{"id":"https://openalex.org/W1971032041","doi":"https://doi.org/10.1021/ja067271f","title":"Ultrafast Structural Rearrangements in the MLCT Excited State for Copper(I) bis-Phenanthrolines in Solution","display_name":"Ultrafast Structural Rearrangements in the MLCT Excited State for Copper(I) bis-Phenanthrolines in Solution","publication_year":2007,"publication_date":"2007-01-26","ids":{"openalex":"https://openalex.org/W1971032041","doi":"https://doi.org/10.1021/ja067271f","mag":"1971032041","pmid":"https://pubmed.ncbi.nlm.nih.gov/17256860"},"language":"en","primary_location":{"id":"doi:10.1021/ja067271f","doi":"https://doi.org/10.1021/ja067271f","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja067271f","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://www.osti.gov/biblio/902226","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":null,"display_name":"George B. Shaw","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I102322142","display_name":"Rutgers, The State University of New Jersey","ror":"https://ror.org/05vt9qd57","country_code":"US","type":"education","lineage":["https://openalex.org/I102322142"]},{"id":"https://openalex.org/I1282105669","display_name":"Argonne National Laboratory","ror":"https://ror.org/05gvnxz63","country_code":"US","type":"facility","lineage":["https://openalex.org/I1282105669","https://openalex.org/I1330989302","https://openalex.org/I39565521","https://openalex.org/I40347166"]},{"id":"https://openalex.org/I1306266525","display_name":"Goddard Space Flight Center","ror":"https://ror.org/0171mag52","country_code":"US","type":"facility","lineage":["https://openalex.org/I1306266525","https://openalex.org/I4210124779"]},{"id":"https://openalex.org/I145311948","display_name":"Johns Hopkins University","ror":"https://ror.org/00za53h95","country_code":"US","type":"education","lineage":["https://openalex.org/I145311948"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"George B. Shaw","raw_affiliation_strings":["Contribution from the Chemistry Division, Argonne National Laboratory, Argonne, Illinois 60439, Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, Piscataway, New Jersey 08854, and Chemistry Department, Johns Hopkins University, Baltimore, Maryland 21218","NASA Goddard Space Flight Center"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Chemistry Division, Argonne National Laboratory, Argonne, Illinois 60439, Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, Piscataway, New Jersey 08854, and Chemistry Department, Johns Hopkins University, Baltimore, Maryland 21218","institution_ids":["https://openalex.org/I102322142","https://openalex.org/I1282105669","https://openalex.org/I145311948"]},{"raw_affiliation_string":"NASA Goddard Space Flight Center","institution_ids":["https://openalex.org/I1306266525"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5081791191","display_name":"Christian D. Grant","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I102322142","display_name":"Rutgers, The State University of New Jersey","ror":"https://ror.org/05vt9qd57","country_code":"US","type":"education","lineage":["https://openalex.org/I102322142"]},{"id":"https://openalex.org/I1282105669","display_name":"Argonne National Laboratory","ror":"https://ror.org/05gvnxz63","country_code":"US","type":"facility","lineage":["https://openalex.org/I1282105669","https://openalex.org/I1330989302","https://openalex.org/I39565521","https://openalex.org/I40347166"]},{"id":"https://openalex.org/I1282311441","display_name":"Lawrence Livermore National Laboratory","ror":"https://ror.org/041nk4h53","country_code":"US","type":"facility","lineage":["https://openalex.org/I1282311441","https://openalex.org/I1330989302","https://openalex.org/I198811213","https://openalex.org/I4210138311"]},{"id":"https://openalex.org/I145311948","display_name":"Johns Hopkins University","ror":"https://ror.org/00za53h95","country_code":"US","type":"education","lineage":["https://openalex.org/I145311948"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Christian