{"id":"https://openalex.org/W1964370244","doi":"https://doi.org/10.1021/om960646t","title":"Examination of Drago's EB and CB Parameters for Phosphines through the Quantitative Analysis of Ligand Effects (QALE)","display_name":"Examination of Drago's EB and CB Parameters for Phosphines through the Quantitative Analysis of Ligand Effects (QALE)","publication_year":1997,"publication_date":"1997-02-01","ids":{"openalex":"https://openalex.org/W1964370244","doi":"https://doi.org/10.1021/om960646t","mag":"1964370244"},"language":"en","primary_location":{"id":"doi:10.1021/om960646t","doi":"https://doi.org/10.1021/om960646t","is_oa":false,"landing_page_url":"https://doi.org/10.1021/om960646t","pdf_url":null,"source":{"id":"https://openalex.org/S4924609","display_name":"Organometallics","issn_l":"0276-7333","issn":["0276-7333","1520-6041"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","norway-2","poland-100","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organometallics","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5025869285","display_name":"Anthony L. Fernandez","orcid":"https://orcid.org/0000-0002-2553-2949","observed_orcids":["https://orcid.org/0000-0002-2553-2949"]},"institutions":[{"id":"https://openalex.org/I111088046","display_name":"Boston University","ror":"https://ror.org/05qwgg493","country_code":"US","type":"education","lineage":["https://openalex.org/I111088046"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Anthony Fernandez","raw_affiliation_strings":["Department of Chemistry, Metcalf Science and Engineering Center, Boston University, Boston, Massachusetts 02215"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Metcalf Science and Engineering Center, Boston University, Boston, Massachusetts 02215","institution_ids":["https://openalex.org/I111088046"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5103515741","display_name":"Clementina Reyes","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I111088046","display_name":"Boston University","ror":"https://ror.org/05qwgg493","country_code":"US","type":"education","lineage":["https://openalex.org/I111088046"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Clementina Reyes","raw_affiliation_strings":["Department of Chemistry, Metcalf Science and Engineering Center, Boston University, Boston, Massachusetts 02215"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Metcalf Science and Engineering Center, Boston University, Boston, Massachusetts 02215","institution_ids":["https://openalex.org/I111088046"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5070671745","display_name":"Matthew R. Wilson","orcid":"https://orcid.org/0000-0001-8047-9469","observed_orcids":["https://orcid.org/0000-0001-8047-9469"]},"institutions":[{"id":"https://openalex.org/I111088046","display_name":"Boston University","ror":"https://ror.org/05qwgg493","country_code":"US","type":"education","lineage":["https://openalex.org/I111088046"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Matthew R. Wilson","raw_affiliation_strings":["Department of Chemistry, Metcalf Science and Engineering Center, Boston University, Boston, Massachusetts 02215"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Metcalf Science and Engineering Center, Boston University, Boston, Massachusetts 02215","institution_ids":["https://openalex.org/I111088046"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5007239883","display_name":"David C. Woska","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I111088046","display_name":"Boston University","ror":"https://ror.org/05qwgg493","country_code":"US","type":"education","lineage":["https://openalex.org/I111088046"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"David C. Woska","raw_affiliation_strings":["Department of Chemistry, Metcalf Science and Engineering Center, Boston University, Boston, Massachusetts 02215"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Metcalf Science and Engineering Center, Boston University, Boston, Massachusetts 02215","institution_ids":["https://openalex.org/I111088046"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5037802438","display_name":"Alfred Prock","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I111088046","display_name":"Boston University","ror":"https://ror.org/05qwgg493","country_code":"US","type":"education","lineage":["https://openalex.org/I111088046"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Alfred Prock","raw_affiliation_strings":["Department of Chemistry, Metcalf Science and Engineering Center, Boston University, Boston, Massachusetts 02215"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Metcalf Science and Engineering Center, Boston University, Boston, Massachusetts 02215","institution_ids":["https://openalex.org/I111088046"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5089825747","display_name":"Warren P. Giering","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I111088046","display_name":"Boston University","ror":"https://ror.org/05qwgg493","country_code":"US","type":"education","lineage":["https://openalex.org/I111088046"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Warren P. Giering","raw_affiliation_strings":["Department of Chemistry, Metcalf Science and Engineering