{"id":"https://openalex.org/W1976349151","doi":"https://doi.org/10.1021/ic9615077","title":"CisEffects in the Cobalt Corrins. 1. Crystal Structures of 10-Chloroaquacobalamin Perchlorate, 10-Chlorocyanocobalamin, and 10-Chloromethylcobalamin","display_name":"CisEffects in the Cobalt Corrins. 1. Crystal Structures of 10-Chloroaquacobalamin Perchlorate, 10-Chlorocyanocobalamin, and 10-Chloromethylcobalamin","publication_year":1997,"publication_date":"1997-08-01","ids":{"openalex":"https://openalex.org/W1976349151","doi":"https://doi.org/10.1021/ic9615077","mag":"1976349151","pmid":"https://pubmed.ncbi.nlm.nih.gov/11670058"},"language":"en","primary_location":{"id":"doi:10.1021/ic9615077","doi":"https://doi.org/10.1021/ic9615077","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ic9615077","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5101408625","display_name":"Kenneth L. Brown","orcid":"https://orcid.org/0000-0002-0864-3110","observed_orcids":["https://orcid.org/0000-0002-0864-3110"]},"institutions":[{"id":"https://openalex.org/I192619145","display_name":"University of the Witwatersrand","ror":"https://ror.org/03rp50x72","country_code":"ZA","type":"education","lineage":["https://openalex.org/I192619145"]},{"id":"https://openalex.org/I4210106879","display_name":"Ohio University","ror":"https://ror.org/01jr3y717","country_code":"US","type":"education","lineage":["https://openalex.org/I4210106879"]},{"id":"https://openalex.org/I52890796","display_name":"Mississippi College","ror":"https://ror.org/01p7j6t08","country_code":"US","type":"education","lineage":["https://openalex.org/I52890796"]},{"id":"https://openalex.org/I61937129","display_name":"Jackson State University","ror":"https://ror.org/01ecnnp60","country_code":"US","type":"education","lineage":["https://openalex.org/I4210141039","https://openalex.org/I61937129"]}],"countries":["US","ZA"],"is_corresponding":false,"raw_author_name":"Kenneth L. Brown","raw_affiliation_strings":["Department of Chemistry, Ohio University, Athens, Ohio 45701, Department of Chemistry, Jackson State University, Jackson, Mississippi 39217, Department of Chemistry, Mississippi College, Clinton, Mississippi 39058, and Centre for Molecular Design, Department of Chemistry, University of the Witwatersrand, PO Wits, 2050 Johannesburg, South Africa"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Ohio University, Athens, Ohio 45701, Department of Chemistry, Jackson State University, Jackson, Mississippi 39217, Department of Chemistry, Mississippi College, Clinton, Mississippi 39058, and Centre for Molecular Design, Department of Chemistry, University of the Witwatersrand, PO Wits, 2050 Johannesburg, South Africa","institution_ids":["https://openalex.org/I192619145","https://openalex.org/I4210106879","https://openalex.org/I52890796","https://openalex.org/I61937129"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5103566631","display_name":"Shifa Cheng","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I192619145","display_name":"University of the Witwatersrand","ror":"https://ror.org/03rp50x72","country_code":"ZA","type":"education","lineage":["https://openalex.org/I192619145"]},{"id":"https://openalex.org/I4210106879","display_name":"Ohio University","ror":"https://ror.org/01jr3y717","country_code":"US","type":"education","lineage":["https://openalex.org/I4210106879"]},{"id":"https://openalex.org/I52890796","display_name":"Mississippi College","ror":"https://ror.org/01p7j6t08","country_code":"US","type":"education","lineage":["https://openalex.org/I52890796"]},{"id":"https://openalex.org/I61937129","display_name":"Jackson State