{"id":"https://openalex.org/W1967480333","doi":"https://doi.org/10.1021/la500476u","title":"Observing Phthalate Leaching from Plasticized Polymer Films at the Molecular Level","display_name":"Observing Phthalate Leaching from Plasticized Polymer Films at the Molecular Level","publication_year":2014,"publication_date":"2014-04-12","ids":{"openalex":"https://openalex.org/W1967480333","doi":"https://doi.org/10.1021/la500476u","mag":"1967480333","pmid":"https://pubmed.ncbi.nlm.nih.gov/24725143"},"language":"en","primary_location":{"id":"doi:10.1021/la500476u","doi":"https://doi.org/10.1021/la500476u","is_oa":false,"landing_page_url":"https://doi.org/10.1021/la500476u","pdf_url":null,"source":{"id":"https://openalex.org/S75741262","display_name":"Langmuir","issn_l":"0743-7463","issn":["0743-7463","1520-5827"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","doyens","jufo-2","ki-jl-1","medline","norway-1","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Langmuir","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5100622027","display_name":"Xiaoxian Zhang","orcid":"https://orcid.org/0000-0002-4215-8274","observed_orcids":["https://orcid.org/0000-0002-4215-8274","https://orcid.org/0000-0002-3916-8463"]},"institutions":[{"id":"https://openalex.org/I27837315","display_name":"University of Michigan","ror":"https://ror.org/00jmfr291","country_code":"US","type":"education","lineage":["https://openalex.org/I27837315"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Xiaoxian Zhang","raw_affiliation_strings":["Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109, United States","institution_ids":["https://openalex.org/I27837315"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5054123780","display_name":"Zhan Chen","orcid":"https://orcid.org/0000-0001-8687-8348","observed_orcids":["https://orcid.org/0000-0001-8687-8348"]},"institutions":[{"id":"https://openalex.org/I27837315","display_name":"University of Michigan","ror":"https://ror.org/00jmfr291","country_code":"US","type":"education","lineage":["https://openalex.org/I27837315"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Zhan Chen","raw_affiliation_strings":["Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109, United States","institution_ids":["https://openalex.org/I27837315"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5054123780"],"corresponding_institution_ids":["https://openalex.org/I27837315"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":3.953,"has_fulltext":false,"cited_by_count":69,"citation_normalized_percentile":{"value":0.93358634,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":89,"max":99},"biblio":{"volume":"30","issue":"17","first_page":"4933","last_page":"4944"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T13171","display_name":"Polymer Science and PVC","score":0.9907000064849854,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T13171","display_name":"Polymer Science and PVC","score":0.9907000064849854,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10686","display_name":"Effects and risks of endocrine disrupting chemicals","score":0.00839999970048666,"subfield":{"id":"https://openalex.org/subfields/2307","display_name":"Health, Toxicology and Mutagenesis"},"field":{"id":"https://openalex.org/fields/23","display_name":"Environmental Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11177","display_name":"Spectroscopy and Quantum Chemical Studies","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/polyvinyl-chloride","display_name":"polyvinyl chloride","score":0.8619999885559082},{"id":"https://openalex.org/keywords/plasticizers","display_name":"plasticizers","score":0.8420000076293945},{"id":"https://openalex.org/keywords/diethyl-phthalate","display_name":"diethyl phthalate","score":0.984000027179718},{"id":"https://openalex.org/keywords/dibutyl-phthalate","display_name":"dibutyl phthalate","score":1.0},{"id":"https://openalex.org/keywords/oxygen-plasma-surface-treatment","display_name":"oxygen plasma surface treatment","score":0.8500000238418579},{"id":"https://openalex.org/keywords/environmental-contaminants","display_name":"environmental pollutants","score":0.41999998688697815},{"id":"https://openalex.org/keywords/sum-frequency-generation-spectroscopy","display_name":"sum frequency generation