{"id":"https://openalex.org/W1970189412","doi":"https://doi.org/10.1021/om4010548","title":"Chiral (\u03b76-p-Cymene)ruthenium(II) Complexes Containing Monodentate Acylthiourea Ligands for Efficient Asymmetric Transfer Hydrogenation of Ketones","display_name":"Chiral (\u03b76-p-Cymene)ruthenium(II) Complexes Containing Monodentate Acylthiourea Ligands for Efficient Asymmetric Transfer Hydrogenation of Ketones","publication_year":2014,"publication_date":"2014-01-08","ids":{"openalex":"https://openalex.org/W1970189412","doi":"https://doi.org/10.1021/om4010548","mag":"1970189412"},"language":"en","primary_location":{"id":"doi:10.1021/om4010548","doi":"https://doi.org/10.1021/om4010548","is_oa":false,"landing_page_url":"https://doi.org/10.1021/om4010548","pdf_url":null,"source":{"id":"https://openalex.org/S4924609","display_name":"Organometallics","issn_l":"0276-7333","issn":["0276-7333","1520-6041"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","norway-2","poland-100","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organometallics","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5076215509","display_name":"Mani Mary Sheeba","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I122964287","display_name":"National Institute of Technology Tiruchirappalli","ror":"https://ror.org/047x65e68","country_code":"IN","type":"education","lineage":["https://openalex.org/I122964287"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"Mani Mary Sheeba","raw_affiliation_strings":["Department of Chemistry, National Institute of Technology, Tiruchirappalli 620015, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, National Institute of Technology, Tiruchirappalli 620015, India","institution_ids":["https://openalex.org/I122964287"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5071156189","display_name":"Manoharan Muthu Tamizh","orcid":"https://orcid.org/0000-0002-0673-5177","observed_orcids":["https://orcid.org/0000-0002-0673-5177"]},"institutions":[{"id":"https://openalex.org/I122964287","display_name":"National Institute of Technology Tiruchirappalli","ror":"https://ror.org/047x65e68","country_code":"IN","type":"education","lineage":["https://openalex.org/I122964287"]},{"id":"https://openalex.org/I4210131147","display_name":"SRM University","ror":"https://ror.org/037skf023","country_code":"IN","type":"education","lineage":["https://openalex.org/I145286018","https://openalex.org/I4210131147"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"Manoharan Muthu Tamizh","raw_affiliation_strings":["Department of Chemistry, National Institute of Technology, Tiruchirappalli 620015, India","Interdisciplinary School of Indian System of Medicine, SRM University, Kattankulathur 603203, India","Interdisciplinary School of Indian System of#R#Medicine, SRM University, Kattankulathur 603203, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, National Institute of Technology, Tiruchirappalli 620015, India","institution_ids":["https://openalex.org/I122964287"]},{"raw_affiliation_string":"Interdisciplinary School of Indian System of Medicine, SRM University, Kattankulathur 603203, India","institution_ids":["https://openalex.org/I4210131147"]},{"raw_affiliation_string":"Interdisciplinary School of Indian System of#R#Medicine, SRM University, Kattankulathur 603203, India","institution_ids":["https://openalex.org/I4210131147"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5083617813","display_name":"Louis J. Farrugia","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I7882870","display_name":"University of Glasgow","ror":"https://ror.org/00vtgdb53","country_code":"GB","type":"education","lineage":["https://openalex.org/I7882870"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"Louis J. Farrugia","raw_affiliation_strings":["WESTChem School of Chemistry, University of Glasgow, Glasgow, G12 8QQ, Scotland, United Kingdom"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"WESTChem School of Chemistry, University of Glasgow, Glasgow, G12 8QQ, Scotland, United Kingdom","institution_ids":["https://openalex.org/I7882870"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5049981252","display_name":"Akira Endo","orcid":"https://orcid.org/0000-0001-9695-4172","observed_orcids":["https://orcid.org/0000-0001-9695-4172"]},"institutions":[{"id":"https://openalex.org/I42999171","display_name":"Sophia University","ror":"https://ror.org/01nckkm68","country_code":"JP","type":"education","lineage":["https://openalex.org/I42999171"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Akira