{"id":"https://openalex.org/W192525544","doi":null,"title":"Design, Synthesis, and Application of Photoactive Complexes of Biologically Relevant Metals","display_name":"Design, Synthesis, and Application of Photoactive Complexes of Biologically Relevant Metals","publication_year":2013,"publication_date":"2013-01-01","ids":{"openalex":"https://openalex.org/W192525544","mag":"192525544"},"language":"en","primary_location":{"id":"pmh:oai:opencommons.uconn.edu:dissertations-6382","doi":null,"is_oa":true,"landing_page_url":"https://opencommons.uconn.edu/dissertations/235","pdf_url":"https://opencommons.uconn.edu/dissertations/235","source":{"id":"https://openalex.org/S4306401180","display_name":"OpenCommons at University of Connecticut (University of Connecticut)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I140172145","host_organization_name":"University of Connecticut","host_organization_lineage":["https://openalex.org/I140172145"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Doctoral Dissertations","raw_type":"text"},"volume":null,"type":"dissertation","is_traditional":true,"indexed_in":[],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://opencommons.uconn.edu/dissertations/235","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5001271624","display_name":"Celina Gwizdala","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":true,"raw_author_name":"Celina Gwizdala","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":["https://openalex.org/A5001271624"],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":null,"has_fulltext":true,"cited_by_count":0,"citation_normalized_percentile":null,"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11708","display_name":"Photochromic and Fluorescence Chemistry","score":0.8119999766349792,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11708","display_name":"Photochromic and Fluorescence Chemistry","score":0.8119999766349792,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10578","display_name":"Supramolecular Chemistry and Complexes","score":0.05869999900460243,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10163","display_name":"Metal complexes synthesis and properties","score":0.05420000106096268,"subfield":{"id":"https://openalex.org/subfields/2730","display_name":"Oncology"},"field":{"id":"https://openalex.org/fields/27","display_name":"Medicine"},"domain":{"id":"https://openalex.org/domains/4","display_name":"Health Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/photolabile-protecting-groups","display_name":"photolabile protecting groups","score":0.6589999794960022},{"id":"https://openalex.org/keywords/photochemical-release","display_name":"photochemical release","score":0.5109999775886536},{"id":"https://openalex.org/keywords/metal-ligand-interactions","display_name":"metal-ligand interactions","score":0.7160000205039978},{"id":"https://openalex.org/keywords/zinc-ii-complexes","display_name":"zinc(II) complexes","score":0.8259999752044678},{"id":"https://openalex.org/keywords/nickel-ii-complexes","display_name":"nickel(II) complexes","score":1.0},{"id":"https://openalex.org/keywords/photochemical-properties","display_name":"photochemical properties","score":0.31700000166893005}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.49330297112464905},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.3707018494606018},{"id":"https://openalex.org/C183696295","wikidata":"https://www.wikidata.org/wiki/Q2487696","display_name":"Biochemical engineering","level":1,"score":0.35075730085372925},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.3463892936706543},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.2817596197128296},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.16249486804008484}],"mesh":[],"locations_count":3,"locations":[{"id":"pmh:oai:opencommons.uconn.edu:dissertations-6382","doi":null,"is_oa":true,"landing_page_url":"https://opencommons.uconn.edu/dissertations/235","pdf_url":"https://opencommons.uconn.edu/dissertations/235","source":{"id":"https://openalex.org/S4306401180","display_name":"OpenCommons at University of Connecticut (University of Connecticut)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I140172145","host_organization_name":"University of Connecticut","host_organization_lineage":["https://openalex.org/I140172145"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Doctoral Dissertations","raw_type":"text"},{"id":"pmh:oai:digitalcommons.lib.uconn.edu:dissertations-6382","doi":null,"is_oa":false,"landing_page_url":"https://digitalcommons.lib.uconn.edu/dissertations/235","pdf_url":null,"source":{"id":"https://openalex.org/S4377196438","display_name":"OpenCommons - UConn (University of Connecticut)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I140172145","host_organization_name":"University of Connecticut","host_organization_lineage":["https://openalex.org/I140172145"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Doctoral Dissertations","raw_type":"text"},{"id":"mag:192525544","doi":null,"is_oa":false,"landing_page_url":"http://digitalcommons.uconn.edu/cgi/viewcontent.cgi?article=6382&context=dissertations","pdf_url":null,"source":null,"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":null}],"best_oa_location":{"id":"pmh:oai:opencommons.uconn.edu:dissertations-6382","doi":null,"is_oa":true,"landing_page_url":"https://opencommons.uconn.edu/dissertations/235","pdf_url":"https://opencommons.uconn.edu/dissertations/235","source":{"id":"https://openalex.org/S4306401180","display_name":"OpenCommons at University of Connecticut (University of Connecticut)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I140172145","host_organization_name":"University of