{"id":"https://openalex.org/W1978341437","doi":"https://doi.org/10.1021/jp001539m","title":"Photoinduced Electron Transfer in an Oligodeoxynucleotide Duplex: Observation of the Electron-Transfer Intermediate","display_name":"Photoinduced Electron Transfer in an Oligodeoxynucleotide Duplex: Observation of the Electron-Transfer Intermediate","publication_year":2000,"publication_date":"2000-07-19","ids":{"openalex":"https://openalex.org/W1978341437","doi":"https://doi.org/10.1021/jp001539m","mag":"1978341437"},"language":"en","primary_location":{"id":"doi:10.1021/jp001539m","doi":"https://doi.org/10.1021/jp001539m","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jp001539m","pdf_url":null,"source":{"id":"https://openalex.org/S185621672","display_name":"The Journal of Physical Chemistry B","issn_l":"1520-5207","issn":["1520-5207","1520-6106"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","ki-jl-1","medline","norway-1","poland-140","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry B","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5035599834","display_name":"Mark T. Tierney","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I170897317","display_name":"Duke University","ror":"https://ror.org/00py81415","country_code":"US","type":"education","lineage":["https://openalex.org/I170897317"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Mark T. Tierney","raw_affiliation_strings":["Department of Chemistry, Paul M. Gross Chemical Laboratory, Duke University, Durham, North Carolina 27708"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Paul M. Gross Chemical Laboratory, Duke University, Durham, North Carolina 27708","institution_ids":["https://openalex.org/I170897317"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5103268601","display_name":"Milan S\u00fdkora","orcid":"https://orcid.org/0000-0002-1747-0709","observed_orcids":["https://orcid.org/0000-0002-1747-0709"]},"institutions":[{"id":"https://openalex.org/I170897317","display_name":"Duke University","ror":"https://ror.org/00py81415","country_code":"US","type":"education","lineage":["https://openalex.org/I170897317"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Milan Sykora","raw_affiliation_strings":["Department of Chemistry, Paul M. Gross Chemical Laboratory, Duke University, Durham, North Carolina 27708"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Paul M. Gross Chemical Laboratory, Duke University, Durham, North Carolina 27708","institution_ids":["https://openalex.org/I170897317"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5113534574","display_name":"Shoeb I. Khan","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I170897317","display_name":"Duke University","ror":"https://ror.org/00py81415","country_code":"US","type":"education","lineage":["https://openalex.org/I170897317"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Shoeb I. Khan","raw_affiliation_strings":["Department of Chemistry, Paul M. Gross Chemical Laboratory, Duke University, Durham, North Carolina 27708"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Paul M. Gross Chemical Laboratory, Duke University, Durham, North Carolina 27708","institution_ids":["https://openalex.org/I170897317"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5001975624","display_name":"Mark W. Grinstaff","orcid":"https://orcid.org/0000-0002-5453-3668","observed_orcids":["https://orcid.org/0000-0002-5453-3668"]},"institutions":[{"id":"https://openalex.org/I170897317","display_name":"Duke University","ror":"https://ror.org/00py81415","country_code":"US","type":"education","lineage":["https://openalex.org/I170897317"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Mark W. Grinstaff","raw_affiliation_strings":["Department of Chemistry, Paul M. Gross Chemical Laboratory, Duke University, Durham, North Carolina 27708"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Paul M. Gross Chemical Laboratory, Duke University, Durham, North Carolina 27708","institution_ids":["https://openalex.org/I170897317"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I170897317"],"apc_list":null,"apc_paid":null,"fwci":2.2752,"has_fulltext":false,"cited_by_count":35,"citation_normalized_percentile":{"value":0.85587364,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":98},"biblio":{"volume":"104","issue":"32","first_page":"7574","last_page":"7576"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11129","display_name":"Photochemistry and Electron Transfer Studies","score":0.9682999849319458,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11129","display_name":"Photochemistry and Electron Transfer Studies","score":0.9682999849319458,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10432","display_name":"DNA and Nucleic Acid Chemistry","score":0.020999999716877937,"subfield":{"id":"https://openalex.org/subfields/1312","display_name":"Molecular Biology"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}},{"id":"https://openalex.org/T10207","display_name":"Advanced biosensing and bioanalysis techniques","score":0.008999999612569809,"subfield":{"id":"https://openalex.org/subfields/1312","display_name":"Molecular Biology"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/photoinduced-electron-transfer","display_name":"photoinduced electron transfer","score":0.9990000128746033},{"id":"https://openalex.org/keywords/phenothiazines","display_name":"phenothiazines","score":0.9020000100135803},{"id":"https://openalex.org/keywords/electron-transfer-intermediates","display_name":"electron transfer intermediates","score":0.8980000019073486},{"id":"https://openalex.org/keywords/back-electron-transfer","display_name":"back electron transfer","score":0.753000020980835},{"id":"https://openalex.org/keywords/transient-absorption-spectroscopy","display_name":"transient