Endo","raw_affiliation_strings":["Department of Materials and Life Sciences, Sophia University, 7-1 Kioicho, Chiyoda-ku, Tokyo 102-8554, Japan","Department of Materials#R#and Life Sciences, Sophia University, 7-1 Kioicho, Chiyoda-ku, Tokyo 102-8554, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Materials and Life Sciences, Sophia University, 7-1 Kioicho, Chiyoda-ku, Tokyo 102-8554, Japan","institution_ids":["https://openalex.org/I42999171"]},{"raw_affiliation_string":"Department of Materials#R#and Life Sciences, Sophia University, 7-1 Kioicho, Chiyoda-ku, Tokyo 102-8554, Japan","institution_ids":["https://openalex.org/I42999171"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5086878929","display_name":"Ramasamy Karvembu","orcid":"https://orcid.org/0000-0001-8966-8602","observed_orcids":["https://orcid.org/0000-0001-8966-8602"]},"institutions":[{"id":"https://openalex.org/I122964287","display_name":"National Institute of Technology Tiruchirappalli","ror":"https://ror.org/047x65e68","country_code":"IN","type":"education","lineage":["https://openalex.org/I122964287"]}],"countries":["IN"],"is_corresponding":true,"raw_author_name":"Ramasamy Karvembu","raw_affiliation_strings":["Department of Chemistry, National Institute of Technology, Tiruchirappalli 620015, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, National Institute of Technology, Tiruchirappalli 620015, India","institution_ids":["https://openalex.org/I122964287"]}]}],"institutions":[],"countries_distinct_count":3,"institutions_distinct_count":4,"corresponding_author_ids":["https://openalex.org/A5086878929"],"corresponding_institution_ids":["https://openalex.org/I122964287"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":3.364,"has_fulltext":false,"cited_by_count":113,"citation_normalized_percentile":{"value":0.93062935,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":96,"max":100},"biblio":{"volume":"33","issue":"2","first_page":"540","last_page":"550"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11281","display_name":"Asymmetric Hydrogenation and Catalysis","score":0.9994999766349792,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11281","display_name":"Asymmetric Hydrogenation and Catalysis","score":0.9994999766349792,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11790","display_name":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/chiral-ruthenium-ii-complexes","display_name":"chiral ruthenium(II) complexes","score":0.9860000014305115},{"id":"https://openalex.org/keywords/asymmetric-transfer-hydrogenation","display_name":"asymmetric transfer hydrogenation","score":0.843999981880188},{"id":"https://openalex.org/keywords/aromatic-ketones","display_name":"aromatic ketones","score":0.9330000281333923},{"id":"https://openalex.org/keywords/chiral-alcohols","display_name":"chiral alcohols","score":0.8009999990463257},{"id":"https://openalex.org/keywords/p-cymene-ruthenium-complexes","display_name":"p-cymene ruthenium complexes","score":0.7070000171661377},{"id":"https://openalex.org/keywords/2-propanol-hydrogen-donor","display_name":"2-propanol hydrogen donor","score":0.6039999723434448},{"id":"https://openalex.org/keywords/asymmetric-catalysis","display_name":"asymmetric catalysis","score":0.8109999895095825}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.939752995967865},{"id":"https://openalex.org/C555196967","wikidata":"https://www.wikidata.org/wiki/Q1086","display_name":"Ruthenium","level":3,"score":0.8088245391845703},{"id":"https://openalex.org/C178516000","wikidata":"https://www.wikidata.org/wiki/Q3023362","display_name":"Denticity","level":3,"score":0.8032958507537842},{"id":"https://openalex.org/C2776715866","wikidata":"https://www.wikidata.org/wiki/Q3143742","display_name":"Transfer hydrogenation","level":4,"score":0.7669430375099182},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.5890398621559143},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.5871016383171082},{"id":"https://openalex.org/C2779953032","wikidata":"https://www.wikidata.org/wiki/Q305364","display_name":"Thiophene","level":2,"score":0.5349750518798828},{"id":"https://openalex.org/C486523","wikidata":"https://www.wikidata.org/wiki/Q494483","display_name":"Enantiomer","level":2,"score":0.5327750444412231},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.5007593631744385},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.44790786504745483},{"id":"https://openalex.org/C146686406","wikidata":"https://www.wikidata.org/wiki/Q898628","display_name":"Enantioselective