Center, Boston University, Boston, Massachusetts 02215"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Metcalf Science and Engineering Center, Boston University, Boston, Massachusetts 02215","institution_ids":["https://openalex.org/I111088046"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I111088046"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":5.3075,"has_fulltext":false,"cited_by_count":39,"citation_normalized_percentile":{"value":0.9657673,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":88,"max":93},"biblio":{"volume":"16","issue":"3","first_page":"342","last_page":"348"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12191","display_name":"Physical Organic Chemistry and Reaction Kinetics","score":0.5414999723434448,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12191","display_name":"Physical Organic Chemistry and Reaction Kinetics","score":0.5414999723434448,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.14399999380111694,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.10830000042915344,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/phosphine","display_name":"phosphine","score":0.6579999923706055},{"id":"https://openalex.org/keywords/ligand-effects","display_name":"ligand effects","score":0.7429999709129333},{"id":"https://openalex.org/keywords/phosphine-complexes","display_name":"phosphine complexes","score":0.593999981880188}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8961107730865479},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.36226212978363037},{"id":"https://openalex.org/C147597530","wikidata":"https://www.wikidata.org/wiki/Q369472","display_name":"Computational chemistry","level":1,"score":0.3385451138019562},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.3333001732826233},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.08831992745399475}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/om960646t","doi":"https://doi.org/10.1021/om960646t","is_oa":false,"landing_page_url":"https://doi.org/10.1021/om960646t","pdf_url":null,"source":{"id":"https://openalex.org/S4924609","display_name":"Organometallics","issn_l":"0276-7333","issn":["0276-7333","1520-6041"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","norway-2","poland-100","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organometallics","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":29,"referenced_works":["https://openalex.org/W1972662486","https://openalex.org/W1973053376","https://openalex.org/W1980061049","https://openalex.org/W1982739004","https://openalex.org/W1982783432","https://openalex.org/W1984992700","https://openalex.org/W1994540569","https://openalex.org/W2003251580","https://openalex.org/W2018107150","https://openalex.org/W2018652743","https://openalex.org/W2019786940","https://openalex.org/W2026640997","https://openalex.org/W2030790509","https://openalex.org/W2052082029","https://openalex.org/W2057470860","https://openalex.org/W2057915643","https://openalex.org/W2058973777","https://openalex.org/W2067999071","https://openalex.org/W2069209751","https://openalex.org/W2075314998","https://openalex.org/W2077320375","https://openalex.org/W2091702998","https://openalex.org/W2107325367","https://openalex.org/W2120019528","https://openalex.org/W2462545012","https://openalex.org/W2950565673","https://openalex.org/W2951540338","https://openalex.org/W2952759656","https://openalex.org/W3138093308"],"related_works":["https://openalex.org/W2063723477","https://openalex.org/W2951143585","https://openalex.org/W2161121285","https://openalex.org/W2062271850","https://openalex.org/W2462545012","https://openalex.org/W2725895286","https://openalex.org/W2047757983","https://openalex.org/W4401332942","https://openalex.org/W2050682625","https://openalex.org/W1977156809"],"abstract_inverted_index":{"Comparison":[0],"of":[1,3,6,55,68,86],"pairs":[2],"physiochemical":[4],"properties":[5],"phosphines":[7],"and":[8,58,73,107],"their":[9],"complexes":[10],"demonstrates":[11],"that,":[12],"in":[13,22,29,47],"general,":[14],"at":[15],"least":[16],"four":[17],"independent":[18],"stereoelectronic":[19],"parameters":[20,64,71],"are":[21,65],"general":[23],"required":[24],"to":[25,95],"describe":[26],"the":[27,69,87,96,99],"variations":[28],"these":[30,63],"properties.":[31],"Consequently,":[32],"any":[33],"two-parameter":[34],"model":[35,42,91],"such":[36],"as":[37],"Drago's":[38],"E":[39,56,80,88],"/":[40,89],"C":[41,59,90],"will":[43,92],"have":[44],"limited":[45],"use":[46],"correlation":[48],"analyses":[49],"involving":[50],"phosphines.":[51],"The":[52],"QALE":[53,70],"analysis":[54],"B":[57,60],"shows":[61],"that":[62],"linear":[66],"combinations":[67],"\u03c7":[72,106],"\u03b8,":[74],"with":[75],"a":[76],"small":[77],"contribution":[78],"from":[79],"ar":[81],".":[82],"Thus,":[83],"successful":[84],"application":[85],"be":[93],"restricted":[94],"situation":[97],"where":[98],"property":[100],"being":[101],"analyzed":[102],"depends":[103],"primarily":[104],"on":[105],"\u03b8.":[108]},"counts_by_year":[{"year":2022,"cited_by_count":1},{"year":2020,"cited_by_count":1},{"year":2019,"cited_by_count":1},{"year":2014,"cited_by_count":1}],"updated_date":"2026-08-21T09:56:20.448147","created_date":"2016-06-24T00:00:00"}
