization_name":"Taylor & Francis","host_organization_lineage":["https://openalex.org/P4310320547","https://openalex.org/P4310320449"],"host_organization_lineage_names":["Taylor & Francis","Informa"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5073028598","display_name":"Kanchugarakoppal Subbegowda Rangappa","orcid":"https://orcid.org/0000-0003-0572-6305","observed_orcids":["https://orcid.org/0000-0003-0572-6305"]},"institutions":[{"id":"https://openalex.org/I204743663","display_name":"University of Mysore","ror":"https://ror.org/012bxv356","country_code":"IN","type":"education","lineage":["https://openalex.org/I204743663"]}],"countries":["IN"],"is_corresponding":true,"raw_author_name":"K. S. Rangappa","raw_affiliation_strings":["a   Department of Studies in Chemistry , University of Mysore , Manasagangothri, Mysore, 570 006,  India","Department of Studies in Chemistry , University of Mysore , Manasagangothri, Mysore, 570 006, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"a   Department of Studies in Chemistry , University of Mysore , Manasagangothri, Mysore, 570 006,  India","institution_ids":["https://openalex.org/I204743663"]},{"raw_affiliation_string":"Department of Studies in Chemistry , University of Mysore , Manasagangothri, Mysore, 570 006, India","institution_ids":["https://openalex.org/I204743663"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5101398592","display_name":"N. Anitha","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I204743663","display_name":"University of Mysore","ror":"https://ror.org/012bxv356","country_code":"IN","type":"education","lineage":["https://openalex.org/I204743663"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"N. Anitha","raw_affiliation_strings":["a   Department of Studies in Chemistry , University of Mysore , Manasagangothri, Mysore, 570 006,  India","Department of Studies in Chemistry , University of Mysore , Manasagangothri, Mysore, 570 006, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"a   Department of Studies in Chemistry , University of Mysore , Manasagangothri, Mysore, 570 006,  India","institution_ids":["https://openalex.org/I204743663"]},{"raw_affiliation_string":"Department of Studies in Chemistry , University of Mysore , Manasagangothri, Mysore, 570 006, India","institution_ids":["https://openalex.org/I204743663"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5113589166","display_name":"N. M. Made Gowda","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I117942362","display_name":"Western Illinois University","ror":"https://ror.org/02sshz518","country_code":"US","type":"education","lineage":["https://openalex.org/I117942362"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"N. M. Made Gowda","raw_affiliation_strings":["b   Department of Chemistry , Western Illinois University , 1 University Circle, Macomb, Illinois, 61455,  U.S.A","Department of Chemistry , Western Illinois University , 1 University Circle, Macomb, Illinois, 61455, U.S.A"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"b   Department of Chemistry , Western Illinois University , 1 University Circle, Macomb, Illinois, 61455,  U.S.A","institution_ids":["https://openalex.org/I117942362"]},{"raw_affiliation_string":"Department of Chemistry , Western Illinois University , 1 University Circle, Macomb, Illinois, 61455, U.S.A","institution_ids":["https://openalex.org/I117942362"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5073028598","https://openalex.org/A5113589166"],"corresponding_institution_ids":["https://openalex.org/I117942362","https://openalex.org/I204743663"],"apc_list":null,"apc_paid":null,"fwci":0.2576,"has_fulltext":false,"cited_by_count":17,"citation_normalized_percentile":{"value":0.48577245,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":87,"max":97},"biblio":{"volume":"31","issue":"8","first_page":"1499","last_page":"1518"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11989","display_name":"Oxidative Organic Chemistry Reactions","score":0.5464000105857849,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11989","display_name":"Oxidative Organic Chemistry Reactions","score":0.5464000105857849,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12191","display_name":"Physical Organic Chemistry and Reaction