{"id":"https://openalex.org/W1976887447","doi":"https://doi.org/10.1021/es403711y","title":"Aromatic and Hydrophobic Surfaces of Wood-derived Biochar Enhance Perchlorate Adsorption via Hydrogen Bonding to Oxygen-containing Organic Groups","display_name":"Aromatic and Hydrophobic Surfaces of Wood-derived Biochar Enhance Perchlorate Adsorption via Hydrogen Bonding to Oxygen-containing Organic Groups","publication_year":2013,"publication_date":"2013-12-02","ids":{"openalex":"https://openalex.org/W1976887447","doi":"https://doi.org/10.1021/es403711y","mag":"1976887447","pmid":"https://pubmed.ncbi.nlm.nih.gov/24289306"},"language":"en","primary_location":{"id":"doi:10.1021/es403711y","doi":"https://doi.org/10.1021/es403711y","is_oa":false,"landing_page_url":"https://doi.org/10.1021/es403711y","pdf_url":null,"source":{"id":"https://openalex.org/S13479253","display_name":"Environmental Science & Technology","issn_l":"0013-936X","issn":["0013-936X","1520-5851"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-class-a","anvur-scientific","cwts-core","dongbi-a","fnege-4","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Environmental Science &amp; Technology","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5000714277","display_name":"Qile Fang","orcid":"https://orcid.org/0000-0003-2679-8711","observed_orcids":["https://orcid.org/0000-0003-2679-8711"]},"institutions":[{"id":"https://openalex.org/I76130692","display_name":"Zhejiang University","ror":"https://ror.org/00a2xv884","country_code":"CN","type":"education","lineage":["https://openalex.org/I76130692"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Qile Fang","raw_affiliation_strings":["Department of Environmental Science, Zhejiang Provincial Key Laboratory of Organic Pollution Process and Control, Zhejiang University , Hangzhou, Zhejiang 310058, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Environmental Science, Zhejiang Provincial Key Laboratory of Organic Pollution Process and Control, Zhejiang University , Hangzhou, Zhejiang 310058, China","institution_ids":["https://openalex.org/I76130692"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5090741037","display_name":"Baoliang Chen","orcid":"https://orcid.org/0000-0001-8196-081X","observed_orcids":["https://orcid.org/0000-0001-8196-081X"]},"institutions":[{"id":"https://openalex.org/I76130692","display_name":"Zhejiang University","ror":"https://ror.org/00a2xv884","country_code":"CN","type":"education","lineage":["https://openalex.org/I76130692"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Baoliang Chen","raw_affiliation_strings":["Department of Environmental Science, Zhejiang Provincial Key Laboratory of Organic Pollution\rProcess and Control, Zhejiang University, Hangzhou, Zhejiang 310058, China","Department of Environmental Science, Zhejiang Provincial Key Laboratory of Organic Pollution#R#Process and Control, Zhejiang University, Hangzhou, Zhejiang 310058, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Environmental Science, Zhejiang Provincial Key Laboratory of Organic Pollution\rProcess and Control, Zhejiang University, Hangzhou, Zhejiang 310058, China","institution_ids":["https://openalex.org/I76130692"]},{"raw_affiliation_string":"Department of Environmental Science, Zhejiang Provincial Key Laboratory of Organic Pollution#R#Process and Control, Zhejiang University, Hangzhou, Zhejiang 310058, China","institution_ids":["https://openalex.org/I76130692"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5102004090","display_name":"Yajie Lin","orcid":"https://orcid.org/0000-0003-3263-2451","observed_orcids":["https://orcid.org/0000-0003-3263-2451"]},"institutions":[{"id":"https://openalex.org/I76130692","display_name":"Zhejiang University","ror":"https://ror.org/00a2xv884","country_code":"CN","type":"education","lineage":["https://openalex.org/I76130692"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yajie Lin","raw_affiliation_strings":["Department of Environmental Science, Zhejiang Provincial Key Laboratory of Organic Pollution\rProcess and Control, Zhejiang University, Hangzhou, Zhejiang 310058, China","Department of Environmental Science, Zhejiang Provincial Key Laboratory of Organic Pollution#R#Process and Control, Zhejiang University, Hangzhou, Zhejiang 310058, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Environmental Science, Zhejiang Provincial Key Laboratory of Organic Pollution\rProcess and Control, Zhejiang University, Hangzhou, Zhejiang 310058, China","institution_ids":["https://openalex.org/I76130692"]},{"raw_affiliation_string":"Department of Environmental Science, Zhejiang Provincial Key Laboratory of Organic Pollution#R#Process