{"id":"https://openalex.org/W1977280338","doi":"https://doi.org/10.1039/c3ra47040g","title":"Role of basic sites of substituted ferrocenes in interaction with the trinuclear 3,5-bis(trifluoromethyl)pyrazolates: thermodynamics and structure of complexes","display_name":"Role of basic sites of substituted ferrocenes in interaction with the trinuclear 3,5-bis(trifluoromethyl)pyrazolates: thermodynamics and structure of complexes","publication_year":2014,"publication_date":"2014-01-01","ids":{"openalex":"https://openalex.org/W1977280338","doi":"https://doi.org/10.1039/c3ra47040g","mag":"1977280338"},"language":"en","primary_location":{"id":"doi:10.1039/c3ra47040g","doi":"https://doi.org/10.1039/c3ra47040g","is_oa":false,"landing_page_url":"https://doi.org/10.1039/c3ra47040g","pdf_url":null,"source":{"id":"https://openalex.org/S2481244646","display_name":"RSC Advances","issn_l":"2046-2069","issn":["2046-2069"],"is_oa":false,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj","dongbi-c","jufo-1","ki-jl-1","norway-1","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"RSC Advances","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","doaj"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":null,"display_name":"Alexey A. Titov","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1313323035","display_name":"Russian Academy of Sciences","ror":"https://ror.org/05qrfxd25","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035"]},{"id":"https://openalex.org/I2802913842","display_name":"A. N. Nesmeyanov Institute of Organoelement Compounds","ror":"https://ror.org/03jzs4815","country_code":"RU","type":"facility","lineage":["https://openalex.org/I1313323035","https://openalex.org/I2802913842","https://openalex.org/I4210145551"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"Alexey A. Titov","raw_affiliation_strings":["A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov str. 28, 119991 Moscow, Russia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov str. 28, 119991 Moscow, Russia","institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I2802913842"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5004284214","display_name":"Oleg A. Filippov","orcid":"https://orcid.org/0000-0002-7963-2806","observed_orcids":["https://orcid.org/0000-0002-7963-2806"]},"institutions":[{"id":"https://openalex.org/I1313323035","display_name":"Russian Academy of Sciences","ror":"https://ror.org/05qrfxd25","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035"]},{"id":"https://openalex.org/I2802913842","display_name":"A. N. Nesmeyanov Institute of Organoelement Compounds","ror":"https://ror.org/03jzs4815","country_code":"RU","type":"facility","lineage":["https://openalex.org/I1313323035","https://openalex.org/I2802913842","https://openalex.org/I4210145551"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"Oleg A. Filippov","raw_affiliation_strings":["A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov str. 28, 119991 Moscow, Russia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov str. 28, 119991 Moscow, Russia","institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I2802913842"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5102408304","display_name":"Ekaterina A. Guseva","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1313323035","display_name":"Russian Academy of Sciences","ror":"https://ror.org/05qrfxd25","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035"]},{"id":"https://openalex.org/I2802913842","display_name":"A. N. Nesmeyanov Institute of Organoelement Compounds","ror":"https://ror.org/03jzs4815","country_code":"RU","type":"facility","lineage":["https://openalex.org/I1313323035","https://openalex.org/I2802913842","https://openalex.org/I4210145551"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"Ekaterina A. Guseva","raw_affiliation_strings":["A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov str. 28, 119991 Moscow, Russia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov str. 28, 119991 Moscow, Russia","institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I2802913842"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5046140968","display_name":"Alexander