{"id":"https://openalex.org/W1964349574","doi":"https://doi.org/10.1139/v80-024","title":"3,5-Dimethylpyrazolylphosphine molybdenum(0) and tungsten(0) carbonyl complexes","display_name":"3,5-Dimethylpyrazolylphosphine molybdenum(0) and tungsten(0) carbonyl complexes","publication_year":1980,"publication_date":"1980-01-15","ids":{"openalex":"https://openalex.org/W1964349574","doi":"https://doi.org/10.1139/v80-024","mag":"1964349574"},"language":"en","primary_location":{"id":"doi:10.1139/v80-024","doi":"https://doi.org/10.1139/v80-024","is_oa":true,"landing_page_url":"https://doi.org/10.1139/v80-024","pdf_url":"https://cdnsciencepub.com/doi/pdf/10.1139/v80-024","source":{"id":"https://openalex.org/S9189650","display_name":"Canadian Journal of Chemistry","issn_l":"0008-4042","issn":["0008-4042","1480-3291"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","norway-1","poland-40","russia-white-list-3"],"host_organization":"https://openalex.org/P4310312929","host_organization_name":"Canadian Science Publishing","host_organization_lineage":["https://openalex.org/P4310312929"],"host_organization_lineage_names":["Canadian Science Publishing"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Canadian Journal of Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"bronze","oa_url":"https://cdnsciencepub.com/doi/pdf/10.1139/v80-024","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5009146875","display_name":"Harry B. Davis","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Harry B. Davis","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5010196658","display_name":"James K. Hoyano","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"James K. Hoyano","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5020924788","display_name":"Ping Y. Leung","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Ping Yuen Leung","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5083191266","display_name":"L. K. Peterson","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210159778","display_name":"National Research Council Canada","ror":"https://ror.org/04mte1k06","country_code":"CA","type":"government","lineage":["https://openalex.org/I4210159778"]}],"countries":["CA"],"is_corresponding":false,"raw_author_name":"Louis K. Peterson","raw_affiliation_strings":["1980 National Research Council of CanadaIConseil national de recherches du Canada"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"1980 National Research Council of CanadaIConseil national de recherches du Canada","institution_ids":["https://openalex.org/I4210159778"]}]},{"author_position":"last","author":{"id":null,"display_name":"Brian Wolstenholme","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Brian Wolstenholme","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":4.4317,"has_fulltext":true,"cited_by_count":44,"citation_normalized_percentile":{"value":0.9452793,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":87,"max":97},"biblio":{"volume":"58","issue":"2","first_page":"151","last_page":"158"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.8804000020027161,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.8804000020027161,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.07199999690055847,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.030899999663233757,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/molybdenum-carbonyl-complexes","display_name":"molybdenum carbonyl complexes","score":0.9120000004768372},{"id":"https://openalex.org/keywords/tungsten-carbonyl-complexes","display_name":"tungsten carbonyl complexes","score":1.0},{"id":"https://openalex.org/keywords/metal-carbonyl-complexes","display_name":"metal carbonyl complexes","score":0.6110000014305115},{"id":"https://openalex.org/keywords/ligand-coordination-modes","display_name":"ligand coordination modes","score":0.7789999842643738},{"id":"https://openalex.org/keywords/tridentate-phosphine-ligands","display_name":"tridentate phosphine ligands","score":0.7379999756813049},{"id":"https://openalex.org/keywords/octahedral-geometry","display_name":"octahedral geometry","score":0.8240000009536743}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8293708562850952},{"id":"https://openalex.org/C178516000","wikidata":"https://www.wikidata.org/wiki/Q3023362","display_name":"Denticity","level":3,"score":0.8226094841957092},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.7523037195205688},{"id":"https://openalex.org/C198819137","wikidata":"https://www.wikidata.org/wiki/Q188884","display_name":"Octahedron","level":3,"score":0.6264677047729492},{"id":"https://openalex.org/C2780378348","wikidata":"https://www.wikidata.org/wiki/Q25351438","display_name":"Ring (chemistry)","level":2,"score":0.5906643867492676},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.5856978297233582},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.5147535800933838},{"id":"https://openalex.org/C549387045","wikidata":"https://www.wikidata.org/wiki/Q1053","display_name":"Molybdenum","level":2,"score":0.5014584064483643},{"id":"https://openalex.org/C2777716191","wikidata":"https://www.wikidata.org/wiki/Q207877","display_name":"Phosphine","level":3,"score":0.48803868889808655},{"id":"https://openalex.org/C58312451","wikidata":"https://www.wikidata.org/wiki/Q4817200","display_name":"Atom (system on chip)","level":2,"score":0.431640088558197},{"id":"https://openalex.org/C135361552","wikidata":"https://www.wikidata.org/wiki/Q17154357","display_name":"Metallacycle","level":4,"score":0.41747161746025085},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.23579180240631104},{"id":"https://openalex.org/C50515024","wikidata":"https://www.wikidata.org/wiki/Q826582","display_name":"X-ray