and Control, Zhejiang University, Hangzhou, Zhejiang 310058, China","institution_ids":["https://openalex.org/I76130692"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5109943358","display_name":"Yuntai Guan","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I76130692","display_name":"Zhejiang University","ror":"https://ror.org/00a2xv884","country_code":"CN","type":"education","lineage":["https://openalex.org/I76130692"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yuntai Guan","raw_affiliation_strings":["Department of Environmental Science, Zhejiang Provincial Key Laboratory of Organic Pollution\rProcess and Control, Zhejiang University, Hangzhou, Zhejiang 310058, China","Department of Environmental Science, Zhejiang Provincial Key Laboratory of Organic Pollution#R#Process and Control, Zhejiang University, Hangzhou, Zhejiang 310058, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Environmental Science, Zhejiang Provincial Key Laboratory of Organic Pollution\rProcess and Control, Zhejiang University, Hangzhou, Zhejiang 310058, China","institution_ids":["https://openalex.org/I76130692"]},{"raw_affiliation_string":"Department of Environmental Science, Zhejiang Provincial Key Laboratory of Organic Pollution#R#Process and Control, Zhejiang University, Hangzhou, Zhejiang 310058, China","institution_ids":["https://openalex.org/I76130692"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5090741037"],"corresponding_institution_ids":["https://openalex.org/I76130692"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":10.5613,"has_fulltext":false,"cited_by_count":448,"citation_normalized_percentile":{"value":0.99306217,"is_in_top_1_percent":true,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":99,"max":100},"biblio":{"volume":"48","issue":"1","first_page":"279","last_page":"288"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T13563","display_name":"Chemical Analysis and Environmental Impact","score":0.9580000042915344,"subfield":{"id":"https://openalex.org/subfields/2307","display_name":"Health, Toxicology and Mutagenesis"},"field":{"id":"https://openalex.org/fields/23","display_name":"Environmental Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T13563","display_name":"Chemical Analysis and Environmental Impact","score":0.9580000042915344,"subfield":{"id":"https://openalex.org/subfields/2307","display_name":"Health, Toxicology and Mutagenesis"},"field":{"id":"https://openalex.org/fields/23","display_name":"Environmental Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10016","display_name":"Adsorption and biosorption for pollutant removal","score":0.034699998795986176,"subfield":{"id":"https://openalex.org/subfields/2312","display_name":"Water Science and Technology"},"field":{"id":"https://openalex.org/fields/23","display_name":"Environmental Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12078","display_name":"Environmental remediation with nanomaterials","score":0.0019000000320374966,"subfield":{"id":"https://openalex.org/subfields/2305","display_name":"Environmental Engineering"},"field":{"id":"https://openalex.org/fields/23","display_name":"Environmental Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/perchlorate-adsorption","display_name":"perchlorate adsorption","score":0.9430000185966492},{"id":"https://openalex.org/keywords/wood-biochar","display_name":"wood biochar","score":0.9430000185966492},{"id":"https://openalex.org/keywords/hydrogen-bonding","display_name":"hydrogen bonding","score":0.9380000233650208},{"id":"https://openalex.org/keywords/oxygen-containing-functional-groups","display_name":"oxygen-containing functional groups","score":0.8740000128746033},{"id":"https://openalex.org/keywords/hydrophobic-surfaces","display_name":"hydrophobic surfaces","score":0.7990000247955322},{"id":"https://openalex.org/keywords/ph-effect-on-adsorption","display_name":"pH effect on adsorption","score":0.8730000257492065},{"id":"https://openalex.org/keywords/anion-retention","display_name":"anion retention","score":0.5740000009536743},{"id":"https://openalex.org/keywords/surface-charge","display_name":"surface charge","score":0.4410000145435333},{"id":"https://openalex.org/keywords/zeta-potential","display_name":"zeta potential","score":0.7839999794960022},{"id":"https://openalex.org/keywords/carboxyl-groups","display_name":"carboxyl groups","score":0.7639999985694885},{"id":"https://openalex.org/keywords/hydroxyl-groups","display_name":"hydroxyl groups","score":0.8190000057220459},{"id":"https://openalex.org/keywords/column-adsorption","display_name":"column