University","ror":"https://ror.org/01ecnnp60","country_code":"US","type":"education","lineage":["https://openalex.org/I4210141039","https://openalex.org/I61937129"]}],"countries":["US","ZA"],"is_corresponding":false,"raw_author_name":"Shifa Cheng","raw_affiliation_strings":["Department of Chemistry, Ohio University, Athens, Ohio 45701, Department of Chemistry, Jackson State University, Jackson, Mississippi 39217, Department of Chemistry, Mississippi College, Clinton, Mississippi 39058, and Centre for Molecular Design, Department of Chemistry, University of the Witwatersrand, PO Wits, 2050 Johannesburg, South Africa"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Ohio University, Athens, Ohio 45701, Department of Chemistry, Jackson State University, Jackson, Mississippi 39217, Department of Chemistry, Mississippi College, Clinton, Mississippi 39058, and Centre for Molecular Design, Department of Chemistry, University of the Witwatersrand, PO Wits, 2050 Johannesburg, South Africa","institution_ids":["https://openalex.org/I192619145","https://openalex.org/I4210106879","https://openalex.org/I52890796","https://openalex.org/I61937129"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5103111217","display_name":"Xiang Zou","orcid":"https://orcid.org/0000-0002-1064-2029","observed_orcids":["https://orcid.org/0000-0002-1064-2029"]},"institutions":[{"id":"https://openalex.org/I192619145","display_name":"University of the Witwatersrand","ror":"https://ror.org/03rp50x72","country_code":"ZA","type":"education","lineage":["https://openalex.org/I192619145"]},{"id":"https://openalex.org/I4210106879","display_name":"Ohio University","ror":"https://ror.org/01jr3y717","country_code":"US","type":"education","lineage":["https://openalex.org/I4210106879"]},{"id":"https://openalex.org/I52890796","display_name":"Mississippi College","ror":"https://ror.org/01p7j6t08","country_code":"US","type":"education","lineage":["https://openalex.org/I52890796"]},{"id":"https://openalex.org/I61937129","display_name":"Jackson State University","ror":"https://ror.org/01ecnnp60","country_code":"US","type":"education","lineage":["https://openalex.org/I4210141039","https://openalex.org/I61937129"]}],"countries":["US","ZA"],"is_corresponding":false,"raw_author_name":"Xiang Zou","raw_affiliation_strings":["Department of Chemistry, Ohio University, Athens, Ohio 45701, Department of Chemistry, Jackson State University, Jackson, Mississippi 39217, Department of Chemistry, Mississippi College, Clinton, Mississippi 39058, and Centre for Molecular Design, Department of Chemistry, University of the Witwatersrand, PO Wits, 2050 Johannesburg, South Africa"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Ohio University, Athens, Ohio 45701, Department of Chemistry, Jackson State University, Jackson, Mississippi 39217, Department of Chemistry, Mississippi College, Clinton, Mississippi 39058, and Centre for Molecular Design, Department of Chemistry, University of the Witwatersrand, PO Wits, 2050 Johannesburg, South Africa","institution_ids":["https://openalex.org/I192619145","https://openalex.org/I4210106879","https://openalex.org/I52890796","https://openalex.org/I61937129"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5108351047","display_name":"Jeffrey D. Zubkowski","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I192619145","display_name":"University of the Witwatersrand","ror":"https://ror.org/03rp50x72","country_code":"ZA","type":"education","lineage":["https://openalex.org/I192619145"]},{"id":"https://openalex.org/I4210106879","display_name":"Ohio University","ror":"https://ror.org/01jr3y717","country_code":"US","type":"education","lineage":["https://openalex.org/I4210106879"]},{"id":"https://openalex.org/I52890796","display_name":"Mississippi