crystallography","level":3,"score":0.1324758529663086},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.10021921992301941},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.08491218090057373},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.0},{"id":"https://openalex.org/C207114421","wikidata":"https://www.wikidata.org/wiki/Q133900","display_name":"Diffraction","level":2,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.0},{"id":"https://openalex.org/C170493617","wikidata":"https://www.wikidata.org/wiki/Q208467","display_name":"Receptor","level":2,"score":0.0},{"id":"https://openalex.org/C149635348","wikidata":"https://www.wikidata.org/wiki/Q193040","display_name":"Embedded system","level":1,"score":0.0},{"id":"https://openalex.org/C120665830","wikidata":"https://www.wikidata.org/wiki/Q14620","display_name":"Optics","level":1,"score":0.0},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1139/v80-024","doi":"https://doi.org/10.1139/v80-024","is_oa":true,"landing_page_url":"https://doi.org/10.1139/v80-024","pdf_url":"https://cdnsciencepub.com/doi/pdf/10.1139/v80-024","source":{"id":"https://openalex.org/S9189650","display_name":"Canadian Journal of Chemistry","issn_l":"0008-4042","issn":["0008-4042","1480-3291"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","norway-1","poland-40","russia-white-list-3"],"host_organization":"https://openalex.org/P4310312929","host_organization_name":"Canadian Science Publishing","host_organization_lineage":["https://openalex.org/P4310312929"],"host_organization_lineage_names":["Canadian Science Publishing"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Canadian Journal of Chemistry","raw_type":"journal-article"}],"best_oa_location":{"id":"doi:10.1139/v80-024","doi":"https://doi.org/10.1139/v80-024","is_oa":true,"landing_page_url":"https://doi.org/10.1139/v80-024","pdf_url":"https://cdnsciencepub.com/doi/pdf/10.1139/v80-024","source":{"id":"https://openalex.org/S9189650","display_name":"Canadian Journal of Chemistry","issn_l":"0008-4042","issn":["0008-4042","1480-3291"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","norway-1","poland-40","russia-white-list-3"],"host_organization":"https://openalex.org/P4310312929","host_organization_name":"Canadian Science Publishing","host_organization_lineage":["https://openalex.org/P4310312929"],"host_organization_lineage_names":["Canadian Science Publishing"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Canadian Journal of Chemistry","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320334593","display_name":"Natural Sciences and Engineering Research Council of Canada","ror":"https://ror.org/01h531d29"}],"has_content":{"grobid_xml":true,"pdf":true},"content_urls":{"pdf":"https://content.openalex.org/works/W1964349574.pdf","grobid_xml":"https://content.openalex.org/works/W1964349574.grobid-xml"},"referenced_works_count":4,"referenced_works":["https://openalex.org/W216330907","https://openalex.org/W346402392","https://openalex.org/W2115883629","https://openalex.org/W4245630025"],"related_works":["https://openalex.org/W1980041227","https://openalex.org/W2077873409","https://openalex.org/W1971845795","https://openalex.org/W2065104823","https://openalex.org/W1964999132","https://openalex.org/W2524823959","https://openalex.org/W1983382501","https://openalex.org/W1969609411","https://openalex.org/W2080305418","https://openalex.org/W2001145902"],"abstract_inverted_index":{"Complexes":[0],"with":[1,44],"the":[2,36,39,60,70,82,106,110,123,131,137,143,148,172,179,183,191,197],"general":[3],"formula":[4],"[LnM(CO)m],":[5],"where":[6,101,164],"[Formula:":[7,84,92,98,115,124,150,155,161],"see":[8,85,93,99,116,125,151,156,162],"text]":[9,86,94,100,117,126,152,157,163],"x":[10,79,120,188],"=":[11,14,19,24,80,121,189],"0\u20132,":[12],"n":[13],"1":[15],"or":[16,21,26,32,52],"2,":[17,81],"M":[18],"Mo(0)":[20],"W(0),":[22],"m":[23],"3":[25],"4,":[27],"were":[28],"prepared":[29],"by":[30,35,103],"thermal":[31],"photolytic":[33],"methods":[34],"reaction":[37],"of":[38,67,109,136,140,142,171,178,200],"appropriate":[40],"3,5-dimethylpyrazolyl":[41],"phosphine":[42],"ligand":[43,83,127,193],"M(CO)6,":[45],"norbornadienemetaltetracarbonyl":[46],"[C7H8M(CO)4],":[47],"cycloheptatrienylmetaltricarbonyl":[48],"[C7H8M(CO)3],":[49],"[(Me2N(CH2)3NMe2)M(CO)4],":[50],"[(CH3CN)2M(CO)4],":[51],"[(CH3CN)3M(CO)3].":[53],"Structural":[54],"evidence":[55],"indicates":[56],"octahedral":[57],"geometry":[58],"about":[59],"metal":[61],"atom":[62,133],"centre,":[63],"and":[64,76,95,105,134,158,175],"several":[65],"modes":[66],"coordination":[68,102,185],"for":[69],"ligands":[71],"in":[72,91,97,154,160],"those":[73],"complexes":[74],"isolated":[75],"characterized.":[77],"For":[78,119,187],"was":[87,128,194],"monodentate,":[88],"via":[89,130,196],"phosphorus":[90,132],"bidentate":[96],"P":[104],"2N":[107,138,169,198],"site":[108],"pyrazolyl":[111,144,173,203],"ring":[112,181],"yielded":[113],"four-membered":[114,149],"metallocycles.":[118],"1,":[122],"bidentate,":[129],"one":[135,141],"sites":[139],"substituents,":[145],"thus":[146,205],"giving":[147,206],"metallocycle":[153],"tridentate":[159,195],"three":[165,202],"facial":[166],"CO's,":[167],"two":[168],"atoms":[170,199],"rings,":[174,204],"a":[176],"part":[177],"phenyl":[180],"occupy":[182],"six":[184],"sites.":[186],"0,":[190],"P(Me2pz)3":[192],"all":[201],"tricyclic":[207],"systems":[208],"[P(Me2pz)3M(CO)3]":[209],"(VIII,":[210],"IX).":[211]},"counts_by_year":[{"year":2021,"cited_by_count":1},{"year":2017,"cited_by_count":1},{"year":2015,"cited_by_count":1},{"year":2014,"cited_by_count":1},{"year":2013,"cited_by_count":3},{"year":2012,"cited_by_count":1}],"updated_date":"2026-10-31T12:09:11.096373","created_date":"2016-06-24T00:00:00"}