adsorption","score":0.578000009059906}],"concepts":[{"id":"https://openalex.org/C150394285","wikidata":"https://www.wikidata.org/wiki/Q180254","display_name":"Adsorption","level":2,"score":0.8617850542068481},{"id":"https://openalex.org/C56085101","wikidata":"https://www.wikidata.org/wiki/Q905495","display_name":"Biochar","level":3,"score":0.8567306995391846},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8562971949577332},{"id":"https://openalex.org/C112887158","wikidata":"https://www.wikidata.org/wiki/Q169324","display_name":"Hydrogen bond","level":3,"score":0.7907926440238953},{"id":"https://openalex.org/C2780709120","wikidata":"https://www.wikidata.org/wiki/Q407189","display_name":"Perchlorate","level":3,"score":0.7815617322921753},{"id":"https://openalex.org/C90260826","wikidata":"https://www.wikidata.org/wiki/Q899157","display_name":"Hydrophobic effect","level":2,"score":0.6012465357780457},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.5260065793991089},{"id":"https://openalex.org/C192386470","wikidata":"https://www.wikidata.org/wiki/Q210390","display_name":"Aromaticity","level":3,"score":0.493434339761734},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.38633808493614197},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.35189875960350037},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.20686274766921997},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.1725180447101593},{"id":"https://openalex.org/C36759035","wikidata":"https://www.wikidata.org/wiki/Q176848","display_name":"Pyrolysis","level":2,"score":0.121896892786026},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0}],"mesh":[{"descriptor_ui":"D000327","descriptor_name":"Adsorption","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D002606","descriptor_name":"Charcoal","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D006358","descriptor_name":"Hot Temperature","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D006860","descriptor_name":"Hydrogen Bonding","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D006863","descriptor_name":"Hydrogen-Ion Concentration","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D010100","descriptor_name":"Oxygen","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D010472","descriptor_name":"Perchlorates","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D014867","descriptor_name":"Water","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D014934","descriptor_name":"Wood","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D057927","descriptor_name":"Hydrophobic and Hydrophilic Interactions","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false}],"locations_count":2,"locations":[{"id":"doi:10.1021/es403711y","doi":"https://doi.org/10.1021/es403711y","is_oa":false,"landing_page_url":"https://doi.org/10.1021/es403711y","pdf_url":null,"source":{"id":"https://openalex.org/S13479253","display_name":"Environmental Science & Technology","issn_l":"0013-936X","issn":["0013-936X","1520-5851"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-class-a","anvur-scientific","cwts-core","dongbi-a","fnege-4","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Environmental Science &amp; Technology","raw_type":"journal-article"},{"id":"pmid:24289306","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/24289306","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Environmental science & technology","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[{"id":"https://metadata.un.org/sdg/6","score":0.7778000235557556,"display_name":"Clean water and sanitation"}],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":67,"referenced_works":["https://openalex.org/W1571059297","https://openalex.org/W1953124228","https://openalex.org/W1964679905","https://openalex.org/W1965666143","https://openalex.org/W1972897831","https://openalex.org/W1974048949","https://openalex.org/W1974971913","https://openalex.org/W1984063809","https://openalex.org/W1986610323","https://openalex.org/W1995758078","https://openalex.org/W1997501934","https://openalex.org/W1998036099","https://openalex.org/W2000337849","https://openalex.org/W2000794353","https://openalex.org/W2002023126","https://openalex.org/W2006276740","https://openalex.org/W2009254120","https://openalex.org/W2009603916","https://openalex.org/W2010120136","https://openalex.org/W2010566784","https://openalex.org/W2011203196","https://openalex.org/W2013118853","https://openalex.org/W2017199888","https://openalex.org/W2023631329","https://openalex.org/W2024104908","https://openalex.org/W2025515113","https://openalex.org/W2027934291","https://openalex.org/W2029534777","https://openalex.org/W2032515808","https://openalex.org/W2036023620","https://openalex.org/W2036965767","https