{"id":"https://openalex.org/W1963980355","doi":"https://doi.org/10.1039/dt9840001667","title":"Electron spin resonance studies of a range of stannane radical cations","display_name":"Electron spin resonance studies of a range of stannane radical cations","publication_year":1984,"publication_date":"1984-01-01","ids":{"openalex":"https://openalex.org/W1963980355","doi":"https://doi.org/10.1039/dt9840001667","mag":"1963980355"},"language":"en","primary_location":{"id":"doi:10.1039/dt9840001667","doi":"https://doi.org/10.1039/dt9840001667","is_oa":false,"landing_page_url":"https://doi.org/10.1039/dt9840001667","pdf_url":null,"source":{"id":"https://openalex.org/S4210210551","display_name":"Journal of the Chemical Society Dalton Transactions","issn_l":"1364-5447","issn":["1364-5447","1472-7773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the Chemical Society, Dalton Transactions","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5082061547","display_name":"Akinori Hasegawa","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Akinori Hasegawa","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5034531085","display_name":"Shoji Kaminaka","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Shoji Kaminaka","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5038632934","display_name":"Toshio Wakabayashi","orcid":"https://orcid.org/0000-0001-7241-5123","observed_orcids":["https://orcid.org/0000-0001-7241-5123"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Toshio Wakabayashi","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5110340712","display_name":"Michir\u00f4 Hayashi","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Michiro Hayashi","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5110006191","display_name":"Martyn C. R. Symons","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Martyn C. R. Symons","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5088206446","display_name":"Jan Rideout","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Jan Rideout","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":0.4962,"has_fulltext":false,"cited_by_count":19,"citation_normalized_percentile":{"value":0.5373642,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":93},"biblio":{"volume":null,"issue":"8","first_page":"1667","last_page":"1667"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.4255000054836273,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.4255000054836273,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12458","display_name":"Organometallic Compounds Synthesis and Characterization","score":0.24480000138282776,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12381","display_name":"Electron Spin Resonance Studies","score":0.17820000648498535,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/organotin-compounds","display_name":"organotin compounds","score":0.7179999947547913},{"id":"https://openalex.org/keywords/hyperfine-interaction","display_name":"hyperfine interaction","score":0.7129999995231628},{"id":"https://openalex.org/keywords/gamma-irradiation","display_name":"gamma irradiation","score":0.5839999914169312},{"id":"https://openalex.org/keywords/methyl-radical","display_name":"methyl radical","score":0.6050000190734863},{"id":"https://openalex.org/keywords/ethyl-radical","display_name":"ethyl radical","score":0.9440000057220459},{"id":"https://openalex.org/keywords/13c-labeling","display_name":"13C labeling","score":0.5799999833106995},{"id":"https://openalex.org/keywords/electron-spin-resonance","display_name":"electron spin resonance","score":0.36800000071525574}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8320827484130859},{"id":"https://openalex.org/C139066938","wikidata":"https://www.wikidata.org/wiki/Q185056","display_name":"Radical","level":2,"score":0.7906274795532227},{"id":"https://openalex.org/C2777897746","wikidata":"https://www.wikidata.org/wiki/Q417040","display_name":"Stannane","level":2,"score":0.7445623874664307},{"id":"https://openalex.org/C525849907","wikidata":"https://www.wikidata.org/wiki/Q1096","display_name":"Tin","level":2,"score":0.6489008069038391},{"id":"https://openalex.org/C186927785","wikidata":"https://www.wikidata.org/wiki/Q374793","display_name":"Unpaired electron","level":3,"score":0.633817195892334},{"id":"https://openalex.org/C187961010","wikidata":"https://www.wikidata.org/wiki/Q260463","display_name":"Electron paramagnetic resonance","level":2,"score":0.49366530776023865},{"id":"https://openalex.org/C139358910","wikidata":"https://www.wikidata.org/wiki/Q725417","display_name":"Molecular orbital","level":3,"score":0.49169331789016724},{"id":"https://openalex.org/C131538251","wikidata":"https://www.wikidata.org/wiki/Q1413102","display_name":"Hyperfine