D. Grant","raw_affiliation_strings":["Contribution from the Chemistry Division, Argonne National Laboratory, Argonne, Illinois 60439, Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, Piscataway, New Jersey 08854, and Chemistry Department, Johns Hopkins University, Baltimore, Maryland 21218","Lawrence Livermore National Laboratory"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Chemistry Division, Argonne National Laboratory, Argonne, Illinois 60439, Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, Piscataway, New Jersey 08854, and Chemistry Department, Johns Hopkins University, Baltimore, Maryland 21218","institution_ids":["https://openalex.org/I102322142","https://openalex.org/I1282105669","https://openalex.org/I145311948"]},{"raw_affiliation_string":"Lawrence Livermore National Laboratory","institution_ids":["https://openalex.org/I1282311441"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5036301051","display_name":"Hideaki Shirota","orcid":"https://orcid.org/0000-0002-5671-4649","observed_orcids":["https://orcid.org/0000-0002-5671-4649"]},"institutions":[{"id":"https://openalex.org/I102322142","display_name":"Rutgers, The State University of New Jersey","ror":"https://ror.org/05vt9qd57","country_code":"US","type":"education","lineage":["https://openalex.org/I102322142"]},{"id":"https://openalex.org/I1282105669","display_name":"Argonne National Laboratory","ror":"https://ror.org/05gvnxz63","country_code":"US","type":"facility","lineage":["https://openalex.org/I1282105669","https://openalex.org/I1330989302","https://openalex.org/I39565521","https://openalex.org/I40347166"]},{"id":"https://openalex.org/I145311948","display_name":"Johns Hopkins University","ror":"https://ror.org/00za53h95","country_code":"US","type":"education","lineage":["https://openalex.org/I145311948"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Hideaki Shirota","raw_affiliation_strings":["Contribution from the Chemistry Division, Argonne National Laboratory, Argonne, Illinois 60439, Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, Piscataway, New Jersey 08854, and Chemistry Department, Johns Hopkins University, Baltimore, Maryland 21218"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Chemistry Division, Argonne National Laboratory, Argonne, Illinois 60439, Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, Piscataway, New Jersey 08854, and Chemistry Department, Johns Hopkins University, Baltimore, Maryland 21218","institution_ids":["https://openalex.org/I102322142","https://openalex.org/I1282105669","https://openalex.org/I145311948"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5032749422","display_name":"Edward W. Castner","orcid":"https://orcid.org/0000-0003-1101-1090","observed_orcids":["https://orcid.org/0000-0003-1101-1090"]},"institutions":[{"id":"https://openalex.org/I102322142","display_name":"Rutgers, The State University of New Jersey","ror":"https://ror.org/05vt9qd57","country_code":"US","type":"education","lineage":["https://openalex.org/I102322142"]},{"id":"https://openalex.org/I1282105669","display_name":"Argonne National Laboratory","ror":"https://ror.org/05gvnxz63","country_code":"US","type":"facility","lineage":["https://openalex.org/I1282105669","https://openalex.org/I1330989302","https://openalex.org/I39565521","https://openalex.org/I40347166"]},{"id":"https://openalex.org/I145311948","display_name":"Johns Hopkins University","ror":"https://ror.org/00za53h95","country_code":"US","type":"education","lineage":["https://openalex.org/I145311948"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Edward W. Castner","raw_affiliation_strings":["Contribution from the Chemistry Division, Argonne National Laboratory, Argonne, Illinois 60439, Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, Piscataway, New Jersey 08854, and Chemistry Department, Johns Hopkins University, Baltimore, Maryland 21218"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Chemistry Division, Argonne National Laboratory, Argonne, Illinois 60439, Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, Piscataway, New