College","ror":"https://ror.org/01p7j6t08","country_code":"US","type":"education","lineage":["https://openalex.org/I52890796"]},{"id":"https://openalex.org/I61937129","display_name":"Jackson State University","ror":"https://ror.org/01ecnnp60","country_code":"US","type":"education","lineage":["https://openalex.org/I4210141039","https://openalex.org/I61937129"]}],"countries":["US","ZA"],"is_corresponding":false,"raw_author_name":"Jeffrey D. Zubkowski","raw_affiliation_strings":["Department of Chemistry, Ohio University, Athens, Ohio 45701, Department of Chemistry, Jackson State University, Jackson, Mississippi 39217, Department of Chemistry, Mississippi College, Clinton, Mississippi 39058, and Centre for Molecular Design, Department of Chemistry, University of the Witwatersrand, PO Wits, 2050 Johannesburg, South Africa"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Ohio University, Athens, Ohio 45701, Department of Chemistry, Jackson State University, Jackson, Mississippi 39217, Department of Chemistry, Mississippi College, Clinton, Mississippi 39058, and Centre for Molecular Design, Department of Chemistry, University of the Witwatersrand, PO Wits, 2050 Johannesburg, South Africa","institution_ids":["https://openalex.org/I192619145","https://openalex.org/I4210106879","https://openalex.org/I52890796","https://openalex.org/I61937129"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5016187623","display_name":"Edward J. Valente","orcid":"https://orcid.org/0000-0002-3261-8716","observed_orcids":["https://orcid.org/0000-0002-3261-8716"]},"institutions":[{"id":"https://openalex.org/I192619145","display_name":"University of the Witwatersrand","ror":"https://ror.org/03rp50x72","country_code":"ZA","type":"education","lineage":["https://openalex.org/I192619145"]},{"id":"https://openalex.org/I4210106879","display_name":"Ohio University","ror":"https://ror.org/01jr3y717","country_code":"US","type":"education","lineage":["https://openalex.org/I4210106879"]},{"id":"https://openalex.org/I52890796","display_name":"Mississippi College","ror":"https://ror.org/01p7j6t08","country_code":"US","type":"education","lineage":["https://openalex.org/I52890796"]},{"id":"https://openalex.org/I61937129","display_name":"Jackson State University","ror":"https://ror.org/01ecnnp60","country_code":"US","type":"education","lineage":["https://openalex.org/I4210141039","https://openalex.org/I61937129"]}],"countries":["US","ZA"],"is_corresponding":false,"raw_author_name":"Edward J. Valente","raw_affiliation_strings":["Department of Chemistry, Ohio University, Athens, Ohio 45701, Department of Chemistry, Jackson State University, Jackson, Mississippi 39217, Department of Chemistry, Mississippi College, Clinton, Mississippi 39058, and Centre for Molecular Design, Department of Chemistry, University of the Witwatersrand, PO Wits, 2050 Johannesburg, South Africa"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Ohio University, Athens, Ohio 45701, Department of Chemistry, Jackson State University, Jackson, Mississippi 39217, Department of Chemistry, Mississippi College, Clinton, Mississippi 39058, and Centre for Molecular Design, Department of Chemistry, University of the Witwatersrand, PO Wits, 2050 Johannesburg, South Africa","institution_ids":["https://openalex.org/I192619145","https://openalex.org/I4210106879","https://openalex.org/I52890796","https://openalex.org/I61937129"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5087234808","display_name":"Leanne Knapton","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I192619145","display_name":"University of the