{"id":"https://openalex.org/W1963889725","doi":"https://doi.org/10.1021/ol0614166","title":"Organocatalytic Living Ring-Opening Polymerization of Cyclic Carbosiloxanes","display_name":"Organocatalytic Living Ring-Opening Polymerization of Cyclic Carbosiloxanes","publication_year":2006,"publication_date":"2006-08-30","ids":{"openalex":"https://openalex.org/W1963889725","doi":"https://doi.org/10.1021/ol0614166","mag":"1963889725","pmid":"https://pubmed.ncbi.nlm.nih.gov/17020277"},"language":"en","primary_location":{"id":"doi:10.1021/ol0614166","doi":"https://doi.org/10.1021/ol0614166","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ol0614166","pdf_url":null,"source":{"id":"https://openalex.org/S201989124","display_name":"Organic Letters","issn_l":"1523-7052","issn":["1523-7052","1523-7060"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organic Letters","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5028326090","display_name":"Bas G. G. Lohmeijer","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210085935","display_name":"IBM Research - Almaden","ror":"https://ror.org/005w8dd04","country_code":"US","type":"facility","lineage":["https://openalex.org/I1341412227","https://openalex.org/I4210085935","https://openalex.org/I4210114115"]},{"id":"https://openalex.org/I97018004","display_name":"Stanford University","ror":"https://ror.org/00f54p054","country_code":"US","type":"education","lineage":["https://openalex.org/I97018004"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Bas G. G. Lohmeijer","raw_affiliation_strings":["IBM Almaden Research Center, 650 Harry Road, San Jose California 95123, and Department of Chemistry, Stanford University, Stanford, California 94305"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"IBM Almaden Research Center, 650 Harry Road, San Jose California 95123, and Department of Chemistry, Stanford University, Stanford, California 94305","institution_ids":["https://openalex.org/I4210085935","https://openalex.org/I97018004"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5022255135","display_name":"G\u00e9raud Dubois","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210085935","display_name":"IBM Research - Almaden","ror":"https://ror.org/005w8dd04","country_code":"US","type":"facility","lineage":["https://openalex.org/I1341412227","https://openalex.org/I4210085935","https://openalex.org/I4210114115"]},{"id":"https://openalex.org/I97018004","display_name":"Stanford University","ror":"https://ror.org/00f54p054","country_code":"US","type":"education","lineage":["https://openalex.org/I97018004"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Geraud Dubois","raw_affiliation_strings":["IBM Almaden Research Center, 650 Harry Road, San Jose California 95123, and Department of Chemistry, Stanford University, Stanford, California 94305"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"IBM Almaden Research Center, 650 Harry Road, San Jose California 95123, and Department of Chemistry, Stanford University, Stanford, California 94305","institution_ids":["https://openalex.org/I4210085935","https://openalex.org/I97018004"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5062519013","display_name":"Frank A. Leibfarth","orcid":"https://orcid.org/0000-0001-7737-0331","observed_orcids":["https://orcid.org/0000-0001-7737-0331"]},"institutions":[{"id":"https://openalex.org/I4210085935","display_name":"IBM Research - Almaden","ror":"https://ror.org/005w8dd04","country_code":"US","type":"facility","lineage":["https://openalex.org/I1341412227","https://openalex.org/I4210085935","https://openalex.org/I4210114115"]},{"id":"https://openalex.org/I97018004","display_name":"Stanford University","ror":"https://ror.org/00f54p054","country_code":"US","type":"education","lineage":["https://openalex.org/I97018004"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Frank Leibfarth","raw_affiliation_strings":["IBM Almaden Research Center, 650 Harry Road, San Jose California 95123, and Department of Chemistry, Stanford University, Stanford, California 94305"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"IBM Almaden Research Center, 650 Harry Road, San Jose California 95123, and Department of Chemistry, Stanford University, Stanford, California 94305","institution_ids":["https://openalex.org/I4210085935","https://openalex.org/I97018004"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5110084240","display_name":"Russell C. Pratt","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210085935","display_name":"IBM Research - Almaden","ror":"https://ror.org/005w8dd04","country_code":"US","type":"facility","lineage":["https://openalex.org/I1341412227","https://openalex.org/I4210085935","https://openalex.org/I4210114115"]},{"id":"https://openalex.org/I97018004","display_name":"Stanford