{"id":"https://openalex.org/W1978257308","doi":"https://doi.org/10.1002/polc.5070230206","title":"Solution properties of chlorinated stereoregular polybutadienes","display_name":"Solution properties of chlorinated stereoregular polybutadienes","publication_year":1968,"publication_date":"1968-01-01","ids":{"openalex":"https://openalex.org/W1978257308","doi":"https://doi.org/10.1002/polc.5070230206","mag":"1978257308"},"language":"en","primary_location":{"id":"doi:10.1002/polc.5070230206","doi":"https://doi.org/10.1002/polc.5070230206","is_oa":false,"landing_page_url":"https://doi.org/10.1002/polc.5070230206","pdf_url":null,"source":{"id":"https://openalex.org/S182186474","display_name":"Journal of Polymer Science Part C Polymer Symposia","issn_l":"0449-2994","issn":["0449-2994","1935-3065"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Polymer Science Part C: Polymer Symposia","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5113574554","display_name":"Masatami Takeda","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I161296585","display_name":"Tokyo University of Science","ror":"https://ror.org/05sj3n476","country_code":"JP","type":"education","lineage":["https://openalex.org/I161296585"]},{"id":"https://openalex.org/I4405286007","display_name":"Tokyo College, The University of Tokyo","ror":"https://ror.org/00xmnd177","country_code":"JP","type":"facility","lineage":["https://openalex.org/I4405286007","https://openalex.org/I74801974"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Masatami Takeda","raw_affiliation_strings":["Department of Chemistry, Tokyo College of Science, Kagurazaka, Shinjuku-ku, Tokyo, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Tokyo College of Science, Kagurazaka, Shinjuku-ku, Tokyo, Japan","institution_ids":["https://openalex.org/I161296585","https://openalex.org/I4405286007"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5110160414","display_name":"Ry\u016bichi End\u00f5","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I161296585","display_name":"Tokyo University of Science","ror":"https://ror.org/05sj3n476","country_code":"JP","type":"education","lineage":["https://openalex.org/I161296585"]},{"id":"https://openalex.org/I4405286007","display_name":"Tokyo College, The University of Tokyo","ror":"https://ror.org/00xmnd177","country_code":"JP","type":"facility","lineage":["https://openalex.org/I4405286007","https://openalex.org/I74801974"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Ry\u016bichi End\u00f5","raw_affiliation_strings":["Department of Chemistry, Tokyo College of Science, Kagurazaka, Shinjuku-ku, Tokyo, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Tokyo College of Science, Kagurazaka, Shinjuku-ku, Tokyo, Japan","institution_ids":["https://openalex.org/I161296585","https://openalex.org/I4405286007"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5066438019","display_name":"Yoshikatsu Matsuura","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I161296585","display_name":"Tokyo University of Science","ror":"https://ror.org/05sj3n476","country_code":"JP","type":"education","lineage":["https://openalex.org/I161296585"]},{"id":"https://openalex.org/I4405286007","display_name":"Tokyo College, The University of Tokyo","ror":"https://ror.org/00xmnd177","country_code":"JP","type":"facility","lineage":["https://openalex.org/I4405286007","https://openalex.org/I74801974"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Yoshikatsu Matsuura","raw_affiliation_strings":["Department of Chemistry, Tokyo College of Science, Kagurazaka, Shinjuku-ku, Tokyo, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Tokyo College of Science, Kagurazaka, Shinjuku-ku, Tokyo, Japan","institution_ids":["https://openalex.org/I161296585","https://openalex.org/I4405286007"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":13,"citation_normalized_percentile":{"value":0.0,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":93},"biblio":{"volume":"23","issue":"2","first_page":"487","last_page":"498"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11379","display_name":"Rheology and Fluid Dynamics Studies","score":0.2736999988555908,"subfield":{"id":"https://openalex.org/subfields/1507","display_name":"Fluid Flow and Transfer Processes"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11379","display_name":"Rheology and Fluid Dynamics Studies","score":0.2736999988555908,"subfield":{"id":"https://openalex.org/subfields/1507","display_name":"Fluid Flow and Transfer Processes"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.22920000553131104,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T14303","display_name":"Polymer Synthesis and Characterization","score":0.22169999778270721,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/cis-1-4-polybutadiene","display_name":"cis-1,4-polybutadiene","score":0.9890000224113464},{"id":"https://openalex.org/keywords/trans-1-4-polybutadiene","display_name":"trans-1,4-polybutadiene","score":1.0},{"id":"https://openalex.org/keywords/intrinsic-viscosity","display_name":"intrinsic viscosity","score":0.6150000095367432},{"id":"https://openalex.org/keywords/molecular-weight-dependence","display_name":"molecular weight dependence","score":0.7179999947547913},{"id":"https://openalex.org/keywords/light-scattering","display_name":"light scattering","score":0.5920000076293945},{"id":"https://openalex.org/keywords/end-to-end-distance","display_name":"end-to-end distance","score":0.8299999833106995},{"id":"https://openalex.org/keywords/polymer-conformation","display_name":"chain conformation","score":0.8149999976158142},{"id":"https://openalex.org/keywords/conformational-parameters","display_name":"conformational