Witwatersrand","ror":"https://ror.org/03rp50x72","country_code":"ZA","type":"education","lineage":["https://openalex.org/I192619145"]},{"id":"https://openalex.org/I4210106879","display_name":"Ohio University","ror":"https://ror.org/01jr3y717","country_code":"US","type":"education","lineage":["https://openalex.org/I4210106879"]},{"id":"https://openalex.org/I52890796","display_name":"Mississippi College","ror":"https://ror.org/01p7j6t08","country_code":"US","type":"education","lineage":["https://openalex.org/I52890796"]},{"id":"https://openalex.org/I61937129","display_name":"Jackson State University","ror":"https://ror.org/01ecnnp60","country_code":"US","type":"education","lineage":["https://openalex.org/I4210141039","https://openalex.org/I61937129"]}],"countries":["US","ZA"],"is_corresponding":false,"raw_author_name":"Leanne Knapton","raw_affiliation_strings":["Department of Chemistry, Ohio University, Athens, Ohio 45701, Department of Chemistry, Jackson State University, Jackson, Mississippi 39217, Department of Chemistry, Mississippi College, Clinton, Mississippi 39058, and Centre for Molecular Design, Department of Chemistry, University of the Witwatersrand, PO Wits, 2050 Johannesburg, South Africa"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Ohio University, Athens, Ohio 45701, Department of Chemistry, Jackson State University, Jackson, Mississippi 39217, Department of Chemistry, Mississippi College, Clinton, Mississippi 39058, and Centre for Molecular Design, Department of Chemistry, University of the Witwatersrand, PO Wits, 2050 Johannesburg, South Africa","institution_ids":["https://openalex.org/I192619145","https://openalex.org/I4210106879","https://openalex.org/I52890796","https://openalex.org/I61937129"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5080064731","display_name":"Helder M. Marques","orcid":"https://orcid.org/0000-0003-1675-3835","observed_orcids":["https://orcid.org/0000-0003-1675-3835"]},"institutions":[{"id":"https://openalex.org/I192619145","display_name":"University of the Witwatersrand","ror":"https://ror.org/03rp50x72","country_code":"ZA","type":"education","lineage":["https://openalex.org/I192619145"]},{"id":"https://openalex.org/I4210106879","display_name":"Ohio University","ror":"https://ror.org/01jr3y717","country_code":"US","type":"education","lineage":["https://openalex.org/I4210106879"]},{"id":"https://openalex.org/I52890796","display_name":"Mississippi College","ror":"https://ror.org/01p7j6t08","country_code":"US","type":"education","lineage":["https://openalex.org/I52890796"]},{"id":"https://openalex.org/I61937129","display_name":"Jackson State University","ror":"https://ror.org/01ecnnp60","country_code":"US","type":"education","lineage":["https://openalex.org/I4210141039","https://openalex.org/I61937129"]}],"countries":["US","ZA"],"is_corresponding":false,"raw_author_name":"Helder M. Marques","raw_affiliation_strings":["Department of Chemistry, Ohio University, Athens, Ohio 45701, Department of Chemistry, Jackson State University, Jackson, Mississippi 39217, Department of Chemistry, Mississippi College, Clinton, Mississippi 39058, and Centre for Molecular Design, Department of Chemistry, University of the Witwatersrand, PO Wits, 2050 Johannesburg, South Africa"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Ohio University, Athens, Ohio 45701, Department of Chemistry, Jackson State University, Jackson, Mississippi 39217, Department of Chemistry, Mississippi College, Clinton, Mississippi 39058, and Centre for Molecular Design, Department of Chemistry, University of the Witwatersrand, PO Wits, 2050 Johannesburg, South