{"id":"https://openalex.org/W1963806719","doi":"https://doi.org/10.1021/ja017214g","title":"Rapid Excited-State Structural Reorganization Captured by Pulsed X-rays","display_name":"Rapid Excited-State Structural Reorganization Captured by Pulsed X-rays","publication_year":2002,"publication_date":"2002-08-15","ids":{"openalex":"https://openalex.org/W1963806719","doi":"https://doi.org/10.1021/ja017214g","mag":"1963806719","pmid":"https://pubmed.ncbi.nlm.nih.gov/12207541"},"language":"en","primary_location":{"id":"doi:10.1021/ja017214g","doi":"https://doi.org/10.1021/ja017214g","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja017214g","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5014620636","display_name":"Lin X. Chen","orcid":"https://orcid.org/0000-0002-8450-6687","observed_orcids":["https://orcid.org/0000-0002-8450-6687"]},"institutions":[{"id":"https://openalex.org/I1282105669","display_name":"Argonne National Laboratory","ror":"https://ror.org/05gvnxz63","country_code":"US","type":"facility","lineage":["https://openalex.org/I1282105669","https://openalex.org/I1330989302","https://openalex.org/I39565521","https://openalex.org/I40347166"]},{"id":"https://openalex.org/I145311948","display_name":"Johns Hopkins University","ror":"https://ror.org/00za53h95","country_code":"US","type":"education","lineage":["https://openalex.org/I145311948"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Lin X. Chen","raw_affiliation_strings":["Contribution from the Chemistry Division and Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439, and Department of Chemistry, The Johns Hopkins University, Baltimore, Maryland 21210","argonne national laboratory"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Chemistry Division and Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439, and Department of Chemistry, The Johns Hopkins University, Baltimore, Maryland 21210","institution_ids":["https://openalex.org/I1282105669","https://openalex.org/I145311948"]},{"raw_affiliation_string":"argonne national laboratory","institution_ids":["https://openalex.org/I1282105669"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5000114383","display_name":"Guy Jennings","orcid":"https://orcid.org/0000-0001-6790-2904","observed_orcids":["https://orcid.org/0000-0001-6790-2904"]},"institutions":[{"id":"https://openalex.org/I1282105669","display_name":"Argonne National Laboratory","ror":"https://ror.org/05gvnxz63","country_code":"US","type":"facility","lineage":["https://openalex.org/I1282105669","https://openalex.org/I1330989302","https://openalex.org/I39565521","https://openalex.org/I40347166"]},{"id":"https://openalex.org/I145311948","display_name":"Johns Hopkins University","ror":"https://ror.org/00za53h95","country_code":"US","type":"education","lineage":["https://openalex.org/I145311948"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Guy Jennings","raw_affiliation_strings":["Contribution from the Chemistry Division and Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439, and Department of Chemistry, The Johns Hopkins University, Baltimore, Maryland 21210","argonne national laboratory"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Chemistry Division and Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439, and Department of Chemistry, The Johns Hopkins University, Baltimore, Maryland 21210","institution_ids":["https://openalex.org/I1282105669","https://openalex.org/I145311948"]},{"raw_affiliation_string":"argonne national laboratory","institution_ids":["https://openalex.org/I1282105669"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5021568197","display_name":"Tao Liu","orcid":"https://orcid.org/0000-0001-6763-6271","observed_orcids":["https://orcid.org/0000-0001-6763-6271"]},"institutions":[{"id":"https://openalex.org/I1282105669","display_name":"Argonne National Laboratory","ror":"https://ror.org/05gvnxz63","country_code":"US","type":"facility","lineage":["https://openalex.org/I1282105669","https://openalex.org/I1330989302","https://openalex.org/I39565521","https://openalex.org/I40347166"]},{"id":"https://openalex.org/I145311948","display_name":"Johns Hopkins University","ror":"https://ror.org/00za53h95","country_code":"US","type":"education","lineage":["https://openalex.org/I145311948"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Tao Liu","raw_affiliation_strings":["Contribution from the Chemistry Division and Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439, and Department of Chemistry, The Johns Hopkins University, Baltimore, Maryland 21210","argonne national laboratory"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Chemistry Division and Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439, and Department of Chemistry, The Johns Hopkins University, Baltimore, Maryland 21210","institution_ids":["https://openalex.org/I1282105669","https://openalex.org/I145311948"]},{"raw_affiliation_string":"argonne national laboratory","institution_ids":["https://openalex.org/I1282105669"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5068778877","display_name":"David