spectroscopy","score":0.7590000033378601}],"concepts":[{"id":"https://openalex.org/C2781005124","wikidata":"https://www.wikidata.org/wiki/Q84483575","display_name":"Phthalate","level":2,"score":0.8096027374267578},{"id":"https://openalex.org/C90982505","wikidata":"https://www.wikidata.org/wiki/Q16938886","display_name":"Leaching (pedology)","level":3,"score":0.7039008140563965},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.6923844814300537},{"id":"https://openalex.org/C58968531","wikidata":"https://www.wikidata.org/wiki/Q910212","display_name":"Plasticizer","level":2,"score":0.6585517525672913},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.5844520926475525},{"id":"https://openalex.org/C2776481364","wikidata":"https://www.wikidata.org/wiki/Q419811","display_name":"Diethyl phthalate","level":3,"score":0.5673620104789734},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.4371100664138794},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.4315970540046692},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.41336938738822937},{"id":"https://openalex.org/C126348684","wikidata":"https://www.wikidata.org/wiki/Q3456979","display_name":"Polymer science","level":1,"score":0.35215675830841064},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.2647170424461365},{"id":"https://openalex.org/C39432304","wikidata":"https://www.wikidata.org/wiki/Q188847","display_name":"Environmental science","level":0,"score":0.10962536931037903},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0},{"id":"https://openalex.org/C159390177","wikidata":"https://www.wikidata.org/wiki/Q9161265","display_name":"Soil science","level":1,"score":0.0},{"id":"https://openalex.org/C159750122","wikidata":"https://www.wikidata.org/wiki/Q96621023","display_name":"Soil water","level":2,"score":0.0}],"mesh":[{"descriptor_ui":"D008567","descriptor_name":"Membranes, Artificial","qualifier_ui":null,"qualifier_name":null,"is_major_topic":true},{"descriptor_ui":"D010755","descriptor_name":"Organophosphates","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D010795","descriptor_name":"Phthalic Acids","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D010968","descriptor_name":"Plasticizers","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D011108","descriptor_name":"Polymers","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true}],"locations_count":2,"locations":[{"id":"doi:10.1021/la500476u","doi":"https://doi.org/10.1021/la500476u","is_oa":false,"landing_page_url":"https://doi.org/10.1021/la500476u","pdf_url":null,"source":{"id":"https://openalex.org/S75741262","display_name":"Langmuir","issn_l":"0743-7463","issn":["0743-7463","1520-5827"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","doyens","jufo-2","ki-jl-1","medline","norway-1","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Langmuir","raw_type":"journal-article"},{"id":"pmid:24725143","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/24725143","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Langmuir : the ACS journal of surfaces and colloids","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[{"id":"https://metadata.un.org/sdg/12","score":0.5925999879837036,"display_name":"Responsible consumption and production"}],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":43,"referenced_works":["https://openalex.org/W177270658","https://openalex.org/W1511905418","https://openalex.org/W1959181161","https://openalex.org/W1968637523","https://openalex.org/W1970004609","https://openalex.org/W1975805501","https://openalex.org/W1983200449","https://openalex.org/W1990445509","https://openalex.org/W1996139616","https://openalex.org/W2003364885","https://openalex.org/W2003536240","https://openalex.org/W2008577210","https://openalex.org/W2010033656","https://openalex.org/W2013963844","https://openalex.org/W2019566628","https://openalex.org/W2029372637","https://openalex.org/W2034470409","https://openalex.org/W2034681771","https://openalex.org/W2036080540","https://openalex.org/W2040558970","https://openalex.org/W2043337062","https://openalex.org/W2048239931","https://openalex.org/W2048981720","https://openalex.org/W2056154520","https://openalex.org/W2058472473","https://openalex.org/W2058758040","https://openalex.org/W2066512277","https://openalex.org/W2073629778","https://openalex.org/W2074888815","https://openalex.org/W2076245465","https://openalex.org/W2086125825","https://openalex.org/W2093374359","https://