structure","level":2,"score":0.46895068883895874},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.4639854431152344},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.45432794094085693},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.20629456639289856},{"id":"https://openalex.org/C46141821","wikidata":"https://www.wikidata.org/wiki/Q209402","display_name":"Nuclear magnetic resonance","level":1,"score":0.20029249787330627},{"id":"https://openalex.org/C184779094","wikidata":"https://www.wikidata.org/wiki/Q26383","display_name":"Atomic physics","level":1,"score":0.1614370048046112},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.13239553570747375},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.12785476446151733},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1039/dt9840001667","doi":"https://doi.org/10.1039/dt9840001667","is_oa":false,"landing_page_url":"https://doi.org/10.1039/dt9840001667","pdf_url":null,"source":{"id":"https://openalex.org/S4210210551","display_name":"Journal of the Chemical Society Dalton Transactions","issn_l":"1364-5447","issn":["1364-5447","1472-7773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the Chemical Society, Dalton Transactions","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2107862685","https://openalex.org/W2017506991","https://openalex.org/W2048888438","https://openalex.org/W2036955191","https://openalex.org/W1992747235","https://openalex.org/W1976604382","https://openalex.org/W2950693331","https://openalex.org/W2014569744","https://openalex.org/W2039365310","https://openalex.org/W2058893674"],"abstract_inverted_index":{"Exposure":[0],"of":[1,4,201,218,248,293],"dilute":[2],"solutions":[3],"stannanes":[5,237],"in":[6,81,182,239,282],"freon":[7],"(CFCl3)":[8],"at":[9,206,251,261],"77":[10,165,207,252,262],"K":[11],"to":[12,32,43,49,55,74,138,178,229,297],"60Co":[13],"\u03b3-rays":[14],"gave":[15,21,245,257],"the":[16,51,89,134,170,183,211,290],"parent":[17,212],"radical":[18,149],"cations.":[19],"SnH4":[20],"two":[22,75],"well":[23,171],"defined":[24],"centres,":[25],"both":[26],"exhibiting":[27],"very":[28],"large":[29,62],"hyperfine":[30],"coupling":[31,42,73],"117Sn":[33],"and":[34,78,97],"119Sn,":[35],"One,":[36],"with":[37,60,71,104,124,156,169,284,289],"C3v":[38,90],"symmetry,":[39],"showing":[40,220],"strong":[41,72],"a":[44,61,120,232,258,265,271],"unique":[45],"proton,":[46],"is":[47,85,226],"thought":[48],"have":[50,100,139],"unpaired":[52],"electron":[53,222],"confined":[54],"one":[56],"\u03c3":[57,234],"Sn\u2013H":[58],"orbital":[59],"5s":[63],"contribution":[64],"from":[65,224,231],"tin.":[66,130],"The":[67,92,254],"other":[68],"(C2v":[69],"symmetry),":[70],"equivalent":[76],"protons,":[77],"formed":[79],"initially":[80],"almost":[82,125],"equal":[83],"yield,":[84],"slowly":[86],"converted":[87],"into":[88],"form.":[91],"main":[93],"cations":[94],"SnMeH3+,":[95],"SnMe2H2+,":[96],"SnMe3H":[98],"+":[99],"comparable":[101],"C2v":[102],"structures":[103],"strongly":[105],"s\u2013p":[106],"hybridised":[107],"tin":[108],"orbitals,":[109],"but":[110,270],"that":[111,147,217,221,285],"for":[112,174,286],"SnMe4":[113],"has":[114,150],"its":[115],"major":[116],"spin":[117],"density":[118],"on":[119,129,162,186,280],"single":[121],"methyl":[122,158,192,202],"group,":[123],"no":[126],"5s-orbital":[127],"character":[128],"In":[131,154],"this":[132,148,240],"case,":[133],"SnMe3":[135,268],"unit":[136,269],"appears":[137],"become":[140],"planar.":[141],"Studies":[142],"using":[143],"13CH3":[144],"labelling":[145],"confirm":[146],"extensive":[151],"Me3Sn+\u22ef\u010aH3":[152],"character.":[153],"accord":[155],"this,":[157],"radicals":[159,181,203,250],"were":[160,194,204],"detected":[161],"annealing":[163],"above":[164],"K.":[166,208,253],"This":[167,275],"agrees":[168],"established":[172],"tendency":[173],"such":[175],"organometallic":[176],"compounds":[177],"give":[179],"alkyl":[180],"liquid":[184],"phase":[185],"chemical":[187],"or":[188],"electrochemical":[189],"reduction.":[190],"When":[191],"groups":[193],"progressively":[195],"replaced":[196],"by":[197],"chlorine,":[198],"good":[199],"yields":[200,247],"obtained":[205],"For":[209],"SnMe3Cl+":[210],"cation":[213,260],"spectrum":[214],"closely":[215],"resembled":[216],"SnMe4,":[219],"loss":[223,230],"chlorine":[225],"disfavoured":[227],"relative":[228],"tin\u2013carbon":[233],"bond.":[235],"Other":[236],"studied":[238],"way":[241],"include":[242],"SnMe3Et,":[243],"which":[244],"high":[246],"ethyl":[249],"t-butyl":[255],"derivative":[256],"stable":[259],"K,":[263],"having":[264],"nearly":[266],"planar":[267],"pyramidal":[272],"\u2013CMe3":[273],"unit.":[274],"signal":[276],"was":[277],"lost":[278],"reversibly":[279],"annealing,":[281],"contrast":[283],"SnMe4+":[287],"cations,":[288],"reversible":[291],"growth":[292],"broad":[294],"features":[295],"assigned":[296],"\u02d9CMe3":[298],"radicals.":[299]},"counts_by_year":[{"year":2018,"cited_by_count":1},{"year":2013,"cited_by_count":1}],"updated_date":"2025-11-06T03:46:38.306776","created_date":"2016-06-24T00:00:00"}