{"id":"https://openalex.org/W1970729975","doi":"https://doi.org/10.1021/ic049627z","title":"Mechanistic Variations in the Oxidation of Piloty's Acid by Metal Complexes","display_name":"Mechanistic Variations in the Oxidation of Piloty's Acid by Metal Complexes","publication_year":2004,"publication_date":"2004-11-01","ids":{"openalex":"https://openalex.org/W1970729975","doi":"https://doi.org/10.1021/ic049627z","mag":"1970729975","pmid":"https://pubmed.ncbi.nlm.nih.gov/15554653"},"language":"en","primary_location":{"id":"doi:10.1021/ic049627z","doi":"https://doi.org/10.1021/ic049627z","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ic049627z","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5109959979","display_name":"Patricia C. Wilkins","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I10052268","display_name":"New Mexico State University","ror":"https://ror.org/00hpz7z43","country_code":"US","type":"education","lineage":["https://openalex.org/I10052268"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Patricia C. Wilkins","raw_affiliation_strings":["Department of Chemistry and Biochemistry, MSC 3C, New Mexico State University, Box 30001, Las Cruces, New Mexico 88003-8001","Department of Chemistry and Biochemistry, MSC 3C, New Mexico State University, Box 30001, Las Cruces, New Mexico 88003-8001, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, MSC 3C, New Mexico State University, Box 30001, Las Cruces, New Mexico 88003-8001","institution_ids":["https://openalex.org/I10052268"]},{"raw_affiliation_string":"Department of Chemistry and Biochemistry, MSC 3C, New Mexico State University, Box 30001, Las Cruces, New Mexico 88003-8001, USA","institution_ids":["https://openalex.org/I10052268"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5050269125","display_name":"Hollie K. Jacobs","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I10052268","display_name":"New Mexico State University","ror":"https://ror.org/00hpz7z43","country_code":"US","type":"education","lineage":["https://openalex.org/I10052268"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Hollie K. Jacobs","raw_affiliation_strings":["Department of Chemistry and Biochemistry, MSC 3C, New Mexico State University, Box 30001, Las Cruces, New Mexico 88003-8001"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, MSC 3C, New Mexico State University, Box 30001, Las Cruces, New Mexico 88003-8001","institution_ids":["https://openalex.org/I10052268"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5051998027","display_name":"Michael D. Johnson","orcid":"https://orcid.org/0000-0001-5483-5933","observed_orcids":["https://orcid.org/0000-0001-5483-5933"]},"institutions":[{"id":"https://openalex.org/I10052268","display_name":"New Mexico State University","ror":"https://ror.org/00hpz7z43","country_code":"US","type":"education","lineage":["https://openalex.org/I10052268"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Michael D. Johnson","raw_affiliation_strings":["Department of Chemistry and Biochemistry, MSC 3C, New Mexico State University, Box 30001, Las Cruces, New Mexico 88003-8001"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, MSC 3C, New Mexico State University, Box 30001, Las Cruces, New Mexico 88003-8001","institution_ids":["https://openalex.org/I10052268"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5075954299","display_name":"Aravamudan S. Gopalan","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I10052268","display_name":"New Mexico State University","ror":"https://ror.org/00hpz7z43","country_code":"US","type":"education","lineage":["https://openalex.org/I10052268"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Aravamudan S. Gopalan","raw_affiliation_strings":["Department of Chemistry and Biochemistry, MSC 3C, New Mexico State University, Box 30001, Las Cruces, New Mexico 88003-8001"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, MSC 3C, New Mexico State University, Box 30001, Las Cruces, New Mexico 88003-8001","institution_ids":["https://openalex.org/I10052268"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5051998027"],"corresponding_institution_ids":["https://openalex.org/I10052268"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":0.634,"has_fulltext":false,"cited_by_count":17,"citation_normalized_percentile":{"value":0.62037232,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":97},"biblio":{"volume":"43","issue":"24","first_page":"7877","last_page":"7881"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.6987000107765198,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.6987000107765198,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11989","display_name":"Oxidative Organic Chemistry Reactions","score":0.20200000703334808,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11747","display_name":"Metal-Catalyzed Oxygenation Mechanisms","score":0.03550000116229057,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/nitric-oxide","display_name":"nitric