{"id":"https://openalex.org/W1966095412","doi":"https://doi.org/10.1039/b809265f","title":"Excellent chiralselectivity in sulfur-bridged CoIIIMCoIII (M = NiII and PdII) trinuclear complexes containing 1,2-cyclohexanediamine","display_name":"Excellent chiralselectivity in sulfur-bridged CoIIIMCoIII (M = NiII and PdII) trinuclear complexes containing 1,2-cyclohexanediamine","publication_year":2008,"publication_date":"2008-01-01","ids":{"openalex":"https://openalex.org/W1966095412","doi":"https://doi.org/10.1039/b809265f","mag":"1966095412","pmid":"https://pubmed.ncbi.nlm.nih.gov/18985264"},"language":"en","primary_location":{"id":"doi:10.1039/b809265f","doi":"https://doi.org/10.1039/b809265f","is_oa":false,"landing_page_url":"https://doi.org/10.1039/b809265f","pdf_url":null,"source":{"id":"https://openalex.org/S166159787","display_name":"Dalton Transactions","issn_l":"1477-9226","issn":["1477-9226","1477-9234"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","ki-jl-1","medline","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Dalton Transactions","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5021195091","display_name":"A. Igashira-Kamiyama","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I98285908","display_name":"The University of Osaka","ror":"https://ror.org/035t8zc32","country_code":"JP","type":"education","lineage":["https://openalex.org/I98285908"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Asako Igashira-Kamiyama","raw_affiliation_strings":["Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan","Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka,,Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan","institution_ids":["https://openalex.org/I98285908"]},{"raw_affiliation_string":"Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka,,Japan","institution_ids":["https://openalex.org/I98285908"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5070043913","display_name":"Toshihiro Tamai","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I98285908","display_name":"The University of Osaka","ror":"https://ror.org/035t8zc32","country_code":"JP","type":"education","lineage":["https://openalex.org/I98285908"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Toshihiro Tamai","raw_affiliation_strings":["Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka, Japan","Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka,,Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka, Japan","institution_ids":["https://openalex.org/I98285908"]},{"raw_affiliation_string":"Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka,,Japan","institution_ids":["https://openalex.org/I98285908"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5110028584","display_name":"Tatsuya Kawamoto","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I41802502","display_name":"Kanagawa University","ror":"https://ror.org/02j6c0d67","country_code":"JP","type":"education","lineage":["https://openalex.org/I41802502"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Tatsuya Kawamoto","raw_affiliation_strings":["Department of Chemistry, Faculty of Science, Kanagawa University, Hiratsuka, Kanagawa, Japan","Department of Chemistry, Faculty of Science , Kanagawa University , Hiratsuka, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Faculty of Science, Kanagawa University, Hiratsuka, Kanagawa, Japan","institution_ids":["https://openalex.org/I41802502"]},{"raw_affiliation_string":"Department of Chemistry, Faculty of Science , Kanagawa University , Hiratsuka, Japan","institution_ids":["https://openalex.org/I41802502"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5090678127","display_name":"Takumi Konno","orcid":"https://orcid.org/0000-0003-4612-5418","observed_orcids":["https://orcid.org/0000-0003-4612-5418"]},"institutions":[{"id":"https://openalex.org/I98285908","display_name":"The University of Osaka","ror":"https://ror.org/035t8zc32","country_code":"JP","type":"education","lineage":["https://openalex.org/I98285908"]}],"countries":["JP"],"is_corresponding":true,"raw_author_name":"Takumi