parameters","score":0.7870000004768372},{"id":"https://openalex.org/keywords/conformers","display_name":"conformational isomers","score":0.7429999709129333}],"concepts":[{"id":"https://openalex.org/C2776701986","wikidata":"https://www.wikidata.org/wiki/Q278332","display_name":"Tetrahydrofuran","level":3,"score":0.7496917247772217},{"id":"https://openalex.org/C26360006","wikidata":"https://www.wikidata.org/wiki/Q2804680","display_name":"Intrinsic viscosity","level":3,"score":0.6855930685997009},{"id":"https://openalex.org/C2781144210","wikidata":"https://www.wikidata.org/wiki/Q172275","display_name":"Chloroform","level":2,"score":0.6505522727966309},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6393651366233826},{"id":"https://openalex.org/C2779607525","wikidata":"https://www.wikidata.org/wiki/Q14982","display_name":"Methanol","level":2,"score":0.5073642134666443},{"id":"https://openalex.org/C93218973","wikidata":"https://www.wikidata.org/wiki/Q7934790","display_name":"Virial coefficient","level":2,"score":0.5024111270904541},{"id":"https://openalex.org/C127172972","wikidata":"https://www.wikidata.org/wiki/Q128709","display_name":"Viscosity","level":2,"score":0.4725242257118225},{"id":"https://openalex.org/C113196181","wikidata":"https://www.wikidata.org/wiki/Q485223","display_name":"Analytical Chemistry (journal)","level":2,"score":0.4477703869342804},{"id":"https://openalex.org/C2780901341","wikidata":"https://www.wikidata.org/wiki/Q143668","display_name":"Polybutadiene","level":4,"score":0.41251420974731445},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.3511698246002197},{"id":"https://openalex.org/C2780471494","wikidata":"https://www.wikidata.org/wiki/Q146505","display_name":"Solvent","level":2,"score":0.2465815544128418},{"id":"https://openalex.org/C43617362","wikidata":"https://www.wikidata.org/wiki/Q170050","display_name":"Chromatography","level":1,"score":0.21854928135871887},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.18463438749313354},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.12635934352874756},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.08178848028182983},{"id":"https://openalex.org/C15920480","wikidata":"https://www.wikidata.org/wiki/Q421281","display_name":"Copolymer","level":3,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/polc.5070230206","doi":"https://doi.org/10.1002/polc.5070230206","is_oa":false,"landing_page_url":"https://doi.org/10.1002/polc.5070230206","pdf_url":null,"source":{"id":"https://openalex.org/S182186474","display_name":"Journal of Polymer Science Part C Polymer Symposia","issn_l":"0449-2994","issn":["0449-2994","1935-3065"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Polymer Science Part C: Polymer Symposia","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":8,"referenced_works":["https://openalex.org/W1824415929","https://openalex.org/W1980475823","https://openalex.org/W2000072619","https://openalex.org/W2003642531","https://openalex.org/W2024817415","https://openalex.org/W2041955341","https://openalex.org/W2099724549","https://openalex.org/W2331285563"],"related_works":["https://openalex.org/W2127494116","https://openalex.org/W2022951403","https://openalex.org/W1993115254","https://openalex.org/W2069818512","https://openalex.org/W1752229444","https://openalex.org/W1484414477","https://openalex.org/W2002325549","https://openalex.org/W1570949434","https://openalex.org/W2068147860","https://openalex.org/W3094228482"],"abstract_inverted_index":{"Abstract":[0],"Commercial":[1],"samples":[2,39],"of":[3,30,157,165],"cis\u20101,4\u2010polybutadiene":[4],"and":[5,17,32,73,95,115,145,162],"trans\u20101,4\u2010polybutadiene":[6],"have":[7],"been":[8],"chlorinated":[9,137,151],"with":[10,19,26,42,63,69,74],"chlorine":[11],"gas":[12],"in":[13,34,55,155,175],"a":[14,27,64,75,169],"chloroform":[15],"solution":[16],"precipitated":[18],"methanol.":[20],"The":[21,38,48,58,89,104,139],"precipitates":[22],"were":[23,40,51,61],"thoroughly":[24],"washed":[25],"large":[28],"amount":[29],"methanol":[31],"dried":[33],"vacuum":[35],"at":[36,46,53,86],"40\u00b0C.":[37,47],"fractionated":[41],"the":[43,79,92,96,112,120,142,146,158,172,176],"tetrahydrofuran\u2010water":[44],"system":[45],"viscosity":[49,94],"measurements":[50,60],"made":[52,62],"30\u00b0C.":[54],"various":[56],"solvents.":[57],"light\u2010scattering":[59,67],"modified":[65],"Brice\u2010type":[66],"photometer":[68],"unpolarized":[70],"blue":[71],"light":[72],"cylindrical":[76],"cell,":[77],"over":[78],"angular":[80],"range":[81],"from":[82],"35\u00b0":[83],"to":[84],"145\u00b0,":[85],"room":[87],"temperature.":[88],"relation":[90,140],"between":[91,141],"intrinsic":[93],"molecular":[97,160],"weight":[98],"was":[99,109,116,153],"obtained":[100],"for":[101,118,135,149,168],"each":[102,136,150],"sample.":[103,138],"unperturbed":[105,159],"mean\u2010square":[106],"end\u2010to\u2010end":[107],"distance":[108],"estimated":[110],"by":[111],"Stockmayer\u2010Fixman":[113],"equation,":[114],"used":[117],"calculating":[119],"conformational":[121],"parameter":[122],"\\documentclass{article}\\pagestyle{empty}\\begin{document}$":[123],"\\sigma":[124],"=":[125],"\\;(\\overline":[126],"{r_0":[127],"^2":[128,132],"}":[129],"/\\overline":[130],"{r_{0f}":[131],"})^{1/2}":[133],"$\\end{document}":[134],"chemical":[143],"configuration":[144],"chain":[147],"conformation":[148],"sample":[152],"discussed":[154],"terms":[156],"dimension":[161],"rotational":[163],"isomers":[164],"model":[166],"compounds":[167],"rotation":[170],"around":[171],"C\uf8ffC":[173],"bonds":[174],"main":[177],"chain.":[178]},"counts_by_year":[{"year":2025,"cited_by_count":1},{"year":2020,"cited_by_count":1},{"year":2015,"cited_by_count":1}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2016-06-24T00:00:00"}