Jersey 08854, and Chemistry Department, Johns Hopkins University, Baltimore, Maryland 21218","institution_ids":["https://openalex.org/I102322142","https://openalex.org/I1282105669","https://openalex.org/I145311948"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5073119387","display_name":"Gerald J. Meyer","orcid":"https://orcid.org/0000-0002-4227-6393","observed_orcids":["https://orcid.org/0000-0002-4227-6393"]},"institutions":[{"id":"https://openalex.org/I102322142","display_name":"Rutgers, The State University of New Jersey","ror":"https://ror.org/05vt9qd57","country_code":"US","type":"education","lineage":["https://openalex.org/I102322142"]},{"id":"https://openalex.org/I1282105669","display_name":"Argonne National Laboratory","ror":"https://ror.org/05gvnxz63","country_code":"US","type":"facility","lineage":["https://openalex.org/I1282105669","https://openalex.org/I1330989302","https://openalex.org/I39565521","https://openalex.org/I40347166"]},{"id":"https://openalex.org/I145311948","display_name":"Johns Hopkins University","ror":"https://ror.org/00za53h95","country_code":"US","type":"education","lineage":["https://openalex.org/I145311948"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Gerald J. Meyer","raw_affiliation_strings":["Contribution from the Chemistry Division, Argonne National Laboratory, Argonne, Illinois 60439, Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, Piscataway, New Jersey 08854, and Chemistry Department, Johns Hopkins University, Baltimore, Maryland 21218"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Chemistry Division, Argonne National Laboratory, Argonne, Illinois 60439, Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, Piscataway, New Jersey 08854, and Chemistry Department, Johns Hopkins University, Baltimore, Maryland 21218","institution_ids":["https://openalex.org/I102322142","https://openalex.org/I1282105669","https://openalex.org/I145311948"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5014620636","display_name":"Lin X. Chen","orcid":"https://orcid.org/0000-0002-8450-6687","observed_orcids":["https://orcid.org/0000-0002-8450-6687"]},"institutions":[{"id":"https://openalex.org/I102322142","display_name":"Rutgers, The State University of New Jersey","ror":"https://ror.org/05vt9qd57","country_code":"US","type":"education","lineage":["https://openalex.org/I102322142"]},{"id":"https://openalex.org/I1282105669","display_name":"Argonne National Laboratory","ror":"https://ror.org/05gvnxz63","country_code":"US","type":"facility","lineage":["https://openalex.org/I1282105669","https://openalex.org/I1330989302","https://openalex.org/I39565521","https://openalex.org/I40347166"]},{"id":"https://openalex.org/I145311948","display_name":"Johns Hopkins University","ror":"https://ror.org/00za53h95","country_code":"US","type":"education","lineage":["https://openalex.org/I145311948"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Lin X. Chen","raw_affiliation_strings":["Contribution from the Chemistry Division, Argonne National Laboratory, Argonne, Illinois 60439, Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, Piscataway, New Jersey 08854, and Chemistry Department, Johns Hopkins University, Baltimore, Maryland 21218","argonne national laboratory"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Chemistry Division, Argonne National Laboratory, Argonne, Illinois 60439, Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, Piscataway, New Jersey 08854, and Chemistry Department, Johns Hopkins University, Baltimore, Maryland 21218","institution_ids":["https://openalex.org/I102322142","https://openalex.org/I1282105669","https://openalex.org/I145311948"]},{"raw_affiliation_string":"argonne national laboratory","institution_ids":["https://openalex.org/I1282105669"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":5,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":5.3727,"has_fulltext":false,"cited_by_count":219,"citation_normalized_percentile":{"value":0.96862148,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":98,"max":100},"biblio":{"volume":"129","issue":"7","first_page":"2147","last_page":"2160"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11129","display_name":"Photochemistry