Africa","institution_ids":["https://openalex.org/I192619145","https://openalex.org/I4210106879","https://openalex.org/I52890796","https://openalex.org/I61937129"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":4,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":4.3124,"has_fulltext":false,"cited_by_count":64,"citation_normalized_percentile":{"value":0.94469328,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":89,"max":98},"biblio":{"volume":"36","issue":"17","first_page":"3666","last_page":"3675"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10464","display_name":"Crystal structures of chemical compounds","score":0.9922000169754028,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10464","display_name":"Crystal structures of chemical compounds","score":0.9922000169754028,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11162","display_name":"Enzyme Structure and Function","score":0.00139999995008111,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12441","display_name":"Porphyrin Metabolism and Disorders","score":0.00139999995008111,"subfield":{"id":"https://openalex.org/subfields/1312","display_name":"Molecular Biology"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/crystal-structure","display_name":"crystal structure","score":0.7110000252723694},{"id":"https://openalex.org/keywords/13c-nmr-chemical-shifts","display_name":"13C NMR chemical shifts","score":0.8529999852180481}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9447224140167236},{"id":"https://openalex.org/C37243968","wikidata":"https://www.wikidata.org/wiki/Q648961","display_name":"Orthorhombic crystal system","level":3,"score":0.7919200658798218},{"id":"https://openalex.org/C61276311","wikidata":"https://www.wikidata.org/wiki/Q624543","display_name":"Monoclinic crystal system","level":3,"score":0.7253578901290894},{"id":"https://openalex.org/C2780187287","wikidata":"https://www.wikidata.org/wiki/Q120384","display_name":"Corrin","level":3,"score":0.7074005603790283},{"id":"https://openalex.org/C2780709120","wikidata":"https://www.wikidata.org/wiki/Q407189","display_name":"Perchlorate","level":3,"score":0.6890251040458679},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.6467770338058472},{"id":"https://openalex.org/C201194858","wikidata":"https://www.wikidata.org/wiki/Q898238","display_name":"Steric effects","level":2,"score":0.6192482113838196},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.5997868776321411},{"id":"https://openalex.org/C2780378348","wikidata":"https://www.wikidata.org/wiki/Q25351438","display_name":"Ring (chemistry)","level":2,"score":0.5825209617614746},{"id":"https://openalex.org/C2781060337","wikidata":"https://www.wikidata.org/wiki/Q462174","display_name":"Hydrate","level":2,"score":0.5255005359649658},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.5142926573753357},{"id":"https://openalex.org/C2908647359","wikidata":"https://www.wikidata.org/wiki/Q2625603","display_name":"Population","level":2,"score":0.4801028072834015},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.10193043947219849},{"id":"https://openalex.org/C144024400","wikidata":"https://www.wikidata.org/wiki/Q21201","display_name":"Sociology","level":0,"score":0.0},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.0},{"id":"https://openalex.org/C149923435","wikidata":"https://www.wikidata.org/wiki/Q37732","display_name":"Demography","level":1,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1021/ic9615077","doi":"https://doi.org/10.1021/ic9615077","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ic9615077","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},{"id":"pmid:11670058","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/11670058","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic chemistry","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":75,"referenced_works":["https://openalex.org/W192245335","https://openalex.org/W1018813964","https://openalex.org/W1499094942","https://openalex.org/W1502068659","https://openalex.org/W1547335399","https://openalex.org/W1963556494","https://openalex.org/W1968199859","https://openalex.org/W1969058620","https://openalex.org/W1969772813","https://openalex.org/W1973309466","https://openalex.org/W1974471377","https://openalex.org/W1975979982","https://openalex.org/W1976070987","https://openalex.org/W1977930029","https://openalex.org/W1978360039","https://openalex.org/W1982040658","https://openalex.org/W1986233251","https://openalex.org/W1986847107","https://openalex.org/W1996786961","https://openalex.org/W2000475214","https://openalex.org/W2000818231","https://openalex.org/W2003681250","https://openalex.org/W2005842893","https://openalex.org/W2007319908","https://openalex.org/W2007481733","https://openalex.org/W2011222492","https://openalex.org/W2012084977","https://openalex.org/W2013307148","https://openalex.org/W2013542770","https://openalex.org/W2013790391","https://openalex.org/W2015507588","https://openalex.org/W2016099899","https://openalex.org/W2016246519","https://openalex.org/W2016421990","https://openalex.org/W2025328417","https://openalex.org/W2026990899","https://openalex.org/W2031613324","https://openalex.org/W2032605653","https://openalex.org/W2032897372","https://openalex.org/W2035156594","https://openalex.org/W2039922625","https://openalex.org/W2048903985","https://openalex.org/W2050668588","https://openalex.org/W2052771814","https://openalex.org/W2055093322","https://openalex.org/W2057182104","https://openalex.org/W2058653907","https://openalex.org/W2059473103","https://openalex.org/W2062445896","https://openalex.org/W2062446565","https://openalex.org/W2064396466","https://openalex.org/W2069462248","https://openalex.org/W2071394380","https://openalex.org/W2078728250","https://openalex.org/W2080081939","https://openalex.org/W2080495160","https://openalex.org/W2081263315","https://openalex.org/W2082667110","https://openalex.org/W2086304434","https://openalex.org/W2088660282","https://openalex.org/W2089621810","https://openalex.org/W2091979836","https://openalex.org/W2092164294","https://openalex.org/W2117187589","https://openalex.org/W2117236066","https://openalex.org/W2155430111","https://openalex.org/W2321859908","https://openalex.org/W2328613431","https://openalex.org/W2331464269","https://openalex.org/W2334975039","https://openalex.org/W2395436798","https://openalex.org/W2943242402","https://openalex.org/W2951752789","https://openalex.org/W2951902443","https://openalex.org/W3004518568"],"related_works":["https://openalex.org/W1983510930","https://openalex.org/W2075845864","https://openalex.org/W2080374122","https://openalex.org/W2015297063","https://openalex.org/W2076824023","https://openalex.org/W2071110579","https://openalex.org/W7073537009","https://openalex.org/W2080443003","https://openalex.org/W2040166045","https://openalex.org/W2013697573"],"abstract_inverted_index":{"The":[0,209,289,323,361,706,738],"crystal":[1,587],"structures":[2,114],"of":[3,112,166,195,367,401,409,414,427,496,515,608,703,712,744],"10-chloroaquacobalamin":[4],"perchlorate":[5],"hydrate":[6,40,70],"(10-Cl-H(2)OCbl.ClO(4))":[7],"(Mo":[8,42,72],"Kalpha,":[9,43,73],"0.710":[10,44],"73":[11,45],"\u00c5,":[12,19,23,27,46,53,57,61,75,82,86,90,261,281],"monoclinic":[13],"system,":[14,48,77],"P2(1),":[15],"a":[16,50,79,123,183,647,727],"=":[17,21,25,29,37,51,55,59,66,80,84,88,95,223,230,629,651],"11.922(4)":[18],"b":[20,54,83],"26.592(10)":[22],"c":[24,58,87,334,354],"13.511(5)":[26],"beta