absorption spectroscopy","score":0.7049999833106995},{"id":"https://openalex.org/keywords/electron-transfer-kinetics","display_name":"electron transfer kinetics","score":0.6010000109672546}],"concepts":[{"id":"https://openalex.org/C123669783","wikidata":"https://www.wikidata.org/wiki/Q902898","display_name":"Electron transfer","level":2,"score":0.7964010238647461},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.741660475730896},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.7217998504638672},{"id":"https://openalex.org/C95503338","wikidata":"https://www.wikidata.org/wiki/Q186105","display_name":"Ultrafast laser spectroscopy","level":3,"score":0.6974340677261353},{"id":"https://openalex.org/C2781018080","wikidata":"https://www.wikidata.org/wiki/Q7187813","display_name":"Photoinduced electron transfer","level":3,"score":0.6629933714866638},{"id":"https://openalex.org/C2900893","wikidata":"https://www.wikidata.org/wiki/Q1231592","display_name":"Electron acceptor","level":2,"score":0.5813731551170349},{"id":"https://openalex.org/C180577832","wikidata":"https://www.wikidata.org/wiki/Q127920","display_name":"Covalent bond","level":2,"score":0.5775498151779175},{"id":"https://openalex.org/C192468462","wikidata":"https://www.wikidata.org/wiki/Q533543","display_name":"Chromophore","level":2,"score":0.517057478427887},{"id":"https://openalex.org/C2778148179","wikidata":"https://www.wikidata.org/wiki/Q911571","display_name":"Electron donor","level":3,"score":0.4649476110935211},{"id":"https://openalex.org/C32891209","wikidata":"https://www.wikidata.org/wiki/Q483666","display_name":"Spectroscopy","level":2,"score":0.43061894178390503},{"id":"https://openalex.org/C119824511","wikidata":"https://www.wikidata.org/wiki/Q13553575","display_name":"Absorption spectroscopy","level":2,"score":0.4206867516040802},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.10363534092903137},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.07680973410606384},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/jp001539m","doi":"https://doi.org/10.1021/jp001539m","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jp001539m","pdf_url":null,"source":{"id":"https://openalex.org/S185621672","display_name":"The Journal of Physical Chemistry B","issn_l":"1520-5207","issn":["1520-5207","1520-6106"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","ki-jl-1","medline","norway-1","poland-140","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry B","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":33,"referenced_works":["https://openalex.org/W1611836266","https://openalex.org/W1676620288","https://openalex.org/W1964311884","https://openalex.org/W1971499243","https://openalex.org/W1975464372","https://openalex.org/W1975532341","https://openalex.org/W1977184994","https://openalex.org/W1991072674","https://openalex.org/W1995191154","https://openalex.org/W1999264620","https://openalex.org/W2001287959","https://openalex.org/W2006130370","https://openalex.org/W2007008105","https://openalex.org/W2012970572","https://openalex.org/W2018433273","https://openalex.org/W2036447850","https://openalex.org/W2036675006","https://openalex.org/W2037066176","https://openalex.org/W2038434811","https://openalex.org/W2043733885","https://openalex.org/W2045123737","https://openalex.org/W2058878291","https://openalex.org/W2067054519","https://openalex.org/W2073126970","https://openalex.org/W2075570601","https://openalex.org/W2085795760","https://openalex.org/W2093821031","https://openalex.org/W2131128533","https://openalex.org/W2133667940","https://openalex.org/W2135186262","https://openalex.org/W2165337540","https://openalex.org/W2166723844","https://openalex.org/W2952076861"],"related_works":["https://openalex.org/W2502731663","https://openalex.org/W2149381426","https://openalex.org/W2033504051","https://openalex.org/W2903599787","https://openalex.org/W2021391133","https://openalex.org/W1966005088","https://openalex.org/W2058695452","https://openalex.org/W7070827319","https://openalex.org/W3027384849","https://openalex.org/W2321224848"],"abstract_inverted_index":{"Kinetics":[0],"of":[1,43,60,81,93,119],"a":[2,24,58],"photoinduced":[3],"electron-transfer":[4,84,96,121],"reaction":[5,97],"between":[6,66],"phenothiazine":[7],"(PTZ)":[8],"and":[9,17,47,70,78],"Ru(bpy)":[10,50],"2":[11,51,74],"(4-m-4\u2018-pa-bpy)":[12,52,75],"2+":[13],"[bpy":[14],"=":[15,19,101],"2,2\u2018-bipyridine":[16],"4-m-4\u2018-pa-bpy":[18],"4-methyl-4\u2018-carbonylpropargylamine]":[20],"covalently":[21,55],"bound":[22],"to":[23,39,57],"DNA":[25],"duplex":[26],"is":[27,37,54,89,113],"investigated":[28],"by":[29,115,126],"transient":[30,127],"absorption":[31,128],"spectroscopy.":[32,129],"The":[33,91],"electron":[34],"donor,":[35,68],"PTZ,":[36,69],"attached":[38],"the":[40,48,61,67,79,82,94,117,120],"5\u2018":[41],"terminal":[42],"one":[44],"oligodeoxynucleotide":[45],"strand,":[46],"chromophore,":[49],"2+,":[53,76],"linked":[56],"uridine":[59],"complementary":[62],"strand.":[63],"Electron":[64],"transfer":[65],"photoexcited":[71],"acceptor,":[72],"*Ru(bpy)":[73],"occurs,":[77],"product":[80],"forward":[83],"reaction,":[85],"PTZ":[86,123],"+":[87,124],"\u2022,":[88,125],"observed.":[90],"rate":[92],"back":[95],"(":[98],"k":[99],"b":[100],"3.94":[102],"\u00d7":[103],"10":[104],"6":[105],"s":[106],"-1;":[107],"\u0394":[108],"G":[109],"\u223c":[110],"2.0":[111],"eV)":[112],"determined":[114],"monitoring":[116],"decay":[118],"intermediate,":[122]},"counts_by_year":[{"year":2022,"cited_by_count":1},{"year":2020,"cited_by_count":1},{"year":2014,"cited_by_count":3},{"year":2012,"cited_by_count":5}],"updated_date":"2026-08-21T09:56:20.448147","created_date":"2016-06-24T00:00:00"}