F. Smol\u2019yakov","orcid":"https://orcid.org/0000-0002-7228-7093","observed_orcids":["https://orcid.org/0000-0002-7228-7093"]},"institutions":[{"id":"https://openalex.org/I1313323035","display_name":"Russian Academy of Sciences","ror":"https://ror.org/05qrfxd25","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035"]},{"id":"https://openalex.org/I2802913842","display_name":"A. N. Nesmeyanov Institute of Organoelement Compounds","ror":"https://ror.org/03jzs4815","country_code":"RU","type":"facility","lineage":["https://openalex.org/I1313323035","https://openalex.org/I2802913842","https://openalex.org/I4210145551"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"Alexander F. Smol'yakov","raw_affiliation_strings":["A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov str. 28, 119991 Moscow, Russia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov str. 28, 119991 Moscow, Russia","institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I2802913842"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5082532445","display_name":"Fedor M. Dolgushin","orcid":"https://orcid.org/0000-0001-7716-0668","observed_orcids":["https://orcid.org/0000-0001-7716-0668"]},"institutions":[{"id":"https://openalex.org/I1313323035","display_name":"Russian Academy of Sciences","ror":"https://ror.org/05qrfxd25","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035"]},{"id":"https://openalex.org/I2802913842","display_name":"A. N. Nesmeyanov Institute of Organoelement Compounds","ror":"https://ror.org/03jzs4815","country_code":"RU","type":"facility","lineage":["https://openalex.org/I1313323035","https://openalex.org/I2802913842","https://openalex.org/I4210145551"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"Fedor M. Dolgushin","raw_affiliation_strings":["A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov str. 28, 119991 Moscow, Russia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov str. 28, 119991 Moscow, Russia","institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I2802913842"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5027884354","display_name":"Lina M. Epstein","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1313323035","display_name":"Russian Academy of Sciences","ror":"https://ror.org/05qrfxd25","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035"]},{"id":"https://openalex.org/I2802913842","display_name":"A. N. Nesmeyanov Institute of Organoelement Compounds","ror":"https://ror.org/03jzs4815","country_code":"RU","type":"facility","lineage":["https://openalex.org/I1313323035","https://openalex.org/I2802913842","https://openalex.org/I4210145551"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"Lina M. Epstein","raw_affiliation_strings":["A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov str. 28, 119991 Moscow, Russia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov str. 28, 119991 Moscow, Russia","institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I2802913842"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5111540728","display_name":"Vitaly K. Belsky","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210097270","display_name":"Karpov Institute of Physical Chemistry","ror":"https://ror.org/00p8xqj61","country_code":"RU","type":"facility","lineage":["https://openalex.org/I4210097270"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"Vitaly K. Belsky","raw_affiliation_strings":["L. Ya. Karpov Institute of Physical Chemistry, Vorontsovo Pole St. 10, Moscow, Russia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"L. Ya. Karpov Institute of Physical Chemistry, Vorontsovo Pole St. 10, Moscow, Russia","institution_ids":["https://openalex.org/I4210097270"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5079996831","display_name":"Elena S. Shubina","orcid":"https://orcid.org/0000-0001-8057-3703","observed_orcids":["https://orcid.org/0000-0001-8057-3703"]},"institutions":[{"id":"https://openalex.org/I1313323035","display_name":"Russian Academy of Sciences","ror":"https://ror.org/05qrfxd25","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035"]},{"id":"https://openalex.org/I2802913842","display_name":"A. N. Nesmeyanov Institute of Organoelement Compounds","ror":"https://ror.org/03jzs4815","country_code":"RU","type":"facility","lineage":["https://openalex.org/I1313323035","https://openalex.org/I2802913842","https://openalex.org/I4210145551"]}],"countries":["RU"],"is_corresponding":true,"raw_author_name":"Elena