J. Gosztola","orcid":"https://orcid.org/0000-0003-2674-1379","observed_orcids":["https://orcid.org/0000-0003-2674-1379"]},"institutions":[{"id":"https://openalex.org/I1282105669","display_name":"Argonne National Laboratory","ror":"https://ror.org/05gvnxz63","country_code":"US","type":"facility","lineage":["https://openalex.org/I1282105669","https://openalex.org/I1330989302","https://openalex.org/I39565521","https://openalex.org/I40347166"]},{"id":"https://openalex.org/I145311948","display_name":"Johns Hopkins University","ror":"https://ror.org/00za53h95","country_code":"US","type":"education","lineage":["https://openalex.org/I145311948"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"David J. Gosztola","raw_affiliation_strings":["Contribution from the Chemistry Division and Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439, and Department of Chemistry, The Johns Hopkins University, Baltimore, Maryland 21210","argonne national laboratory"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Chemistry Division and Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439, and Department of Chemistry, The Johns Hopkins University, Baltimore, Maryland 21210","institution_ids":["https://openalex.org/I1282105669","https://openalex.org/I145311948"]},{"raw_affiliation_string":"argonne national laboratory","institution_ids":["https://openalex.org/I1282105669"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5003290182","display_name":"Jan P. Hessler","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1282105669","display_name":"Argonne National Laboratory","ror":"https://ror.org/05gvnxz63","country_code":"US","type":"facility","lineage":["https://openalex.org/I1282105669","https://openalex.org/I1330989302","https://openalex.org/I39565521","https://openalex.org/I40347166"]},{"id":"https://openalex.org/I145311948","display_name":"Johns Hopkins University","ror":"https://ror.org/00za53h95","country_code":"US","type":"education","lineage":["https://openalex.org/I145311948"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Jan P. Hessler","raw_affiliation_strings":["Contribution from the Chemistry Division and Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439, and Department of Chemistry, The Johns Hopkins University, Baltimore, Maryland 21210","argonne national laboratory"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Chemistry Division and Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439, and Department of Chemistry, The Johns Hopkins University, Baltimore, Maryland 21210","institution_ids":["https://openalex.org/I1282105669","https://openalex.org/I145311948"]},{"raw_affiliation_string":"argonne national laboratory","institution_ids":["https://openalex.org/I1282105669"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5087986081","display_name":"Donald V. Scaltrito","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1282105669","display_name":"Argonne National Laboratory","ror":"https://ror.org/05gvnxz63","country_code":"US","type":"facility","lineage":["https://openalex.org/I1282105669","https://openalex.org/I1330989302","https://openalex.org/I39565521","https://openalex.org/I40347166"]},{"id":"https://openalex.org/I145311948","display_name":"Johns Hopkins University","ror":"https://ror.org/00za53h95","country_code":"US","type":"education","lineage":["https://openalex.org/I145311948"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Donald V. Scaltrito","raw_affiliation_strings":["Contribution from the Chemistry Division and Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439, and Department of Chemistry, The Johns Hopkins University, Baltimore, Maryland 21210"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Chemistry Division and Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439, and Department of Chemistry, The Johns Hopkins University, Baltimore, Maryland 21210","institution_ids":["https://openalex.org/I1282105669","https://openalex.org/I145311948"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5073119387","display_name":"Gerald J. Meyer","orcid":"https://orcid.org/0000-0002-4227-6393","observed_orcids":["https://orcid.org/0000-0002-4227-6393"]},"institutions":[{"id":"https://openalex.org/I1282105669","display_name":"Argonne National Laboratory","ror":"https://ror.org/05gvnxz63","country_code":"US","type":"facility","lineage":["https://openalex.org/I1282105669","https://openalex.org/I1330989302","https://openalex.org/I39565521","https://openalex.org/I40347166"]},{"id":"https://openalex.org/I145311948","display_name":"Johns Hopkins University","ror":"https://ror.org/00za53h95","country_code":"US","type":"education","lineage":["https://openalex.org/I145311948"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Gerald J. Meyer","raw_affiliation_strings":["Contribution from the Chemistry Division and Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439, and Department of Chemistry, The Johns Hopkins