synthesis","level":3,"score":0.44474703073501587},{"id":"https://openalex.org/C32489680","wikidata":"https://www.wikidata.org/wiki/Q5101833","display_name":"Chiral ligand","level":4,"score":0.4343443810939789},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.407384991645813},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.27879011631011963},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.18219196796417236},{"id":"https://openalex.org/C170493617","wikidata":"https://www.wikidata.org/wiki/Q208467","display_name":"Receptor","level":2,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/om4010548","doi":"https://doi.org/10.1021/om4010548","is_oa":false,"landing_page_url":"https://doi.org/10.1021/om4010548","pdf_url":null,"source":{"id":"https://openalex.org/S4924609","display_name":"Organometallics","issn_l":"0276-7333","issn":["0276-7333","1520-6041"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","norway-2","poland-100","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organometallics","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":140,"referenced_works":["https://openalex.org/W31596692","https://openalex.org/W84703959","https://openalex.org/W1532684710","https://openalex.org/W1539796472","https://openalex.org/W1786162208","https://openalex.org/W1957759356","https://openalex.org/W1963540684","https://openalex.org/W1964869980","https://openalex.org/W1966302049","https://openalex.org/W1968655363","https://openalex.org/W1973085336","https://openalex.org/W1974832894","https://openalex.org/W1975922969","https://openalex.org/W1977076547","https://openalex.org/W1979248984","https://openalex.org/W1984105513","https://openalex.org/W1988529340","https://openalex.org/W1989303320","https://openalex.org/W1990170643","https://openalex.org/W1990520630","https://openalex.org/W1990715565","https://openalex.org/W1992039036","https://openalex.org/W1993835123","https://openalex.org/W1995655398","https://openalex.org/W1995822687","https://openalex.org/W1996593532","https://openalex.org/W1999400954","https://openalex.org/W2000263654","https://openalex.org/W2001211140","https://openalex.org/W2002290813","https://openalex.org/W2003269576","https://openalex.org/W2003638963","https://openalex.org/W2004762913","https://openalex.org/W2006051124","https://openalex.org/W2007042952","https://openalex.org/W2011107126","https://openalex.org/W2011344922","https://openalex.org/W2011437849","https://openalex.org/W2012785151","https://openalex.org/W2013160605","https://openalex.org/W2013781623","https://openalex.org/W2014568782","https://openalex.org/W2014878853","https://openalex.org/W2017638672","https://openalex.org/W2018736044","https://openalex.org/W2019319389","https://openalex.org/W2020294161","https://openalex.org/W2021497305","https://openalex.org/W2022511233","https://openalex.org/W2023174370","https://openalex.org/W2023749745","https://openalex.org/W2025469282","https://openalex.org/W2028257896","https://openalex.org/W2029629979","https://openalex.org/W2030036303","https://openalex.org/W2030173183","https://openalex.org/W2030259467","https://openalex.org/W2030590215","https://openalex.org/W2032541221","https://openalex.org/W2033288172","https://openalex.org/W2033482065","https://openalex.org/W2035747345","https://openalex.org/W2036626807","https://openalex.org/W2041905889","https://openalex.org/W2043533637","https://openalex.org/W2043989603","https://openalex.org/W2044808060","https://openalex.org/W2045283569","https://openalex.org/W2048541781","https://openalex.org/W2053502432","https://openalex.org/W2054674087","https://openalex.org/W2054713137","https://openalex.org/W2055568399","https://openalex.org/W2057623886","https://openalex.org/W2057750824","https://openalex.org/W2060470103","https://openalex.org/W2061312817","https://openalex.org/W2061538353","https://openalex.org/W2061904404","https://openalex.org/W2065489777","https://openalex.org/W2067416688","https://openalex.org/W2070634928","https://openalex.org/W2071690550","https://openalex.org/W2071772821","https://openalex.org/W2076912405","https://openalex.org/W2077452337","https://openalex.org/W2084708787","https://openalex.org/W2084935596","https://openalex.org/W2085538761","https://openalex.org/W2085923279","https://openalex.org/W2089259902","https://openalex.org/W2090568434","https://openalex.org/W2092429837","https://openalex.org/W2094845874","https://openalex.org/W