Konno","raw_affiliation_strings":["Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka, Japan","Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka,,Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka, Japan","institution_ids":["https://openalex.org/I98285908"]},{"raw_affiliation_string":"Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka,,Japan","institution_ids":["https://openalex.org/I98285908"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5090678127"],"corresponding_institution_ids":["https://openalex.org/I98285908"],"apc_list":null,"apc_paid":null,"fwci":0.9501,"has_fulltext":false,"cited_by_count":10,"citation_normalized_percentile":{"value":0.73139501,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":96},"biblio":{"volume":null,"issue":"44","first_page":"6305","last_page":"6305"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.3869999945163727,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.3869999945163727,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10464","display_name":"Crystal structures of chemical compounds","score":0.12520000338554382,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.12060000002384186,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/trinuclear-complexes","display_name":"trinuclear complexes","score":0.7609999775886536},{"id":"https://openalex.org/keywords/sulfur-bridged-complexes","display_name":"sulfur-bridged complexes","score":0.8859999775886536},{"id":"https://openalex.org/keywords/chirality-transfer","display_name":"chirality transfer","score":0.7009999752044678},{"id":"https://openalex.org/keywords/1-2-cyclohexanediamine","display_name":"1,2-cyclohexanediamine","score":0.9509999752044678},{"id":"https://openalex.org/keywords/2-aminoethanethiolate","display_name":"2-aminoethanethiolate","score":0.8840000033378601},{"id":"https://openalex.org/keywords/nickel-ii-complexes","display_name":"nickel(II) complexes","score":0.6700000166893005},{"id":"https://openalex.org/keywords/palladium-ii-complexes","display_name":"palladium(II) complexes","score":0.9980000257492065},{"id":"https://openalex.org/keywords/cobalt-iii-complexes","display_name":"cobalt(III) complexes","score":0.8859999775886536},{"id":"https://openalex.org/keywords/delta-configuration","display_name":"delta configuration","score":0.6000000238418579},{"id":"https://openalex.org/keywords/enantioselectivity","display_name":"enantioselectivity","score":0.6819999814033508},{"id":"https://openalex.org/keywords/racemic-ligands","display_name":"racemic ligands","score":0.6340000033378601},{"id":"https://openalex.org/keywords/stereocontrol","display_name":"stereocontrol","score":0.40799999237060547},{"id":"https://openalex.org/keywords/crystal-structure","display_name":"crystal structure","score":0.6079999804496765}],"concepts":[{"id":"https://openalex.org/C124668440","wikidata":"https://www.wikidata.org/wiki/Q2305173","display_name":"Chirality (physics)","level":5,"score":0.7643892765045166},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7052815556526184},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.6623958349227905},{"id":"https://openalex.org/C486523","wikidata":"https://www.wikidata.org/wiki/Q494483","display_name":"Enantiomer","level":2,"score":0.6330596208572388},{"id":"https://openalex.org/C518881349","wikidata":"https://www.wikidata.org/wiki/Q682","display_name":"Sulfur","level":2,"score":0.523411750793457},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.500906229019165},{"id":"https://openalex.org/C2778564446","wikidata":"https://www.wikidata.org/wiki/Q2305173","display_name":"Chiral symmetry","level":3,"score":0.09079596400260925},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.06943786144256592},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.04777812957763672},{"id":"https://openalex.org/C20621625","wikidata":"https://www.wikidata.org/wiki/Q6961432","display_name":"Nambu\u2013Jona-Lasinio model","level":4,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C7602139","wikidata":"https://www.wikidata.org/wiki/Q6718","display_name":"Quark","level":2,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1039/b809265f","doi":"https://doi.org/10.1039/b809265f","is_oa":false,"landing_page_url":"https://doi.org/10.1039/b809265f","pdf_url":null,"source":{"id":"https://openalex.org/S166159787","display_name":"Dalton