{"id":"https://openalex.org/W1968678564","doi":"https://doi.org/10.1002/app.1995.070581116","title":"Mixed initiator approach to the surfactant\u2010free semicontinuous emulsion polymerization of large MMA/BA particles","display_name":"Mixed initiator approach to the surfactant\u2010free semicontinuous emulsion polymerization of large MMA/BA particles","publication_year":1995,"publication_date":"1995-12-12","ids":{"openalex":"https://openalex.org/W1968678564","doi":"https://doi.org/10.1002/app.1995.070581116","mag":"1968678564"},"language":"en","primary_location":{"id":"doi:10.1002/app.1995.070581116","doi":"https://doi.org/10.1002/app.1995.070581116","is_oa":false,"landing_page_url":"https://doi.org/10.1002/app.1995.070581116","pdf_url":null,"source":{"id":"https://openalex.org/S200764475","display_name":"Journal of Applied Polymer Science","issn_l":"0021-8995","issn":["0021-8995","1097-4628"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","norway-1","poland-70","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Applied Polymer Science","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5057436470","display_name":"Kenneth J. O'Callaghan","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I151746483","display_name":"University of Waterloo","ror":"https://ror.org/01aff2v68","country_code":"CA","type":"education","lineage":["https://openalex.org/I151746483"]}],"countries":["CA"],"is_corresponding":false,"raw_author_name":"K. J. O'Callaghan","raw_affiliation_strings":["Department of Chemistry, University of Waterloo, Waterloo, ON N2L 3G1, Canada"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Waterloo, Waterloo, ON N2L 3G1, Canada","institution_ids":["https://openalex.org/I151746483"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5064839233","display_name":"Anthony James Paine","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210159094","display_name":"Xerox (Canada)","ror":"https://ror.org/04z9w5078","country_code":"CA","type":"company","lineage":["https://openalex.org/I4210132870","https://openalex.org/I4210159094"]}],"countries":["CA"],"is_corresponding":false,"raw_author_name":"A. J. Paine","raw_affiliation_strings":["Xerox Research Centre of Canada, 2660 Speakman Drive, Mississauga, ON L5K 2L1, Canada"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Xerox Research Centre of Canada, 2660 Speakman Drive, Mississauga, ON L5K 2L1, Canada","institution_ids":["https://openalex.org/I4210159094"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5108351113","display_name":"Alfred Rudin","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I151746483","display_name":"University of Waterloo","ror":"https://ror.org/01aff2v68","country_code":"CA","type":"education","lineage":["https://openalex.org/I151746483"]}],"countries":["CA"],"is_corresponding":true,"raw_author_name":"A. Rudin","raw_affiliation_strings":["Department of Chemistry, University of Waterloo, Waterloo, ON N2L 3G1, Canada"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Waterloo, Waterloo, ON N2L 3G1, Canada","institution_ids":["https://openalex.org/I151746483"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5108351113"],"corresponding_institution_ids":["https://openalex.org/I151746483"],"apc_list":{"value":4140,"currency":"USD","value_usd":4140},"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":17,"citation_normalized_percentile":{"value":0.12019291,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":93},"biblio":{"volume":"58","issue":"11","first_page":"2047","last_page":"2055"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11915","display_name":"Pickering emulsions and particle stabilization","score":0.5845000147819519,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11915","display_name":"Pickering emulsions and particle stabilization","score":0.5845000147819519,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.3905999958515167,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T14303","display_name":"Polymer Synthesis and Characterization","score":0.015699999406933784,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/emulsion-polymerization","display_name":"emulsion polymerization","score":0.7929999828338623},{"id":"https://openalex.org/keywords/surfactant-free-polymerization","display_name":"surfactant-free polymerization","score":0.9229999780654907},{"id":"https://openalex.org/keywords/azobisisobutyronitrile","display_name":"azobisisobutyronitrile","score":0.7419999837875366},{"id":"https://openalex.org/keywords/ammonium-persulfate","display_name":"ammonium persulfate","score":0.9990000128746033},{"id":"https://openalex.org/keywords/seed-mediated-growth","display_name":"seed-mediated growth","score":0.7609999775886536},{"id":"https://openalex.org/keywords/high-solid-content","display_name":"high solid content","score":0.843999981880188},{"id":"https://openalex.org/keywords/particle-surface-area","display_name":"particle surface area","score":0.44600000977516174}],"concepts":[{"id":"https://openalex.org/C2780023803","wikidata":"https://www.wikidata.org/wiki/Q412085","display_name":"Ammonium