oxide","score":0.6779999732971191},{"id":"https://openalex.org/keywords/nitrite","display_name":"nitrite","score":0.9879999756813049},{"id":"https://openalex.org/keywords/oxidation-mechanism","display_name":"oxidation mechanism","score":0.6669999957084656},{"id":"https://openalex.org/keywords/coordination-compounds","display_name":"metal complexes","score":0.4230000078678131}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9844679236412048},{"id":"https://openalex.org/C2776179834","wikidata":"https://www.wikidata.org/wiki/Q72158415","display_name":"Nitrite","level":3,"score":0.8156789541244507},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.7772685289382935},{"id":"https://openalex.org/C2776910235","wikidata":"https://www.wikidata.org/wiki/Q18574","display_name":"Reactivity (psychology)","level":3,"score":0.6796605587005615},{"id":"https://openalex.org/C2778504605","wikidata":"https://www.wikidata.org/wiki/Q83320","display_name":"Nitric acid","level":2,"score":0.5536075830459595},{"id":"https://openalex.org/C2779851234","wikidata":"https://www.wikidata.org/wiki/Q50690","display_name":"Oxide","level":2,"score":0.5535337924957275},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.547631561756134},{"id":"https://openalex.org/C519581460","wikidata":"https://www.wikidata.org/wiki/Q207843","display_name":"Nitric oxide","level":2,"score":0.47857001423835754},{"id":"https://openalex.org/C537208039","wikidata":"https://www.wikidata.org/wiki/Q627","display_name":"Nitrogen","level":2,"score":0.45010846853256226},{"id":"https://openalex.org/C55904794","wikidata":"https://www.wikidata.org/wiki/Q82682","display_name":"Redox","level":2,"score":0.4302721917629242},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.3292863965034485},{"id":"https://openalex.org/C2776384668","wikidata":"https://www.wikidata.org/wiki/Q182168","display_name":"Nitrate","level":2,"score":0.14897087216377258},{"id":"https://openalex.org/C71924100","wikidata":"https://www.wikidata.org/wiki/Q11190","display_name":"Medicine","level":0,"score":0.0},{"id":"https://openalex.org/C204787440","wikidata":"https://www.wikidata.org/wiki/Q188504","display_name":"Alternative medicine","level":2,"score":0.0},{"id":"https://openalex.org/C142724271","wikidata":"https://www.wikidata.org/wiki/Q7208","display_name":"Pathology","level":1,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1021/ic049627z","doi":"https://doi.org/10.1021/ic049627z","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ic049627z","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},{"id":"pmid:15554653","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/15554653","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic chemistry","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":19,"referenced_works":["https://openalex.org/W1515948134","https://openalex.org/W1560973356","https://openalex.org/W1849554878","https://openalex.org/W1874097147","https://openalex.org/W1964001013","https://openalex.org/W1977725014","https://openalex.org/W1981889286","https://openalex.org/W1985113871","https://openalex.org/W2011271849","https://openalex.org/W2024163805","https://openalex.org/W2034948004","https://openalex.org/W2048294992","https://openalex.org/W2054717184","https://openalex.org/W2062354750","https://openalex.org/W2067050128","https://openalex.org/W2067493659","https://openalex.org/W2082298267","https://openalex.org/W3135979946","https://openalex.org/W3136385079"],"related_works":["https://openalex.org/W2020659061","https://openalex.org/W1964001013","https://openalex.org/W2335598698","https://openalex.org/W4233221464","https://openalex.org/W2020785750","https://openalex.org/W4255686303","https://openalex.org/W4253953483","https://openalex.org/W2088414661","https://openalex.org/W3122564619","https://openalex.org/W2952302285"],"abstract_inverted_index":{"The":[0,33,54],"reactions":[1],"of":[2,10,41,59,63,73],"N-hydroxybenzenesulfonamide":[3],"(Piloty's":[4],"acid,":[5],"PA)":[6],"with":[7,26],"a":[8,67],"variety":[9],"metal":[11,31,43],"oxidants":[12],"are":[13],"reported.":[14],"Either":[15],"nitric":[16],"oxide":[17],"or":[18],"nitrite":[19],"is":[20,69],"the":[21,29,38,42],"final":[22],"reaction":[23],"product,":[24],"along":[25],"benzenesulfinate":[27],"and":[28,45,56,78],"reduced":[30],"compound.":[32],"nitrogen":[34],"product":[35],"depends":[36],"on":[37],"oxidation":[39],"potential":[40],"oxidant":[44],"its":[46],"ability":[47],"to":[48,52,80],"further":[49],"oxidize":[50],"NO":[51],"nitrite.":[53],"observation":[55],"preliminary":[57],"interpretation":[58],"unusual":[60],"kinetic":[61],"behavior":[62],"Piloty's":[64],"acid":[65],"as":[66],"reductant":[68],"also":[70,76],"described.":[71],"Analogues":[72],"PA":[74],"were":[75],"prepared":[77],"found":[79],"show":[81],"similar":[82],"reactivity.":[83]},"counts_by_year":[{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":1},{"year":2022,"cited_by_count":1},{"year":2021,"cited_by_count":1},{"year":2018,"cited_by_count":1},{"year":2016,"cited_by_count":3},{"year":2012,"cited_by_count":2}],"updated_date":"2026-08-21T09:56:20.448147","created_date":"2016-06-24T00:00:00"}