://openalex.org/W2038240177","https://openalex.org/W2039385541","https://openalex.org/W2039808319","https://openalex.org/W2042953363","https://openalex.org/W2050695214","https://openalex.org/W2053995985","https://openalex.org/W2057853739","https://openalex.org/W2068713574","https://openalex.org/W2071959285","https://openalex.org/W2074489500","https://openalex.org/W2075667152","https://openalex.org/W2076614292","https://openalex.org/W2081442531","https://openalex.org/W2082025112","https://openalex.org/W2082032698","https://openalex.org/W2083918445","https://openalex.org/W2086808606","https://openalex.org/W2087867696","https://openalex.org/W2094613549","https://openalex.org/W2095454675","https://openalex.org/W2101695193","https://openalex.org/W2115805579","https://openalex.org/W2118750261","https://openalex.org/W2119280206","https://openalex.org/W2123145468","https://openalex.org/W2130793751","https://openalex.org/W2132407977","https://openalex.org/W2132482638","https://openalex.org/W2137495760","https://openalex.org/W2142107860","https://openalex.org/W2145713406","https://openalex.org/W2312559707","https://openalex.org/W2313294126","https://openalex.org/W2328874691","https://openalex.org/W2418222258","https://openalex.org/W4233828289"],"related_works":["https://openalex.org/W2800368909","https://openalex.org/W2086808606","https://openalex.org/W4379390283","https://openalex.org/W3147551144","https://openalex.org/W2744770807","https://openalex.org/W2956128190","https://openalex.org/W7128817954","https://openalex.org/W2263979730","https://openalex.org/W2082032698","https://openalex.org/W3037611848"],"abstract_inverted_index":{"The":[0,111,152],"pH-dependent":[1],"adsorption":[2,36,70,102,202],"of":[3,24,31,46,50,113,190,200],"perchlorate":[4,95,174],"(ClO4(-))":[5],"by":[6,39,76,120,157,185],"wood-derived":[7],"biochars":[8,25,59,88,165,205],"produced":[9],"at":[10],"200-700":[11],"\u00b0C":[12],"(referred":[13],"as":[14],"FB200-FB700)":[15],"was":[16,37,74,89,118,155],"investigated":[17],"to":[18,27,84,99,144,170,182],"probe":[19],"the":[20,29,40,47,91,100,127,158,177,186,195],"anion":[21,212],"retention":[22],"mechanisms":[23],"and":[26,33,43,63,141,175,197],"identify":[28],"interactions":[30],"water":[32],"biochar.":[34],"ClO4(-)":[35,69,134,180,201],"controlled":[38],"surface":[41,107,115,132],"polarities":[42],"structural":[44],"compositions":[45],"organic":[48],"components":[49],"biochars,":[51],"rather":[52],"than":[53],"their":[54,191],"inorganic":[55],"mineral":[56],"components.":[57],"FB500-FB700":[58],"with":[60,147],"low":[61],"polarity":[62],"high":[64,163],"aromaticity":[65],"displayed":[66],"a":[67,167],"superior":[68],"capacity,":[71],"but":[72],"which":[73,97,124],"affected":[75],"solution":[77],"pH.":[78,151],"Besides":[79],"electrostatic":[80],"interaction,":[81],"hydrogen":[82],"bonding":[83],"oxygen-containing":[85,116],"groups":[86,117,184],"on":[87,130],"proposed":[90],"dominant":[92],"force":[93,154],"for":[94,133,179,211],"adsorption,":[96],"led":[98],"maximum":[101],"occurring":[103],"near":[104],"pHIEP,":[105],"where":[106],"charge":[108],"equals":[109],"zero.":[110],"dissociation":[112],"these":[114],"monitored":[119],"zeta":[121],"potential":[122],"curves,":[123],"indicated":[125],"that":[126,204],"H-bonds":[128,178],"donors":[129],"biochar":[131],"binding":[135,181],"were":[136],"changed":[137],"from":[138],"-COOH":[139],"(ClO4(-)\u00b7\u00b7\u00b7HOOC-)":[140],"-OH":[142,145],"(ClO4(-)\u00b7\u00b7\u00b7HO-)":[143],"alone":[146],"an":[148],"increase":[149],"in":[150],"H-bond":[153],"strengthened":[156],"condensed":[159],"aromatic":[160,192],"surfaces,":[161],"since":[162],"temperature":[164],"provided":[166],"hydrophobic":[168],"microenvironment":[169],"accommodate":[171],"weakly":[172],"hydrated":[173],"facilitated":[176],"functional":[183],"large":[187],"\u03c0":[188],"subunit":[189],"substrate.":[193],"Lastly,":[194],"batch":[196],"column":[198],"tests":[199],"showed":[203],"like":[206],"FB700":[207],"are":[208],"effective":[209],"adsorbents":[210],"pollutant":[213],"removal":[214],"via":[215],"H-bonding":[216],"interaction.":[217]},"counts_by_year":[{"year":2026,"cited_by_count":31},{"year":2025,"cited_by_count":54},{"year":2024,"cited_by_count":46},{"year":2023,"cited_by_count":39},{"year":2022,"cited_by_count":36},{"year":2021,"cited_by_count":49},{"year":2020,"cited_by_count":46},{"year":2019,"cited_by_count":36},{"year":2018,"cited_by_count":37},{"year":2017,"cited_by_count":22},{"year":2016,"cited_by_count":23},{"year":2015,"cited_by_count":20},{"year":2014,"cited_by_count":9}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2016-06-24T00:00:00"}