University","ror":"https://ror.org/00f54p054","country_code":"US","type":"education","lineage":["https://openalex.org/I97018004"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Russell C. Pratt","raw_affiliation_strings":["IBM Almaden Research Center, 650 Harry Road, San Jose California 95123, and Department of Chemistry, Stanford University, Stanford, California 94305"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"IBM Almaden Research Center, 650 Harry Road, San Jose California 95123, and Department of Chemistry, Stanford University, Stanford, California 94305","institution_ids":["https://openalex.org/I4210085935","https://openalex.org/I97018004"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5056089992","display_name":"Fredrik Nederberg","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210085935","display_name":"IBM Research - Almaden","ror":"https://ror.org/005w8dd04","country_code":"US","type":"facility","lineage":["https://openalex.org/I1341412227","https://openalex.org/I4210085935","https://openalex.org/I4210114115"]},{"id":"https://openalex.org/I97018004","display_name":"Stanford University","ror":"https://ror.org/00f54p054","country_code":"US","type":"education","lineage":["https://openalex.org/I97018004"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Fredrik Nederberg","raw_affiliation_strings":["IBM Almaden Research Center, 650 Harry Road, San Jose California 95123, and Department of Chemistry, Stanford University, Stanford, California 94305"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"IBM Almaden Research Center, 650 Harry Road, San Jose California 95123, and Department of Chemistry, Stanford University, Stanford, California 94305","institution_ids":["https://openalex.org/I4210085935","https://openalex.org/I97018004"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5015322042","display_name":"Alshakim Nelson","orcid":"https://orcid.org/0000-0001-8060-8611","observed_orcids":["https://orcid.org/0000-0001-8060-8611"]},"institutions":[{"id":"https://openalex.org/I4210085935","display_name":"IBM Research - Almaden","ror":"https://ror.org/005w8dd04","country_code":"US","type":"facility","lineage":["https://openalex.org/I1341412227","https://openalex.org/I4210085935","https://openalex.org/I4210114115"]},{"id":"https://openalex.org/I97018004","display_name":"Stanford University","ror":"https://ror.org/00f54p054","country_code":"US","type":"education","lineage":["https://openalex.org/I97018004"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Alshakim Nelson","raw_affiliation_strings":["IBM Almaden Research Center, 650 Harry Road, San Jose California 95123, and Department of Chemistry, Stanford University, Stanford, California 94305"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"IBM Almaden Research Center, 650 Harry Road, San Jose California 95123, and Department of Chemistry, Stanford University, Stanford, California 94305","institution_ids":["https://openalex.org/I4210085935","https://openalex.org/I97018004"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5009737401","display_name":"Robert M. Waymouth","orcid":"https://orcid.org/0000-0001-9862-9509","observed_orcids":["https://orcid.org/0000-0001-9862-9509"]},"institutions":[{"id":"https://openalex.org/I4210085935","display_name":"IBM Research - Almaden","ror":"https://ror.org/005w8dd04","country_code":"US","type":"facility","lineage":["https://openalex.org/I1341412227","https://openalex.org/I4210085935","https://openalex.org/I4210114115"]},{"id":"https://openalex.org/I97018004","display_name":"Stanford University","ror":"https://ror.org/00f54p054","country_code":"US","type":"education","lineage":["https://openalex.org/I97018004"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Robert M. Waymouth","raw_affiliation_strings":["IBM Almaden Research Center, 650 Harry Road, San Jose California 95123, and Department of Chemistry, Stanford University, Stanford, California 94305"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"IBM Almaden Research Center, 650 Harry Road, San Jose California 95123, and Department of Chemistry, Stanford University, Stanford, California 94305","institution_ids":["https://openalex.org/I4210085935","https://openalex.org/I97018004"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5108410309","display_name":"Charles G. Wade","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210085935","display_name":"IBM Research - Almaden","ror":"https://ror.org/005w8dd04","country_code":"US","type":"facility","lineage":["https://openalex.org/I1341412227","https://openalex.org/I4210085935","https://openalex.org/I4210114115"]},{"id":"https://openalex.org/I97018004","display_name":"Stanford