and Electron Transfer Studies","score":0.9922000169754028,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11129","display_name":"Photochemistry and Electron Transfer Studies","score":0.9922000169754028,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11177","display_name":"Spectroscopy and Quantum Chemical Studies","score":0.006899999920278788,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11733","display_name":"X-ray Spectroscopy and Fluorescence Analysis","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/3108","display_name":"Radiation"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/metal-to-ligand-charge-transfer","display_name":"metal-to-ligand charge transfer","score":0.9459999799728394},{"id":"https://openalex.org/keywords/excited-state-structural-dynamics","display_name":"excited-state structural dynamics","score":0.9369999766349792},{"id":"https://openalex.org/keywords/franck-condon-state","display_name":"Franck-Condon state","score":0.7910000085830688},{"id":"https://openalex.org/keywords/internal-conversion","display_name":"internal conversion","score":0.800000011920929},{"id":"https://openalex.org/keywords/intersystem-crossing","display_name":"intersystem crossing","score":0.9990000128746033},{"id":"https://openalex.org/keywords/dielectric-constant-effect","display_name":"dielectric constant effect","score":0.6589999794960022},{"id":"https://openalex.org/keywords/acetonitrile","display_name":"acetonitrile","score":0.656000018119812},{"id":"https://openalex.org/keywords/solar-energy-conversion","display_name":"solar energy conversion","score":0.6340000033378601}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8443849682807922},{"id":"https://openalex.org/C95503338","wikidata":"https://www.wikidata.org/wiki/Q186105","display_name":"Ultrafast laser spectroscopy","level":3,"score":0.6863341331481934},{"id":"https://openalex.org/C73978554","wikidata":"https://www.wikidata.org/wiki/Q772919","display_name":"Intersystem crossing","level":4,"score":0.6862454414367676},{"id":"https://openalex.org/C181500209","wikidata":"https://www.wikidata.org/wiki/Q215328","display_name":"Excited state","level":2,"score":0.6743305325508118},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.560728132724762},{"id":"https://openalex.org/C32891209","wikidata":"https://www.wikidata.org/wiki/Q483666","display_name":"Spectroscopy","level":2,"score":0.4521385431289673},{"id":"https://openalex.org/C119824511","wikidata":"https://www.wikidata.org/wiki/Q13553575","display_name":"Absorption spectroscopy","level":2,"score":0.43635016679763794},{"id":"https://openalex.org/C33062035","wikidata":"https://www.wikidata.org/wiki/Q3296863","display_name":"Singlet state","level":3,"score":0.35992246866226196},{"id":"https://openalex.org/C113196181","wikidata":"https://www.wikidata.org/wiki/Q485223","display_name":"Analytical Chemistry (journal)","level":2,"score":0.34703171253204346},{"id":"https://openalex.org/C184779094","wikidata":"https://www.wikidata.org/wiki/Q26383","display_name":"Atomic physics","level":1,"score":0.17757689952850342},{"id":"https://openalex.org/C120665830","wikidata":"https://www.wikidata.org/wiki/Q14620","display_name":"Optics","level":1,"score":0.06678634881973267},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C43617362","wikidata":"https://www.wikidata.org/wiki/Q170050","display_name":"Chromatography","level":1,"score":0.0}],"mesh":[],"locations_count":5,"locations":[{"id":"doi:10.1021/ja067271f","doi":"https://doi.org/10.1021/ja067271f","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja067271f","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},{"id":"pmid:17256860","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/17256860","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"Journal