2102656055","https://openalex.org/W2104564750","https://openalex.org/W2104692042","https://openalex.org/W2107021329","https://openalex.org/W2109678986","https://openalex.org/W2110841167","https://openalex.org/W2115132894","https://openalex.org/W2117905954","https://openalex.org/W2122077015","https://openalex.org/W2123331774","https://openalex.org/W2125116664","https://openalex.org/W2129177377","https://openalex.org/W2131350133","https://openalex.org/W2131822949","https://openalex.org/W2134013564","https://openalex.org/W2134883502","https://openalex.org/W2137260662","https://openalex.org/W2138520660","https://openalex.org/W2142819264","https://openalex.org/W2144332006","https://openalex.org/W2145096901","https://openalex.org/W2145468040","https://openalex.org/W2145599788","https://openalex.org/W2146743772","https://openalex.org/W2147618695","https://openalex.org/W2148947737","https://openalex.org/W2152744937","https://openalex.org/W2154881052","https://openalex.org/W2159291200","https://openalex.org/W2163678115","https://openalex.org/W2164092305","https://openalex.org/W2165974437","https://openalex.org/W2166810059","https://openalex.org/W2324839637","https://openalex.org/W2328811722","https://openalex.org/W2331314384","https://openalex.org/W2334882085","https://openalex.org/W2949374028","https://openalex.org/W2949819306","https://openalex.org/W2949840789","https://openalex.org/W2951175380","https://openalex.org/W2951213605","https://openalex.org/W2951457831","https://openalex.org/W2953003904","https://openalex.org/W2953286071","https://openalex.org/W4251459638"],"related_works":["https://openalex.org/W2905238385","https://openalex.org/W2051575670","https://openalex.org/W2025387765","https://openalex.org/W2062727730","https://openalex.org/W2900520495","https://openalex.org/W2084708787","https://openalex.org/W2029629979","https://openalex.org/W2218808669","https://openalex.org/W2173803843","https://openalex.org/W4200230591"],"abstract_inverted_index":{"The":[0,52,80,92,148],"new":[1],"chiral":[2,49,53,65,176],"ligands":[3,66,97,139],"(":[4,11,16,23,29,36,73],"R":[5,17,30],")-/(":[6,18,31],"S":[7,19,32],")-":[8,20,33],"N":[9,21,34],"-((1-phenylethyl)carbamothioyl)benzamide":[10],"L1":[12,67,98],"/":[13,25,38],"L2":[14],"),":[15,27],"-((1-phenylethyl)carbamothioyl)thiophene-2-carboxamide":[22],"L3":[24,100],"L4":[26],"and":[28,44,70,86,99,101,105,172,189],"-((1-phenylethyl)carbamothioyl)furan-2-carboxamide":[35],"L5":[37],"L6":[39,69],")":[40],"were":[41,59,82,107],"synthesized,":[42],"characterized,":[43],"used":[45],"to":[46,123,174,187,194],"prepare":[47],"novel":[48],"Ru(II)":[50,54,125,149],"complexes.":[51],"complexes":[55,81,102,150],"1":[56,151],"\u2013":[57,68,152],"6":[58,106,153],"obtained":[60],"from":[61],"reactions":[62],"between":[63],"the":[64,96,117,119,124,129,137,143,160,168,180],"[RuCl":[71],"2":[72,76,78],"p":[74],"-cymene)":[75],"]":[77],".":[79],"characterized":[83],"by":[84,109],"analytical":[85],"spectroscopic":[87],"(NMR,":[88],"FT-IR,":[89],"electronic)":[90],"techniques.":[91],"solid-state":[93],"structures":[94],"of":[95,116,136,164,170,179,185,192],"1,":[103],"4,":[104],"determined":[108],"single-crystal":[110],"X-ray":[111],"diffraction":[112],"methods.":[113],"In":[114],"all":[115,154],"complexes,":[118],"ligand":[120],"is":[121],"bound":[122],"center":[126],"only":[127],"via":[128],"sulfur":[130],"donor":[131],"atom.":[132],"This":[133],"monodentate":[134],"coordination":[135],"acylthiourea":[138],"was":[140],"observed":[141],"for":[142,159],"first":[144],"time":[145],"with":[146],"ruthenium.":[147],"act":[155],"as":[156],"efficient":[157],"catalysts":[158,181],"asymmetric":[161],"transfer":[162],"hydrogenation":[163],"aromatic":[165],"ketones":[166],"in":[167],"presence":[169],"2-propanol":[171],"KOH":[173],"produce":[175],"alcohols.":[177],"All":[178],"showed":[182],"excellent":[183],"conversions":[184],"up":[186,193],"99%":[188],"enantiomeric":[190],"excesses":[191],"99%.":[195]},"counts_by_year":[{"year":2026,"cited_by_count":3},{"year":2025,"cited_by_count":11},{"year":2024,"cited_by_count":9},{"year":2023,"cited_by_count":7},{"year":2022,"cited_by_count":6},{"year":2021,"cited_by_count":9},{"year":2020,"cited_by_count":9},{"year":2019,"cited_by_count":15},{"year":2018,"cited_by_count":18},{"year":2017,"cited_by_count":3},{"year":2016,"cited_by_count":12},{"year":2015,"cited_by_count":7},{"year":2014,"cited_by_count":4}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2016-06-24T00:00:00"}