":[28],"93.05(3)":[30],"degrees,":[31],"10":[32],"535":[33],"independent":[34,63,92],"reflections,":[35,64,93],"R(1)":[36,65,94],"0.0426),":[38],"10-chlorocyanocobalamin-acetone":[39],"(10-Cl-CNCbl)":[41],"orthorhombic":[47,76],"P2(1)2(1)2(1),":[49,78],"16.24(3)":[52],"21.85(5)":[56],"26.75(8)":[60],"7699":[62],"0.0698),":[67],"and":[68,142,157,170,253,259,352,375,468,478,512,518,527,581,600,631,685,750,777,782],"10-chloromethylcobalamin-acetone":[69],"(10-Cl-MeCbl)":[71],"0.71073":[74],"16.041(14)":[81],"22.13(2)":[85],"26.75(4)":[89],"6792":[91],"0.0554),":[96],"in":[97,117,126,136,149,180,213,220,268,287,296,304,327,340,359,373,378,423,441,444,525,563,611,622,668,690,709,715,733,760],"which":[98,127,435],"the":[99,113,118,128,132,137,143,150,159,174,196,199,235,238,264,273,308,317,333,346,353,402,407,410,421,424,445,461,469,486,493,504,513,531,541,556,564,576,586,606,634,638,654,658,669,674,686,693,700,710,753,758,761],"C10":[100,419,618],"meso":[101],"H":[102,347,415],"is":[103,115,201,277,284,298,311,320,329,371,404,436,453,545,555,724,743,779],"substituted":[104],"by":[105,279,416,488,615,748],"Cl,":[106],"are":[107,154,215,244,255,471,522,590,788],"reported.":[108],"An":[109],"unusual":[110],"feature":[111],"disorder":[116,177],"C":[119,175],"ring,":[120],"consistent":[121,437,789],"with":[122,406,438,596,790],"two-site":[124],"occupancy":[125],"major":[129],"conformation":[130,152],"has":[131],"C46":[133],"methyl":[134,145],"group":[135,146],"usual":[138],"position,":[139],"\"upwardly\"":[140],"axial,":[141],"C47":[144],"equatorial,":[147],"while":[148,271,316,633,653,681],"minor":[151,197],"both":[153],"pseudoequatorial,":[155],"above":[156],"below":[158],"corrin":[160,446,487,505,565,754],"ring.":[161,566],"(13)C":[162,597,781],"NMR":[163,342,598,784],"chemical":[164],"shifts":[165,599],"C46,":[167],"C47,":[168],"C12,":[169],"C13":[171],"suggest":[172],"that":[173,302,345,521,543,740,772],"ring":[176,184,506],"may":[178,601],"persist":[179],"solution":[181],"as":[182,339,464,537,699,765],"flip.":[185],"Since":[186],"molecular":[187],"dynamics":[188],"simulations":[189],"fail":[190],"to":[191,203,218,227,237,293,301,332,369,430,432,456,485,510,592,604,718,726,736,769],"reveal":[192],"any":[193],"population":[194],"conformation,":[198],"effect":[200,559],"likely":[202],"be":[204,395,602],"electronic":[205,425],"rather":[206],"than":[207,263,377],"steric.":[208],"axial":[210,462],"bond":[211,265,275,291,310,348,516,519,533,676,763],"lengths":[212,266,517,677],"10-Cl-MeCbl":[214,374],"very":[216,299,321],"similar":[217,300],"those":[219],"MeCbl":[221],"(d(Co)(-)(C)":[222],"1.979(7)":[224],"vs":[225,232,383,388,722],"1.99(2);":[226],"5,6-dimethylbenzimidazole,":[228],"d(Co)(-)(NB3)":[229,254,309,666,682],"2.200(7)":[231],"2.19(2)),":[233],"but":[234,282,307,392,646,673],"bonds":[236,465],"four":[239,639],"equatorial":[240,640,659,675],"N":[241,641,660],"donors,":[242],"d(Co)(-)(N(eq)),":[243],"on":[245,560,579,637,657,696,731,786],"average":[246,318,687],"0.05":[247],"\u00c5":[248],"shorter.":[249],"In":[250,664,756],"10-Cl-CNCbl,":[251,757],"d(Co)(-)(C)":[252],"longer":[256,312,473],"(by":[257],"0.10(2)":[258],"0.03(1)":[260],"respectively)":[262],"observed":[267],"CNCbl":[269,770],"itself,":[270,306],"conversely,":[272],"C-N":[274],"length":[276,292,764],"shorter":[278],"0.06(2)":[280],"there":[283],"little":[285],"difference":[286],"d(Co)(-)(N(eq)).":[288],"Co-O":[290],"coordinated":[294,324,350,713],"water":[295,325],"10-Cl-H(2)OCbl(+)":[297,328,716],"found":[303],"H(2)OCbl(+)":[305,719],"(1.967":[313],"vs1.925(2)":[314],"\u00c5),":[315],"d(Co)(-)(N(eq))":[319,688],"similar.":[322],"molecule":[326],"hydrogen":[330],"bonded":[331],"side":[335,355],"chain":[336,356],"carbonyl":[337],"oxygen,":[338],"H(2)OCbl(+).":[341],"observations":[343,785],"indicate":[344],"between":[349,466,775],"H(2)O":[351,630,714],"amide":[357],"persists":[358],"solution.":[360],"equilibrium":[362],"constant,":[363],"K(Co),":[364],"for":[365,397],"coordination":[366],"bzm":[368],"Co(III)":[370],"smaller":[372],"10-Cl-CNCbl":[376],"their":[379,582],"C10-unsubstituted":[380],"analogs":[381,584],"(181":[382],"452;":[384],"4.57":[385],"x":[386,390],"10(3)":[387],"3.35":[389],"10(5)),":[391],"could":[393],"not":[394,454],"determined":[396],"10-Cl-H(2)OCbl":[398],"because":[399],"hydrolysis":[400],"phosphodiester":[403],"competitive":[405,745],"establishment":[408],"base-off":[411],"equilibrium.":[412],"Substitution":[413,614],"Cl":[417,489,616,751],"at":[418,490,585,617,625],"causes":[420,619],"bands":[422],"spectrum":[426],"10-Cl-XCbl":[428,528],"complexes":[429,672],"move":[431],"lower":[433],"energy,":[434],"an":[439,546,620],"increase":[440,621],"electron":[442,451,458,548,553,561,609,746],"density":[443,452,624,636,656,730],"pi-conjugated":[447],"system.":[448,755],"This":[449],"increased":[450],"due":[455,725],"greater":[457],"donation":[459,554,747],"from":[460,483,570],"ligand":[463],"these":[467,612,791],"metal":[470],"either":[472],"(not":[474],"shorter)":[475],"or":[476],"unchanged,":[477,645,680],"it":[479],"most":[480],"probably":[481],"arises":[482],"pi-donation":[484],"C10.":[491],"As":[492],"donor":[494,701],"power":[495,702],"X":[497,628,650,704,749],"increases":[498,536,667,698,767],"(H(2)O":[499],"<":[500,502],"CN(-)":[501],"Me),":[503],"becomes":[507],"more":[508,557],"flexible":[509],"deformation,":[511],"number":[514],"angles":[520],"significantly":[523],"different":[524],"XCbl":[526,580],"increases;":[529],"importantly,":[530],"C10-Cl":[532],"length,":[534],"d(C10)(-)(Cl),":[535],"well.":[538],"Thus,":[539],"despite":[540],"fact":[542],"chlorine":[544,697],"inductively":[547],"withdrawing":[549],"substituent,":[550],"its":[551],"resonance":[552],"important":[558],"distribution":[562,610],"Mulliken":[567],"charges":[568],"obtained":[569],"semiempirical":[571],"RHF-SCF":[572],"MO":[573],"calculations":[574],"using":[575],"ZINDO/1":[577],"model":[578],"10-Cl":[583],"structure":[588],"geometry":[589],"shown":[591],"correlate":[593],"reasonably":[594],"well":[595],"used":[603],"determine":[605],"pattern":[607],"complexes.":[613],"charge":[623,635,655,695,729],"Co":[626],"when":[627,649],"CN(-),":[632],"donors":[642,661],"remains":[643,683],"virtually":[644,679],"decrease":[648,708,759],"Me,":[652],"also":[662],"decreases.":[663],"response,":[665],"first":[670],"two":[671],"remain":[678],"unchanged":[684],"decreases":[689],"10-Cl-MeCbl.":[691],"Furthermore,":[692],"partial":[694],"increases.":[705],"small":[707],"pK(a)":[711],"compared":[717,735,768],"itself":[720],"(7.65":[721],"8.09)":[723],"decreased":[728],"oxygen":[732],"10-Cl-OHCbl":[734],"OHCbl.":[737],"picture":[739],"emerges,":[741],"therefore,":[742],"toward":[752],"C&tbd1;N":[762],"Co-C":[766],"suggests":[771],"dpi-ppi":[773],"bonding":[774],"cobalt":[776],"cyanide":[778],"important.":[780],"(15)N":[783],"10-Cl-(13)C(15)NCbl":[787],"effects.":[792]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2024,"cited_by_count":3},{"year":2023,"cited_by_count":3},{"year":2021,"cited_by_count":2},{"year":2018,"cited_by_count":2},{"year":2017,"cited_by_count":2},{"year":2016,"cited_by_count":3},{"year":2015,"cited_by_count":4},{"year":2014,"cited_by_count":2},{"year":2013,"cited_by_count":1},{"year":2012,"cited_by_count":4}],"updated_date":"2026-10-02T10:15:12.560889","created_date":"2016-06-24T00:00:00"}