Article"},{"id":"pmh:info:ark/67531/metadc888843","doi":null,"is_oa":false,"landing_page_url":"https://digital.library.unt.edu/ark:/67531/metadc888843/","pdf_url":null,"source":{"id":"https://openalex.org/S4306400792","display_name":"University of North Texas Digital Library (University of North Texas)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I123534392","host_organization_name":"University of North Texas","host_organization_lineage":["https://openalex.org/I123534392"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Journal Name: Journal of the American Chemical Society, vol. 129, no. 7, February 21, 2007, pp. 2147-2160; Journal Volume: 129; Journal Issue: 7","raw_type":"Article"},{"id":"pmh:oai:alma.01RUT_INST:11675554870004646","doi":null,"is_oa":false,"landing_page_url":"https://scholarship.libraries.rutgers.edu/esploro/outputs/journalArticle/Ultrafast-Structural-Rearrangements-in-the-MLCT/991031716714604646","pdf_url":null,"source":{"id":"https://openalex.org/S4306401388","display_name":"Rutgers University Community Repository (Rutgers University)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I102322142","host_organization_name":"Rutgers, The State University of New Jersey","host_organization_lineage":["https://openalex.org/I102322142"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"text"},{"id":"pmh:oai:osti.gov:902226","doi":null,"is_oa":true,"landing_page_url":"https://www.osti.gov/biblio/902226","pdf_url":null,"source":{"id":"https://openalex.org/S4306402487","display_name":"OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I139351228","host_organization_name":"Office of Scientific and Technical Information","host_organization_lineage":["https://openalex.org/I139351228"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":null}],"best_oa_location":{"id":"pmh:oai:osti.gov:902226","doi":null,"is_oa":true,"landing_page_url":"https://www.osti.gov/biblio/902226","pdf_url":null,"source":{"id":"https://openalex.org/S4306402487","display_name":"OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I139351228","host_organization_name":"Office of Scientific and Technical Information","host_organization_lineage":["https://openalex.org/I139351228"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":null},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":56,"referenced_works":["https://openalex.org/W165651719","https://openalex.org/W1608145240","https://openalex.org/W1963974948","https://openalex.org/W1965450832","https://openalex.org/W1968197315","https://openalex.org/W1969463572","https://openalex.org/W1969919479","https://openalex.org/W1973323475","https://openalex.org/W1978104482","https://openalex.org/W1978876412","https://openalex.org/W1980642168","https://openalex.org/W1980905899","https://openalex.org/W1991583740","https://openalex.org/W1992143807","https://openalex.org/W1992292171","https://openalex.org/W1999582957","https://openalex.org/W2004775838","https://openalex.org/W2004977643","https://openalex.org/W2007078309","https://openalex.org/W2015200559","https://openalex.org/W2016138958","https://openalex.org/W2016440172","https://openalex.org/W2017216815","https://openalex.org/W2031447157","https://openalex.org/W2033456703","https://openalex.org/W2035800135","https://openalex.org/W2039484516","https://openalex.org/W2039583181","https://openalex.org/W2041977650","https://openalex.org/W2044596942","https://openalex.org/W2050056663","https://openalex.org/W2050270322","https://openalex.org/W2050634080","https://openalex.org/W2053539541","https://openalex.org/W2054683675","https://openalex.org/W2054793107","https://openalex.org/W2054947925","https://openalex.org/W2055392032","https://openalex.org/W2055991599","https://openalex.org/W2064010970","https://openalex.org/W2066877229","https://openalex.org/W2069739722","https://openalex.org/W2081019235","https://openalex.org/W2082813214","https://openalex.org/W2084389300","https://openalex.org/W2086666384","https://openalex.org/W2087182711","https://openalex.org/W2087999702","https://openalex.org/W2120244319","https://openalex.org/W2126972266","https://openalex.org/W2134192844","https://openalex.org/W2148084147","https://openalex.org/W2151954645","https://openalex.org/W3105705628","https://openalex.org/W3138923988","https://openalex.org/W4238336611"],"related_works":["https://openalex.org/W2104148174","https://openalex.org/W2321560026","https://openalex.org/W2081000035","https://openalex.org/W2698840911","https://openalex.org/W2001413583","https://openalex.org/W2334166368","https://openalex.org/W2316358621","https://openalex.org/W2214140707","https://openalex.org/W2066877229","https://openalex.org/W1968682289"],"abstract_inverted_index":{"Ultrafast":[0],"excited-state":[1,177],"structural":[2,14,82,231],"dynamics":[3,114,141],"of":[4,16,47,56,84,133,142,170,222],"[Cu(I)(dmp)(2)](+)":[5,91,144],"(dmp":[6],"=":[7,95],"2,9-dimethyl-1,10-phenanthroline)":[8],"have":[9,88],"been":[10],"studied":[11,89],"to":[12,36,130,175,181],"identify":[13],"origins":[15],"transient":[17,108],"spectroscopic":[18],"changes":[19],"during":[20],"the":[21,45,48,54,59,63,81,125,131,134,148,153,162,176,182,189,196,201,208,219],"photoinduced":[22],"metal-to-ligand":[23],"charge-transfer":[24],"(MLCT)":[25],"transition":[26],"that":[27,116,206],"induces":[28],"an":[29,213],"electronic":[30],"configuration":[31],"change":[32],"from":[33],"Cu(I)":[34,85],"(3d(10))":[35],"Cu(II)":[37],"(3d(9)).":[38],"This":[39],"study":[40],"has":[41],"important":[42],"connections":[43],"with":[44,58,99,200,207],"flattening":[46,132,216],"Franck-Condon":[49,190,203],"state":[50,67,191,221],"tetrahedral":[51,135,202,210],"geometry":[52,204,211],"and":[53,92,104,185,205],"ligation":[55],"Cu(II)*":[57],"solvent":[60,150],"observed":[61,112],"in":[62,97,147,218,245],"thermally":[64],"equilibrated":[65],"MLCT":[66,220],"by":[68,107],"our":[69],"previous":[70],"laser-initiated":[71],"time-resolved":[72],"X-ray":[73,230],"absorption":[74,109],"spectroscopy":[75],"(LITR-XAS)":[76],"results.":[77],"To":[78],"better":[79],"understand":[80],"photodynamics":[83],"complexes,":[86],"we":[87],"both":[90],"[Cu(I)(dpp)(2)](+)":[93],"(dpp":[94],"2,9-diphenyl-1,10-phenanthroline)":[96],"solvents":[98],"different":[100,158],"dielectric":[101],"constants,":[102],"viscosities,":[103],"thermal":[105],"diffusivities":[106],"spectroscopy.":[110],"The":[111,138,193],"spectral":[113],"suggest":[115],"a":[117,166],"solvent-independent":[118],"inner-sphere":[119],"relaxation":[120],"process":[121,217],"is":[122,173],"occurring":[123],"despite":[124],"large":[126],"amplitude":[127],"motions":[128],"due":[129,180],"coordinated":[136],"geometry.":[137,192],"singlet":[139],"fluorescence":[140,154,168,198],"photoexcited":[143],"were":[145],"measured":[146],"coordinating":[149],"acetonitrile,":[151],"using":[152],"upconversion":[155],"method":[156],"at":[157,188],"emission":[159,164],"wavelengths.":[160],"At":[161],"bluest":[163],"wavelengths,":[165],"prompt":[167,197],"lifetime":[169,199],"77":[171],"fs":[172],"attributed":[174],"deactivation":[178],"processes":[179],"internal":[183],"conversion":[184],"intersystem":[186],"crossing":[187],"differentiation":[194],"between":[195],"flattened":[209],"uncovers":[212],"unexpected":[214],"ultrafast":[215,234],"[Cu(I)(dmp)(2)](+).":[223],"These":[224],"results":[225],"provide":[226],"guidance":[227],"for":[228,240],"future":[229],"studies":[232],"on":[233],"time":[235],"scale,":[236],"as":[237,239],"well":[238],"synthesis":[241],"toward":[242],"its":[243],"applications":[244],"solar":[246],"energy":[247],"conversion.":[248]},"counts_by_year":[{"year":2026,"cited_by_count":7},{"year":2025,"cited_by_count":7},{"year":2024,"cited_by_count":14},{"year":2023,"cited_by_count":13},{"year":2022,"cited_by_count":15},{"year":2021,"cited_by_count":8},{"year":2020,"cited_by_count":11},{"year":2019,"cited_by_count":12},{"year":2018,"cited_by_count":13},{"year":2017,"cited_by_count":20},{"year":2016,"cited_by_count":12},{"year":2015,"cited_by_count":14},{"year":2014,"cited_by_count":19},{"year":2013,"cited_by_count":14},{"year":2012,"cited_by_count":7}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2016-06-24T00:00:00"}