openalex.org/W2098908528","https://openalex.org/W2107504570","https://openalex.org/W2111637658","https://openalex.org/W2115706239","https://openalex.org/W2150850983","https://openalex.org/W2154057981","https://openalex.org/W2155321186","https://openalex.org/W2162966347","https://openalex.org/W2167793260","https://openalex.org/W2314497853","https://openalex.org/W2315141984"],"related_works":["https://openalex.org/W2315141984","https://openalex.org/W1832745035","https://openalex.org/W2078415851","https://openalex.org/W2314497853","https://openalex.org/W1966041450","https://openalex.org/W2330125954","https://openalex.org/W2155305008","https://openalex.org/W4375825641","https://openalex.org/W3131686652","https://openalex.org/W2110658266"],"abstract_inverted_index":{"Phthalates,":[0],"the":[1,35,66,87,102,141,156,162,175,183,202,208,267],"most":[2,206],"widely":[3],"used":[4],"plasticizers":[5],"in":[6,126,174,253],"poly(vinyl":[7],"chloride)":[8],"(PVC),":[9],"have":[10],"been":[11],"extensively":[12],"studied.":[13,95],"In":[14],"this":[15],"paper,":[16],"a":[17,149,259],"highly":[18,260],"sensitive,":[19],"easy,":[20],"and":[21,47,54,82,229,275,286],"effective":[22],"method":[23,262,281],"was":[24,98],"developed":[25,282],"to":[26,100,106,136,140,180,194,263,290],"examine":[27],"short-term":[28],"phthalate":[29,67,80,84,112,215,239],"leaching":[30,68,74,113,190,203,216,240],"from":[31,86,114,143,182,217,241],"PVC/phthalate":[32,59,88,103,127],"films":[33,60,89,219],"at":[34,145,148,266],"molecular":[36,56,268,277],"level":[37,269],"using":[38],"sum":[39],"frequency":[40],"generation":[41],"vibrational":[42],"spectroscopy":[43,51],"(SFG).":[44],"Combining":[45],"SFG":[46],"Fourier":[48],"transform":[49],"infrared":[50],"(FTIR),":[52],"surface":[53,274],"bulk":[55,157,167,225,244,276],"structures":[57],"of":[58,76,227,237,294],"were":[61,94,133],"also":[62,235],"comprehensively":[63],"evaluated":[64],"during":[65],"process":[69],"under":[70],"various":[71,91],"environments.":[72],"The":[73,280],"processes":[75],"two":[77],"phthalates,":[78],"diethyl":[79],"(DEP)":[81],"dibutyl":[83],"(DBP),":[85],"with":[90,223],"weight":[92],"ratios":[93],"Oxygen":[96],"plasma":[97,210],"applied":[99,289],"treat":[101],"film":[104,185],"surfaces":[105],"verify":[107],"its":[108],"efficacy":[109],"on":[110],"preventing/reducing":[111],"PVC.":[115],"Our":[116],"results":[117],"show":[118],"that":[119],"DBP":[120,131,158,163,166,172,189,243,252],"is":[121,191,234,284],"more":[122,186],"stable":[123,171],"than":[124,153],"DEP":[125],"films.":[128],"Even":[129],"so,":[130],"molecules":[132,173,179],"still":[134],"found":[135],"very":[137,192],"slowly":[138],"leach":[139,181],"environment":[142],"PVC":[144,176,218,246],"30":[146,230],"\u00b0C,":[147],"rate":[150],"much":[151],"slower":[152],"DEP.":[154],"Also,":[155],"content":[159],"substantially":[160],"influences":[161],"leaching.":[164],"Higher":[165],"concentration":[168,245],"yields":[169],"less":[170],"matrix,":[177],"allowing":[178],"polymer":[184],"easily.":[187],"Additionally,":[188],"sensitive":[193,261],"temperature":[195,198],"changes;":[196],"higher":[197],"can":[199,212,287],"strongly":[200],"enhance":[201],"process.":[204],"For":[205],"cases,":[207],"oxygen":[209],"treatment":[211],"effectively":[213],"prevent":[214],"(e.g.,":[220,248],"for":[221],"samples":[222,247],"low":[224],"concentrations":[226],"DBP-5":[228],"wt":[231,250],"%).":[232],"It":[233],"capable":[236],"reducing":[238],"high":[242],"70":[249],"%":[251],"PVC/DBP":[254],"mixture).":[255],"This":[256],"research":[257],"develops":[258],"detect":[264,291],"chemicals":[265],"as":[270,272],"well":[271],"provides":[273],"structural":[278],"changes.":[279],"here":[283],"general":[285],"be":[288],"small":[292],"amounts":[293],"chemical/biological":[295],"environmental":[296],"contaminants.":[297]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2025,"cited_by_count":6},{"year":2024,"cited_by_count":10},{"year":2023,"cited_by_count":8},{"year":2022,"cited_by_count":10},{"year":2021,"cited_by_count":11},{"year":2020,"cited_by_count":2},{"year":2019,"cited_by_count":1},{"year":2018,"cited_by_count":2},{"year":2017,"cited_by_count":4},{"year":2016,"cited_by_count":4},{"year":2015,"cited_by_count":8},{"year":2014,"cited_by_count":2}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2016-06-24T00:00:00"}