University, Baltimore, Maryland 21210"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Chemistry Division and Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439, and Department of Chemistry, The Johns Hopkins University, Baltimore, Maryland 21210","institution_ids":["https://openalex.org/I1282105669","https://openalex.org/I145311948"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5014620636"],"corresponding_institution_ids":["https://openalex.org/I1282105669","https://openalex.org/I145311948"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":5.5028,"has_fulltext":false,"cited_by_count":158,"citation_normalized_percentile":{"value":0.97032177,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":93,"max":100},"biblio":{"volume":"124","issue":"36","first_page":"10861","last_page":"10867"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11129","display_name":"Photochemistry and Electron Transfer Studies","score":0.8109999895095825,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11129","display_name":"Photochemistry and Electron Transfer Studies","score":0.8109999895095825,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11177","display_name":"Spectroscopy and Quantum Chemical Studies","score":0.04610000178217888,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11733","display_name":"X-ray Spectroscopy and Fluorescence Analysis","score":0.032499998807907104,"subfield":{"id":"https://openalex.org/subfields/3108","display_name":"Radiation"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/metal-to-ligand-charge-transfer","display_name":"metal-to-ligand charge transfer","score":0.9020000100135803},{"id":"https://openalex.org/keywords/copper-i-complexes","display_name":"copper(I) complexes","score":0.8949999809265137},{"id":"https://openalex.org/keywords/2-9-dimethyl-1-10-phenanthroline","display_name":"2,9-dimethyl-1,10-phenanthroline","score":0.9599999785423279},{"id":"https://openalex.org/keywords/five-coordinate-copper","display_name":"five-coordinate copper","score":0.6830000281333923},{"id":"https://openalex.org/keywords/distorted-trigonal-bipyramidal-geometry","display_name":"distorted trigonal bipyramidal geometry","score":0.8500000238418579},{"id":"https://openalex.org/keywords/cu-n-bond-length","display_name":"Cu-N bond length","score":0.8669999837875366}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8535038828849792},{"id":"https://openalex.org/C181500209","wikidata":"https://www.wikidata.org/wiki/Q215328","display_name":"Excited state","level":2,"score":0.8462037444114685},{"id":"https://openalex.org/C85080765","wikidata":"https://www.wikidata.org/wiki/Q614893","display_name":"Photoluminescence","level":2,"score":0.7145971059799194},{"id":"https://openalex.org/C155220765","wikidata":"https://www.wikidata.org/wiki/Q16905737","display_name":"Photoexcitation","level":3,"score":0.7008690237998962},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.5792993307113647},{"id":"https://openalex.org/C155860418","wikidata":"https://www.wikidata.org/wiki/Q863695","display_name":"Bond length","level":3,"score":0.5406266450881958},{"id":"https://openalex.org/C193547582","wikidata":"https://www.wikidata.org/wiki/Q911331","display_name":"Molecular geometry","level":3,"score":0.5036508440971375},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.48054176568984985},{"id":"https://openalex.org/C111592845","wikidata":"https://www.wikidata.org/wiki/Q2867924","display_name":"Trigonal bipyramidal molecular geometry","level":3,"score":0.47287413477897644},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.43144360184669495},{"id":"https://openalex.org/C69523127","wikidata":"https://www.wikidata.org/wiki/Q4480008","display_name":"Ground state","level":2,"score":0.41692274808883667},{"id":"https://openalex.org/C184779094","wikidata":"https://www.wikidata.org/wiki/Q26383","display_name":"Atomic physics","level":1,"score":0.26835718750953674},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.23966968059539795},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.22173506021499634},{"id":"https://openalex.org/C120665830","wikidata":"https://www.wikidata.org/wiki/Q14620","display_name":"Optics","level":1,"score":0.08523449301719666},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.06708094477653503},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C170493617","wikidata":"https://www.wikidata.org/wiki/Q208467","display_name":"Receptor","level":2,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1021/ja017214g","doi":"https://doi.org/10.1021/ja017214g","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja017214g","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},{"id":"pmid:12207541","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/12207541","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":75,"referenced_works":["https://openalex.org/W165651719","https://openalex.org/W250668721","https://openalex.org/W577968295","https://openalex.org/W1497399712","https://openalex.org/W1497449820