S. Shubina","raw_affiliation_strings":["A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov str. 28, 119991 Moscow, Russia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov str. 28, 119991 Moscow, Russia","institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I2802913842"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":3,"corresponding_author_ids":["https://openalex.org/A5079996831"],"corresponding_institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I2802913842"],"apc_list":{"value":850,"currency":"GBP","value_usd":1042},"apc_paid":null,"fwci":1.0857,"has_fulltext":false,"cited_by_count":25,"citation_normalized_percentile":{"value":0.72494421,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":98},"biblio":{"volume":"4","issue":"16","first_page":"8350","last_page":"8350"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T13833","display_name":"Ferrocene Chemistry and Applications","score":0.864300012588501,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T13833","display_name":"Ferrocene Chemistry and Applications","score":0.864300012588501,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10578","display_name":"Supramolecular Chemistry and Complexes","score":0.10660000145435333,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10798","display_name":"Crystallography and molecular interactions","score":0.00570000009611249,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/copper-complexes","display_name":"copper complexes","score":0.8429999947547913},{"id":"https://openalex.org/keywords/silver-complexes","display_name":"silver complexes","score":0.9990000128746033},{"id":"https://openalex.org/keywords/coordination-sites","display_name":"coordination sites","score":0.5529999732971191},{"id":"https://openalex.org/keywords/stability-constants","display_name":"stability constants","score":0.6380000114440918},{"id":"https://openalex.org/keywords/enthalpy-of-complexation","display_name":"enthalpy of complexation","score":0.8730000257492065},{"id":"https://openalex.org/keywords/crystal-structure","display_name":"crystal structure","score":0.753000020980835},{"id":"https://openalex.org/keywords/pi-pi-stacking","display_name":"\u03c0-\u03c0 stacking","score":0.41600000858306885}],"concepts":[{"id":"https://openalex.org/C2776442012","wikidata":"https://www.wikidata.org/wiki/Q2302144","display_name":"Trifluoromethyl","level":3,"score":0.8788719177246094},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.871936559677124},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.7202448844909668},{"id":"https://openalex.org/C2994492776","wikidata":"https://www.wikidata.org/wiki/Q629","display_name":"Oxygen atom","level":3,"score":0.6183522343635559},{"id":"https://openalex.org/C181458950","wikidata":"https://www.wikidata.org/wiki/Q2855060","display_name":"Cyclopentadienyl complex","level":3,"score":0.6144577264785767},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.5232393145561218},{"id":"https://openalex.org/C11111787","wikidata":"https://www.wikidata.org/wiki/Q675972","display_name":"Coordination sphere","level":3,"score":0.45578283071517944},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.45346084237098694},{"id":"https://openalex.org/C68913812","wikidata":"https://www.wikidata.org/wiki/Q238156","display_name":"Coordination complex","level":3,"score":0.44600430130958557},{"id":"https://openalex.org/C2777237805","wikidata":"https://www.wikidata.org/wiki/Q211972","display_name":"Ferrocene","level":4,"score":0.44010475277900696},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.43529215455055237},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.2961934208869934},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.241612046957016},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.22763732075691223},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.12938404083251953},{"id":"https://openalex.org/C52859227","wikidata":"https://www.wikidata.org/wiki/Q7877","display_name":"Electrochemistry","level":3,"score":0.0},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.0},{"id":"https://openalex.org/C17525397","wikidata":"https://www.wikidata.org/wiki/Q176140","display_name":"Electrode","level":2,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1039/c3ra47040g","doi":"https://doi.org/10.1039/c3ra47040g","is_oa":false,"landing_page_url":"https://doi.org/10.1039/c3ra47040g","pdf_url":null,"source":{"id":"https://openalex.org/S2481244646","display_name":"RSC