University","ror":"https://ror.org/00f54p054","country_code":"US","type":"education","lineage":["https://openalex.org/I97018004"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Charles Wade","raw_affiliation_strings":["IBM Almaden Research Center, 650 Harry Road, San Jose California 95123, and Department of Chemistry, Stanford University, Stanford, California 94305"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"IBM Almaden Research Center, 650 Harry Road, San Jose California 95123, and Department of Chemistry, Stanford University, Stanford, California 94305","institution_ids":["https://openalex.org/I4210085935","https://openalex.org/I97018004"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5087768520","display_name":"James L. Hedrick","orcid":"https://orcid.org/0000-0002-3621-9747","observed_orcids":["https://orcid.org/0000-0002-3621-9747","https://orcid.org/0000-0002-3968-9728"]},"institutions":[{"id":"https://openalex.org/I4210085935","display_name":"IBM Research - Almaden","ror":"https://ror.org/005w8dd04","country_code":"US","type":"facility","lineage":["https://openalex.org/I1341412227","https://openalex.org/I4210085935","https://openalex.org/I4210114115"]},{"id":"https://openalex.org/I97018004","display_name":"Stanford University","ror":"https://ror.org/00f54p054","country_code":"US","type":"education","lineage":["https://openalex.org/I97018004"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"James L. Hedrick","raw_affiliation_strings":["IBM Almaden Research Center, 650 Harry Road, San Jose California 95123, and Department of Chemistry, Stanford University, Stanford, California 94305"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"IBM Almaden Research Center, 650 Harry Road, San Jose California 95123, and Department of Chemistry, Stanford University, Stanford, California 94305","institution_ids":["https://openalex.org/I4210085935","https://openalex.org/I97018004"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":2.6136,"has_fulltext":false,"cited_by_count":136,"citation_normalized_percentile":{"value":0.88765685,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":94,"max":100},"biblio":{"volume":"8","issue":"21","first_page":"4683","last_page":"4686"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.4871000051498413,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.4871000051498413,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12420","display_name":"Silicone and Siloxane Chemistry","score":0.1615000069141388,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11593","display_name":"Carbon dioxide utilization in catalysis","score":0.08919999748468399,"subfield":{"id":"https://openalex.org/subfields/1508","display_name":"Process Chemistry and Technology"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/organocatalysis","display_name":"organocatalysis","score":0.8370000123977661},{"id":"https://openalex.org/keywords/living-ring-opening-polymerization","display_name":"living ring-opening polymerization","score":0.9169999957084656},{"id":"https://openalex.org/keywords/n-heterocyclic-carbenes","display_name":"N-heterocyclic carbenes","score":0.9190000295639038},{"id":"https://openalex.org/keywords/1-5-7-triazabicyclo-4-4-0-dec-5-ene","display_name":"1,5,7-triazabicyclo[4.4.0]dec-5-ene","score":0.9769999980926514},{"id":"https://openalex.org/keywords/transetherification","display_name":"transetherification","score":0.6890000104904175},{"id":"https://openalex.org/keywords/catalyst-basicity","display_name":"catalyst basicity","score":0.6949999928474426},{"id":"https://openalex.org/keywords/hydrogen-bonding","display_name":"hydrogen bonding","score":0.8270000219345093},{"id":"https://openalex.org/keywords/alcohol-activation","display_name":"alcohol activation","score":0.8270000219345093},{"id":"https://openalex.org/keywords/end-group-fidelity","display_name":"end-group fidelity","score":0.6549999713897705},{"id":"https://openalex.org/keywords/molecular-weight-control","display_name":"molecular weight control","score":0.7329999804496765}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8719673156738281},{"id":"https://openalex.org/C2780378348","wikidata":"https://www.wikidata.org/wiki/Q25351438","display_name":"Ring (chemistry)","level":2,"score":0.7743798494338989},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.6459296941757202},{"id":"https://openalex.org/C44228677","wikidata":"https://www.wikidata.org/wiki/Q181898","display_name":"Polymerization","level":3,"score":0.5595312118530273},{"id":"https://openalex.org/C66972969","wikidata":"https://www.wikidata.org/wiki/Q898995","display_name":"Organocatalysis","level":4,"score":0.55820232629776},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.4792342483997345},{"id":"https://openalex.org/C112887158","wikidata":"https://www.wikidata.org/wiki/Q169324","display_name":"Hydrogen