persulfate","level":4,"score":0.7936135530471802},{"id":"https://openalex.org/C199002037","wikidata":"https://www.wikidata.org/wiki/Q910678","display_name":"Emulsion polymerization","level":4,"score":0.7905834913253784},{"id":"https://openalex.org/C11432220","wikidata":"https://www.wikidata.org/wiki/Q1975334","display_name":"Dispersity","level":2,"score":0.7854917049407959},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.6508039236068726},{"id":"https://openalex.org/C44228677","wikidata":"https://www.wikidata.org/wiki/Q181898","display_name":"Polymerization","level":3,"score":0.5668853521347046},{"id":"https://openalex.org/C15920480","wikidata":"https://www.wikidata.org/wiki/Q421281","display_name":"Copolymer","level":3,"score":0.5525944232940674},{"id":"https://openalex.org/C58226133","wikidata":"https://www.wikidata.org/wiki/Q1324199","display_name":"Pulmonary surfactant","level":2,"score":0.540695309638977},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.5284141302108765},{"id":"https://openalex.org/C187530423","wikidata":"https://www.wikidata.org/wiki/Q7140503","display_name":"Particle size","level":2,"score":0.49944114685058594},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.4731522500514984},{"id":"https://openalex.org/C111998727","wikidata":"https://www.wikidata.org/wiki/Q2620998","display_name":"Radical polymerization","level":4,"score":0.4527367651462555},{"id":"https://openalex.org/C2778123984","wikidata":"https://www.wikidata.org/wiki/Q187634","display_name":"Emulsion","level":2,"score":0.4463891386985779},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.4447753131389618},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.38774627447128296},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.1331261396408081},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.07173967361450195},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/app.1995.070581116","doi":"https://doi.org/10.1002/app.1995.070581116","is_oa":false,"landing_page_url":"https://doi.org/10.1002/app.1995.070581116","pdf_url":null,"source":{"id":"https://openalex.org/S200764475","display_name":"Journal of Applied Polymer Science","issn_l":"0021-8995","issn":["0021-8995","1097-4628"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","norway-1","poland-70","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Applied Polymer Science","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":19,"referenced_works":["https://openalex.org/W1486598704","https://openalex.org/W1970634760","https://openalex.org/W1990103871","https://openalex.org/W2013856352","https://openalex.org/W2018299804","https://openalex.org/W2033111669","https://openalex.org/W2040954613","https://openalex.org/W2059254023","https://openalex.org/W2066038669","https://openalex.org/W2069230025","https://openalex.org/W2070370786","https://openalex.org/W2088656858","https://openalex.org/W2092276629","https://openalex.org/W2098004687","https://openalex.org/W2108990444","https://openalex.org/W2115759974","https://openalex.org/W2126397529","https://openalex.org/W2132250292","https://openalex.org/W4245991247"],"related_works":["https://openalex.org/W2066879746","https://openalex.org/W2753674430","https://openalex.org/W2025417939","https://openalex.org/W2025953348","https://openalex.org/W2036986829","https://openalex.org/W1998249787","https://openalex.org/W1966892959","https://openalex.org/W2374052067","https://openalex.org/W1813351280","https://openalex.org/W1988717346"],"abstract_inverted_index":{"Abstract":[0],"The":[1,55,77],"emulsion":[2],"polymerization":[3,62],"of":[4,21,34,41,60,79,95,99,101],"large":[5],"monodisperse":[6,30],"MMA/BA":[7],"copolymer":[8],"particles":[9,31,72],"by":[10],"surfactant\u2010free":[11],"means":[12],"at":[13,35],"high":[14],"solids":[15],"content":[16],"is":[17],"described.":[18],"A":[19,39],"series":[20],"sequential":[22],"seeded":[23],"growth":[24,87],"reactions":[25],"were":[26],"used":[27,84],"to":[28,82,104],"obtain":[29],"with":[32],"diameters":[33],"least":[36],"3":[37],"microns.":[38],"combination":[40],"an":[42],"oil\u2010soluble":[43],"initiator,":[44,49],"AIBN,":[45],"and":[46,63],"a":[47,93,96],"water\u2010soluble":[48],"ammonium":[50],"persulfate":[51],"(AP),":[52],"was":[53,89],"used.":[54],"AIBN":[56],"initiated":[57],"the":[58,61,64,67,70,105],"bulk":[59],"AP":[65,80],"provided":[66],"stabilization":[68],"for":[69],"polymer":[71,106],"through":[73],"its":[74],"charged":[75],"endgroups.":[76],"amount":[78],"initiator":[81],"be":[83],"in":[85],"each":[86],"step":[88],"calculated":[90],"empirically":[91],"using":[92],"criterion":[94],"constant":[97],"ratio":[98],"moles":[100],"sulfate":[102],"groups":[103],"particle":[107],"surface":[108],"area.":[109],"\u00a9":[110],"1995":[111],"John":[112],"Wiley":[113],"&":[114],"Sons,":[115],"Inc.":[116]},"counts_by_year":[{"year":2012,"cited_by_count":1}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2016-06-24T00:00:00"}