","https://openalex.org/W1520991451","https://openalex.org/W1964603841","https://openalex.org/W1965450832","https://openalex.org/W1969919479","https://openalex.org/W1973323475","https://openalex.org/W1975165348","https://openalex.org/W1975878087","https://openalex.org/W1977312621","https://openalex.org/W1978026556","https://openalex.org/W1978509514","https://openalex.org/W1980905899","https://openalex.org/W1987479350","https://openalex.org/W1987741147","https://openalex.org/W1987789400","https://openalex.org/W1992143807","https://openalex.org/W1993804553","https://openalex.org/W1997427363","https://openalex.org/W1998454659","https://openalex.org/W2004253252","https://openalex.org/W2007078309","https://openalex.org/W2007825244","https://openalex.org/W2010297085","https://openalex.org/W2012688681","https://openalex.org/W2016138958","https://openalex.org/W2022996442","https://openalex.org/W2024749585","https://openalex.org/W2025325691","https://openalex.org/W2029870968","https://openalex.org/W2030131984","https://openalex.org/W2030434346","https://openalex.org/W2031779266","https://openalex.org/W2036240062","https://openalex.org/W2037555342","https://openalex.org/W2038119349","https://openalex.org/W2039583181","https://openalex.org/W2042488345","https://openalex.org/W2044238202","https://openalex.org/W2045562184","https://openalex.org/W2049810297","https://openalex.org/W2053098690","https://openalex.org/W2054683675","https://openalex.org/W2055392032","https://openalex.org/W2056308677","https://openalex.org/W2058570219","https://openalex.org/W2062347464","https://openalex.org/W2064901953","https://openalex.org/W2065497508","https://openalex.org/W2069235201","https://openalex.org/W2069715982","https://openalex.org/W2069739722","https://openalex.org/W2070673278","https://openalex.org/W2075624341","https://openalex.org/W2078171437","https://openalex.org/W2079658152","https://openalex.org/W2082301275","https://openalex.org/W2086880887","https://openalex.org/W2087096562","https://openalex.org/W2120104062","https://openalex.org/W2129995310","https://openalex.org/W2141603171","https://openalex.org/W2143197614","https://openalex.org/W2162332156","https://openalex.org/W2169936405","https://openalex.org/W2173429510","https://openalex.org/W2269300947","https://openalex.org/W2313298951","https://openalex.org/W2329952272","https://openalex.org/W2486883092","https://openalex.org/W2950171273","https://openalex.org/W3023165446"],"related_works":["https://openalex.org/W2153040925","https://openalex.org/W2104148174","https://openalex.org/W1971032041","https://openalex.org/W2087060456","https://openalex.org/W2001413583","https://openalex.org/W2698840911","https://openalex.org/W2786850057","https://openalex.org/W2015200559","https://openalex.org/W2321560026","https://openalex.org/W2899510233"],"abstract_inverted_index":{"Visible":[0],"light":[1],"excitation":[2],"of":[3,26,69,115],"[Cu(I)(dmp)(2)](BArF),":[4],"where":[5],"dmp":[6],"is":[7,11,92],"2,9-dimethyl-1,10-phenanthroline":[8],"and":[9,65,102],"BArF":[10],"tetrakis(3,5-bis(trifluoromethylphenyl))borate,":[12],"in":[13,48,79,120],"toluene":[14],"produces":[15],"a":[16,24,44,49,58,66,116,124],"photoluminescent,":[17],"metal-to-ligand":[18],"charge-transfer":[19],"(MLCT)":[20],"excited":[21,81,118],"state":[22,33,82,91,119],"with":[23,39,61],"lifetime":[25],"98":[27],"+/-":[28],"5":[29],"ns.":[30],"Probing":[31],"this":[32],"within":[34],"14":[35],"ns":[36],"after":[37],"photoexcitation":[38],"pulsed":[40],"X-rays":[41],"establishes":[42],"that":[43,99],"Cu(II)":[45],"center,":[46],"borne":[47],"Cu(I)":[50],"geometry,":[51],"binds":[52],"an":[53],"additional":[54],"ligand":[55],"to":[56],"form":[57],"five-coordinate":[59,89],"complex":[60],"increased":[62],"bond":[63,76],"lengths":[64],"coordination":[67],"geometry":[68],"distorted":[70],"trigonal":[71],"bipyramid.":[72],"The":[73,86,108],"average":[74],"Cu-N":[75],"length":[77],"increases":[78],"the":[80,95,100,111],"by":[83],"0.07":[84],"A.":[85],"transiently":[87],"formed":[88],"MLCT":[90],"photoluminescent":[93],"under":[94],"condition":[96],"studied,":[97],"indicating":[98],"absorptive":[101],"emissive":[103],"states":[104],"have":[105],"distinct":[106],"geometries.":[107],"data":[109],"represent":[110],"first":[112],"X-ray":[113],"characterization":[114],"molecular":[117],"fluid":[121],"solution":[122],"on":[123],"nanosecond":[125],"time":[126],"scale.":[127]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2025,"cited_by_count":3},{"year":2024,"cited_by_count":2},{"year":2023,"cited_by_count":7},{"year":2022,"cited_by_count":7},{"year":2021,"cited_by_count":8},{"year":2020,"cited_by_count":6},{"year":2019,"cited_by_count":3},{"year":2018,"cited_by_count":11},{"year":2017,"cited_by_count":14},{"year":2016,"cited_by_count":7},{"year":2015,"cited_by_count":6},{"year":2014,"cited_by_count":9},{"year":2013,"cited_by_count":15},{"year":2012,"cited_by_count":8}],"updated_date":"2026-10-08T09:06:37.294493","created_date":"2016-06-24T00:00:00"}