bond","level":3,"score":0.4639444351196289},{"id":"https://openalex.org/C203897987","wikidata":"https://www.wikidata.org/wiki/Q900770","display_name":"Ring-opening polymerization","level":4,"score":0.418856143951416},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.40347713232040405},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.3898928761482239},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.34966132044792175},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.23699361085891724},{"id":"https://openalex.org/C146686406","wikidata":"https://www.wikidata.org/wiki/Q898628","display_name":"Enantioselective synthesis","level":3,"score":0.19505509734153748}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1021/ol0614166","doi":"https://doi.org/10.1021/ol0614166","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ol0614166","pdf_url":null,"source":{"id":"https://openalex.org/S201989124","display_name":"Organic Letters","issn_l":"1523-7052","issn":["1523-7052","1523-7060"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organic Letters","raw_type":"journal-article"},{"id":"pmid:17020277","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/17020277","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organic letters","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":32,"referenced_works":["https://openalex.org/W1964639919","https://openalex.org/W1967767388","https://openalex.org/W1988566786","https://openalex.org/W1995227684","https://openalex.org/W1996634217","https://openalex.org/W1996880602","https://openalex.org/W2004350652","https://openalex.org/W2004986011","https://openalex.org/W2006567571","https://openalex.org/W2027791687","https://openalex.org/W2041800381","https://openalex.org/W2043073190","https://openalex.org/W2045155504","https://openalex.org/W2055557503","https://openalex.org/W2066146098","https://openalex.org/W2070127123","https://openalex.org/W2070552828","https://openalex.org/W2074309992","https://openalex.org/W2079572766","https://openalex.org/W2082183807","https://openalex.org/W2087266904","https://openalex.org/W2091446566","https://openalex.org/W2094257100","https://openalex.org/W2129699360","https://openalex.org/W2148322883","https://openalex.org/W2159928256","https://openalex.org/W2320163706","https://openalex.org/W2949573161","https://openalex.org/W2950305764","https://openalex.org/W3104042263","https://openalex.org/W4211172071","https://openalex.org/W4237936259"],"related_works":["https://openalex.org/W3000403372","https://openalex.org/W2053379244","https://openalex.org/W3177034461","https://openalex.org/W3106385099","https://openalex.org/W3162638719","https://openalex.org/W2969464925","https://openalex.org/W4393041446","https://openalex.org/W2052578420","https://openalex.org/W1977360021","https://openalex.org/W7172492273"],"abstract_inverted_index":{"[reaction:":[0],"see":[1],"text]":[2],"An":[3],"organocatalytic":[4],"route":[5],"to":[6,55],"narrowly":[7],"dispersed":[8],"poly(carbosiloxanes)":[9],"of":[10,30,35],"predictable":[11],"molecular":[12],"weight":[13],"and":[14,23,45],"end":[15],"group":[16],"fidelity":[17],"is":[18,38],"described.":[19],"N-Heterocyclic":[20],"carbenes":[21],"(NHC)":[22],"1,5,7-triazabicyclo[4.4.0]dec-5-ene":[24],"(TBD)":[25],"catalyze":[26],"the":[27,36,58],"ring":[28],"opening":[29],"cyclic":[31],"carbosiloxanes.":[32],"The":[33],"pK(b)":[34],"catalyst":[37],"important":[39],"in":[40],"preventing":[41],"adverse":[42],"transetherification":[43],"reactions":[44],"obtaining":[46],"well-defined":[47],"polymers.":[48],"Mechanistic":[49],"studies":[50],"indicate":[51],"that":[52],"hydrogen":[53],"bonding":[54],"TBD":[56],"or":[57,62],"NHC":[59],"activates":[60],"alcohols":[61],"silanols":[63],"for":[64],"ring-opening":[65],"reactions.":[66]},"counts_by_year":[{"year":2026,"cited_by_count":8},{"year":2025,"cited_by_count":8},{"year":2024,"cited_by_count":6},{"year":2023,"cited_by_count":3},{"year":2022,"cited_by_count":12},{"year":2021,"cited_by_count":6},{"year":2020,"cited_by_count":4},{"year":2019,"cited_by_count":7},{"year":2018,"cited_by_count":9},{"year":2017,"cited_by_count":8},{"year":2016,"cited_by_count":2},{"year":2015,"cited_by_count":15},{"year":2014,"cited_by_count":10},{"year":2013,"cited_by_count":6},{"year":2012,"cited_by_count":7}],"updated_date":"2026-10-22T09:42:04.148104","created_date":"2016-06-24T00:00:00"}