Transactions","issn_l":"1477-9226","issn":["1477-9226","1477-9234"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","ki-jl-1","medline","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Dalton Transactions","raw_type":"journal-article"},{"id":"pmid:18985264","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/18985264","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Dalton transactions (Cambridge, England : 2003)","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":27,"referenced_works":["https://openalex.org/W1965047546","https://openalex.org/W1968265760","https://openalex.org/W1968882172","https://openalex.org/W1969635440","https://openalex.org/W1985189014","https://openalex.org/W1989573466","https://openalex.org/W2006601548","https://openalex.org/W2012545443","https://openalex.org/W2019508975","https://openalex.org/W2022527870","https://openalex.org/W2040476540","https://openalex.org/W2043042732","https://openalex.org/W2049157244","https://openalex.org/W2049665940","https://openalex.org/W2064791480","https://openalex.org/W2067867878","https://openalex.org/W2079377005","https://openalex.org/W2083732024","https://openalex.org/W2087651449","https://openalex.org/W2088956048","https://openalex.org/W2094136184","https://openalex.org/W2113604817","https://openalex.org/W2153655764","https://openalex.org/W2164503448","https://openalex.org/W2317332786","https://openalex.org/W3138974299","https://openalex.org/W4239252540"],"related_works":["https://openalex.org/W2084313314","https://openalex.org/W2164503448","https://openalex.org/W2013137158","https://openalex.org/W1987787378","https://openalex.org/W2089553740","https://openalex.org/W2088956048","https://openalex.org/W4232692142","https://openalex.org/W2049157244","https://openalex.org/W2084513699","https://openalex.org/W1992077397"],"abstract_inverted_index":{"The":[0,36,58,134],"reaction":[1],"of":[2,53,81,91,121,124,139,147,160],"[Ni(aet)2]":[3],"with":[4,79,156],"[CoCl2(R,R-chxn)2]+":[5],"(aet":[6],"=":[7,10,128],"2-aminoethanethiolate,":[8],"R,R-chxn":[9,56],"1R,2R-cyclohexanediamine)":[11],"in":[12,21,40,62,111],"water":[13],"gave":[14],"a":[15,29,67,122],"CoIIINiIICoIII":[16],"trinuclear":[17,75,114],"complex,":[18,76],"DeltaRRDeltaRR-[Ni(Co(aet)(2-)(R,R-chxn))2]4+":[19],"([1a]4+),":[20],"which":[22,47],"two":[23,37,98,106],"cis(S)-[Co(aet)2(R,R-chxn)]+":[24],"units":[25,39],"are":[26,142],"linked":[27],"by":[28,50,66],"central":[30,59],"NiII":[31,60,129],"ion":[32,61,69],"through":[33],"sulfur":[34],"bridges.":[35],"CoIII":[38,99],"[1a]4+":[41,63,161],"uniformly":[42],"adopt":[43],"the":[44,51,54,82,95,103,112,118,145,148,157],"Delta":[45,83],"configuration,":[46],"is":[48],"induced":[49],"chirality":[52,96,104],"terminal":[55],"ligands.":[57],"was":[64,88,109],"replaced":[65],"PdII":[68,132],"to":[70,117],"produce":[71],"an":[72],"analogous":[73],"CoIIIPdIICoIII":[74],"DeltaRRDeltaRR-[Pd(Co(aet)2(R,R-chxn))2]4+":[77],"([2a]4+),":[78],"retention":[80],"configuration.":[84],"When":[85],"racemic":[86],"R,R/S,S-chxn":[87],"employed":[89],"instead":[90],"R,R-chxn,":[92],"not":[93],"only":[94],"about":[97,105],"centers":[100],"but":[101],"also":[102],"chxn":[107],"ligands":[108],"unified":[110],"S-bridged":[113],"structure,":[115],"leading":[116],"selective":[119],"formation":[120],"pair":[123],"enantiomers,":[125],"DeltaRRDeltaRR/LambdaSSLambdaSS-[M(Co(aet)2(chxn))2]4+":[126],"(M":[127],"([1b]4+)":[130],"and":[131,136,152,162],"([2b]4+)).":[133],"stereochemical":[135],"spectroscopic":[137],"features":[138],"these":[140],"complexes":[141],"discussed":[143],"on":[144],"basis":[146],"electronic":[149],"absorption,":[150],"CD,":[151],"NMR":[153],"spectroscopies,":[154],"along":[155],"crystal":[158],"structures":[159],"[2a]4+.":[163]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2020,"cited_by_count":1},{"year":2018,"cited_by_count":1},{"year":2016,"cited_by_count":2}],"updated_date":"2026-10-14T16:39:01.820549","created_date":"2016-06-24T00:00:00"}