Advances","issn_l":"2046-2069","issn":["2046-2069"],"is_oa":false,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj","dongbi-c","jufo-1","ki-jl-1","norway-1","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"RSC Advances","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320321079","display_name":"Russian Foundation for Basic Research","ror":"https://ror.org/02mh1ke95"},{"id":"https://openalex.org/F4320337393","display_name":"Division of Chemistry","ror":"https://ror.org/01ar8dr59"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":20,"referenced_works":["https://openalex.org/W1970510158","https://openalex.org/W1972419413","https://openalex.org/W1990088809","https://openalex.org/W2008553109","https://openalex.org/W2015943085","https://openalex.org/W2016691291","https://openalex.org/W2026529706","https://openalex.org/W2028916589","https://openalex.org/W2030841140","https://openalex.org/W2063506763","https://openalex.org/W2068421464","https://openalex.org/W2079653350","https://openalex.org/W2086748873","https://openalex.org/W2098163157","https://openalex.org/W2106390651","https://openalex.org/W2131350133","https://openalex.org/W2155946121","https://openalex.org/W2157627190","https://openalex.org/W2157906083","https://openalex.org/W2333488293"],"related_works":["https://openalex.org/W2333488293","https://openalex.org/W1970510158","https://openalex.org/W2776060911","https://openalex.org/W2432902241","https://openalex.org/W2512045721","https://openalex.org/W1968545481","https://openalex.org/W2087860704","https://openalex.org/W2013825080","https://openalex.org/W2155946121","https://openalex.org/W1972419413"],"abstract_inverted_index":{"Formation":[0],"of":[1,3,35,45,53,96,102,121,130,140],"complexes":[2,139],"the":[4,19,50,54,71,75,86,108,122,125,131,155,167],"macrocycles":[5,126],"(ML)3,":[6],"where":[7],"L":[8],"=":[9,11,14,23,26],"3,5-(CF3)2Pz":[10],"3,5-bis(trifluoromethyl)pyrazolate,":[12],"M":[13],"Cu":[15,87],"and":[16,18,63,74,82,149],"Ag,":[17],"acylferrocenes":[20],"FcC(O)CH2R":[21],"(Fc":[22],"(C5H5)Fe(C5H4);":[24],"R":[25],"H":[27],"(1),":[28],"Ph":[29,174],"(2))":[30],"was":[31,105],"studied":[32],"by":[33,111],"means":[34],"variable":[36],"temperature":[37],"IR,":[38],"UV-vis,":[39],"NMR":[40],"spectroscopy.":[41],"The":[42,57,89,138,162],"sole":[43],"site":[44,92],"coordination":[46,91,95],"in":[47,66,107,124,135,166],"solution":[48,68],"is":[49,164],"oxygen":[51,97],"atom":[52],"CO":[55],"group.":[56],"complex":[58,159],"composition":[59,148],"(1":[60],":":[61,146,157],"1)":[62],"thermodynamic":[64],"parameters":[65],"hexane":[67],"were":[69],"determined,":[70],"formation":[72],"constants":[73],"enthalpies":[76],"decreasing":[77],"from":[78,83],"1":[79,143,145,156,158],"to":[80,85,98],"2":[81,147,153],"Ag":[84],"macrocycle.":[88],"same":[90],"featuring":[93],"triple":[94],"all":[99,136],"metal":[100,123],"atoms":[101],"a":[103],"macrocycle":[104],"found":[106],"solid":[109],"state":[110],"single":[112],"crystal":[113],"X-ray":[114],"diffraction.":[115],"There":[116],"are":[117],"no":[118],"shortened":[119],"contacts":[120,172],"with":[127,142,160,173],"\u03c0-electron":[128],"system":[129],"ferrocene's":[132],"cyclopentadienyl":[133],"ligands":[134],"complexes.":[137],"(ML)3":[141],"have":[144],"bipyramidal":[150],"structure":[151],"whereas":[152],"forms":[154],"(AgL)3.":[161],"latter":[163],"packed":[165],"infinite":[168],"stacks":[169],"involving":[170],"additional":[171],"groups.":[175]},"counts_by_year":[{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":1},{"year":2023,"cited_by_count":3},{"year":2022,"cited_by_count":2},{"year":2021,"cited_by_count":2},{"year":2020,"cited_by_count":2},{"year":2019,"cited_by_count":3},{"year":2018,"cited_by_count":3},{"year":2017,"cited_by_count":4},{"year":2016,"cited_by_count":1},{"year":2015,"cited_by_count":1},{"year":2014,"cited_by_count":2}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2016-06-24T00:00:00"}