Kinetics","score":0.2964000105857849,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.09109999984502792,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/ruthenium-iii-catalysis","display_name":"ruthenium(III) catalysis","score":0.9950000047683716},{"id":"https://openalex.org/keywords/reaction-kinetics","display_name":"reaction kinetics","score":0.5669999718666077},{"id":"https://openalex.org/keywords/michaelis-menten-kinetics","display_name":"Michaelis-Menten kinetics","score":0.9480000138282776},{"id":"https://openalex.org/keywords/hammett-acidity-function","display_name":"Hammett acidity function","score":0.9539999961853027},{"id":"https://openalex.org/keywords/solvent-isotope-effect","display_name":"solvent isotope effect","score":0.847000002861023},{"id":"https://openalex.org/keywords/proton-inventory","display_name":"proton inventory","score":0.7720000147819519},{"id":"https://openalex.org/keywords/linear-free-energy-relationships","display_name":"linear free energy relationships","score":0.7390000224113464},{"id":"https://openalex.org/keywords/activation-parameters","display_name":"activation parameters","score":0.8130000233650208},{"id":"https://openalex.org/keywords/reaction-mechanism","display_name":"reaction mechanism","score":0.6890000104904175},{"id":"https://openalex.org/keywords/substituted-phenols","display_name":"substituted phenols","score":0.45500001311302185},{"id":"https://openalex.org/keywords/acid-catalysis","display_name":"acid catalysis","score":0.6240000128746033}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8566403388977051},{"id":"https://openalex.org/C528890316","wikidata":"https://www.wikidata.org/wiki/Q731","display_name":"Manganese","level":2,"score":0.7326579093933105},{"id":"https://openalex.org/C187428577","wikidata":"https://www.wikidata.org/wiki/Q898396","display_name":"Ionic strength","level":3,"score":0.6738348007202148},{"id":"https://openalex.org/C2778199549","wikidata":"https://www.wikidata.org/wiki/Q4118","display_name":"Sulfuric acid","level":2,"score":0.6472240090370178},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.6201587319374084},{"id":"https://openalex.org/C93391505","wikidata":"https://www.wikidata.org/wiki/Q658700","display_name":"Reaction rate constant","level":3,"score":0.6074680685997009},{"id":"https://openalex.org/C128122844","wikidata":"https://www.wikidata.org/wiki/Q4119007","display_name":"Free-energy relationship","level":4,"score":0.5721625685691833},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.5703762173652649},{"id":"https://openalex.org/C69928629","wikidata":"https://www.wikidata.org/wiki/Q1386472","display_name":"Kinetic isotope effect","level":3,"score":0.56989985704422},{"id":"https://openalex.org/C148898269","wikidata":"https://www.wikidata.org/wiki/Q1108792","display_name":"Kinetics","level":2,"score":0.5657050609588623},{"id":"https://openalex.org/C555196967","wikidata":"https://www.wikidata.org/wiki/Q1086","display_name":"Ruthenium","level":3,"score":0.563213050365448},{"id":"https://openalex.org/C2778343803","wikidata":"https://www.wikidata.org/wiki/Q172290","display_name":"Sulfate","level":2,"score":0.5195539593696594},{"id":"https://openalex.org/C190463131","wikidata":"https://www.wikidata.org/wiki/Q249087","display_name":"Rate-determining step","level":3,"score":0.4841381013393402},{"id":"https://openalex.org/C2780471494","wikidata":"https://www.wikidata.org/wiki/Q146505","display_name":"Solvent","level":2,"score":0.42944854497909546},{"id":"https://openalex.org/C95121573","wikidata":"https://www.wikidata.org/wiki/Q190474","display_name":"Activation energy","level":2,"score":0.41855695843696594},{"id":"https://openalex.org/C111163200","wikidata":"https://www.wikidata.org/wiki/Q904041","display_name":"Rate equation","level":3,"score":0.41533857583999634},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.36895665526390076},{"id":"https://openalex.org/C184651966","wikidata":"https://www.wikidata.org/wiki/Q906356","display_name":"Aqueous solution","level":2,"score":0.31718289852142334},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.30135422945022583},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.17771005630493164},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C58364064","wikidata":"https://www.wikidata.org/wiki/Q102296","display_name":"Deuterium","level":2,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1081/sim-100107212","doi":"https://doi.org/10.1081/sim-100107212","is_oa":false,"landing_page_url":"https://doi.org/10.1081/sim-100107212","pdf_url":null,"source":{"id":"https://openalex.org/S4210171602","display_name":"Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry","issn_l":"0094-5714","issn":["0094-5714","1532-2440"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320547","host_organization_name":"Taylor & Francis","host_organization_lineage":["https://openalex.org/P4310320547","https://openalex.org/P4310320449"],"host_organization_lineage_names":["Taylor & Francis","Informa"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":25,"referenced_works":["https://openalex.org/W561167150","https://openalex.org/W599008557","https://openalex.org/W1555323004","https://openalex.org/W1977290741","https://openalex.org/W1977448165","https://openalex.org/W1981683402","https://openalex.org/W1997928225","https://openalex.org/W1998647097","https://openalex.org/W2016628473","https://openalex.org/W2022146067","https://openalex.org/W2037357303","https://openalex.org/W2049744344","https://openalex.org/W2051057697","https://openalex.org/W2061340048","https://openalex.org/W2078205999","https://openalex.org/W2087868165","https://openalex.org/W2089206549","https://openalex.org/W2089955620","https://openalex.org/W2110556134","https://openalex.org/W2255283361","https://openalex.org/W2256662714","https://openalex.org/W2276249230","https://openalex.org/W2327012774","https://openalex.org/W2951237807","https://openalex.org/W2997641574"],"related_works":["https://openalex.org/W2460671269","https://openalex.org/W7020014591","https://openalex.org/W1941664960","https://openalex.org/W2281712684","https://openalex.org/W153946740","https://openalex.org/W1570211085","https://openalex.org/W2051311355","https://openalex.org/W2075109882","https://openalex.org/W2736512078","https://openalex.org/W1590353263"],"abstract_inverted_index":{"The":[0,38,54,122],"kinetics":[1,48,165],"of":[2,7,10,57,72,82,91,102],"the":[3,52,70,73,80,87,92,96,100,103,120,146,163],"Ru(III)":[4],"catalysed":[5],"oxidation":[6],"six":[8],"derivatives":[9],"phenethyl":[11],"alcohol":[12],"(X-C6H4-CH2CH2OH":[13],"where":[14],"X\u2550H,":[15],"Cl,":[16],"Br,":[17],"CH3,":[18],"OCH3":[19],"or":[20],"NO2)":[21],"by":[22,75,150],"manganese(III)":[23],"sulfate,":[24],"in":[25,59,86,135],"sulfuric":[26],"acid":[27],"solution":[28],"at":[29,34],"30\u00b0C,":[30],"were":[31,133,148,157],"followed":[32],"spectrophotometrically":[33],"\u03bbmax":[35],"=500":[36],"nm.":[37],"rate":[39,55,74],"shows":[40],"a":[41],"first-order":[42],"dependence":[43],"on":[44,119],"[Mn(III)]":[45],"and":[46,95,99,107,114,152],"Michaelis-Menten":[47],"was":[49,56,128,143],"observed":[50,144,164],"with":[51,162],"substrate.":[53],"fractional-order":[58],"[Ru(III)].":[60],"Hammett":[61,151],"acidity":[62],"function":[63],"(\u2500H0)":[64],"has":[65,166],"been":[66,167],"invoked":[67],"to":[68],"explain":[69],"retardation":[71],"acid.":[76],"Bunnett":[77],"plots":[78],"indicated":[79],"absence":[81],"water":[83],"molecule":[84],"participation":[85],"rate-limiting":[88],"step.":[89],"Variation":[90],"ionic":[93],"strength":[94],"dielectric":[97],"constant":[98],"addition":[101],"reaction":[104],"product":[105],"Mn(II)":[106],"anions":[108],"such":[109],"as":[110],"C1\u2212,":[111],"SO2+":[112],"4,":[113],"F\u2212":[115],"have":[116],"no":[117],"effect":[118,125],"rate.":[121],"solvent":[123],"isotope":[124],"k(H2O)/k(D2O)":[126],"=1.38":[127],"observed.":[129],"Proton":[130],"inventory":[131],"studies":[132],"made":[134],"H2O-D2O":[136],"mixtures.":[137],"A":[138,159],"linear":[139],"free":[140],"energy":[141],"relationship":[142],"when":[145],"results":[147],"analyzed":[149],"Okamoto-Brown":[153],"equations.":[154],"Activation":[155],"parameters":[156],"computed.":[158],"mechanism":[160],"consistent":[161],"proposed.":[168]},"counts_by_year":[{"year":2024,"cited_by_count":1},{"year":2021,"cited_by_count":1},{"year":2020,"cited_by_count":1},{"year":2019,"cited_by_count":1},{"year":2017,"cited_by_count":1},{"year":2014,"cited_by_count":1},{"year":2012,"cited_by_count":3}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2016-06-24T00:00:00"}