Connecticut","host_organization_lineage":["https://openalex.org/I140172145"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Doctoral Dissertations","raw_type":"text"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320310017","display_name":"University of Connecticut","ror":"https://ror.org/02der9h97"}],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W192525544.pdf","grobid_xml":"https://content.openalex.org/works/W192525544.grobid-xml"},"referenced_works_count":218,"referenced_works":["https://openalex.org/W63999107","https://openalex.org/W161087755","https://openalex.org/W181455524","https://openalex.org/W279719195","https://openalex.org/W1489844805","https://openalex.org/W1529658397","https://openalex.org/W1531010890","https://openalex.org/W1545990390","https://openalex.org/W1552886287","https://openalex.org/W1566080486","https://openalex.org/W1567645807","https://openalex.org/W1589096200","https://openalex.org/W1601936385","https://openalex.org/W1916834624","https://openalex.org/W1946266499","https://openalex.org/W1963851776","https://openalex.org/W1965433258","https://openalex.org/W1965893090","https://openalex.org/W1966521314","https://openalex.org/W1966765421","https://openalex.org/W1967764516","https://openalex.org/W1968608086","https://openalex.org/W1970037890","https://openalex.org/W1970271735","https://openalex.org/W1970503230","https://openalex.org/W1970697235","https://openalex.org/W1971352570","https://openalex.org/W1971979491","https://openalex.org/W1972856320","https://openalex.org/W1975194767","https://openalex.org/W1975606578","https://openalex.org/W1976027757","https://openalex.org/W1976626198","https://openalex.org/W1978059664","https://openalex.org/W1978298108","https://openalex.org/W1981728848","https://openalex.org/W1983078818","https://openalex.org/W1986706568","https://openalex.org/W1987777821","https://openalex.org/W1987873761","https://openalex.org/W1987885461","https://openalex.org/W1990262536","https://openalex.org/W1991058376","https://openalex.org/W1992240624","https://openalex.org/W1994300410","https://openalex.org/W1995047705","https://openalex.org/W1997101105","https://openalex.org/W1997116271","https://openalex.org/W1998332060","https://openalex.org/W1998689607","https://openalex.org/W1999829108","https://openalex.org/W2001731920","https://openalex.org/W2002273487","https://openalex.org/W2002769318","https://openalex.org/W2003394120","https://openalex.org/W2003877206","https://openalex.org/W2004441489","https://openalex.org/W2004750204","https://openalex.org/W2006162922","https://openalex.org/W2006566278","https://openalex.org/W2007121764","https://openalex.org/W2007973974","https://openalex.org/W2008326745","https://openalex.org/W2009248881","https://openalex.org/W2010338437","https://openalex.org/W2011178113","https://openalex.org/W2011444292","https://openalex.org/W2011817526","https://openalex.org/W2011994921","https://openalex.org/W2012150706","https://openalex.org/W2012171863","https://openalex.org/W2015080364","https://openalex.org/W2015687472","https://openalex.org/W2016034432","https://openalex.org/W2016213681","https://openalex.org/W2017350478","https://openalex.org/W2018343864","https://openalex.org/W2018411741","https://openalex.org/W2019345165","https://openalex.org/W2019465667","https://openalex.org/W2019815430","https://openalex.org/W2021142922","https://openalex.org/W2021330392","https://openalex.org/W2021384117","https://openalex.org/W2021840869","https://openalex.org/W2022243850","https://openalex.org/W2022372170","https://openalex.org/W2025081536","https://openalex.org/W2025230186","https://openalex.org/W2026536857","https://openalex.org/W2027092152","https://openalex.org/W2027244224","https://openalex.org/W2027532474","https://openalex.org/W2031923138","https://openalex.org/W2032449682","https://openalex.org/W2033543720","https://openalex.org/W2034156020","https://openalex.org/W2034516685","https://openalex.org/W2035594105","https://openalex.org/W2036839645","https://openalex.org/W2037360899","https://openalex.org/W2039517040","https://openalex.org/W2041243006","https://openalex.org/W2041315640","https://openalex.org/W2041516978","https://openalex.org/W2042729782","https://openalex.org/W2044797989","https://openalex.org/W2044954908","https://openalex.org/W2045261923","https://openalex.org/W2046225168","https://openalex.org/W2046540215","https://openalex.org/W2047679766","https://openalex.org/W2047980386","https://openalex.org/W2048011909","https://openalex.org/W2048038561","https://openalex.org/W2051891646","https://openalex.org/W2056839774","https://openalex.org/W2056925277","https://openalex.org/W2057310735","https://openalex.org/W2057785882","https://openalex.org/W2058257263","https://openalex.org/W2058449890","https://openalex.org/W2060510783","https://openalex.org/W2062402454","https://openalex.org/W2064039337","https://openalex.org/W2066269552","https://openalex.org/W2066753925","https://openalex.org/W2067119870","https://openalex.org/W2067747196","https://openalex.org/W2069258252","https://openalex.org/W2069856306","https://openalex.org/W2070416972","https://openalex.org/W2072829138","https://openalex.org/W2073125666","https://openalex.org/W2073391931","https://openalex.org/W2073586079","https://openalex.org/W2073957896","https://openalex.org/W2076809828","https://openalex.org/W2078134576","https://openalex.org/W2080122988","https://openalex.org/W2080728275","https://openalex.org/W2080728286","https://openalex.org/W2082819269","https://openalex.org/W2084150073","https://openalex.org/W2084238143","https://openalex.org/W2084298135","https://openalex.org/W2085948911","https://openalex.org/W2086412150","https://openalex.org/W2087891209","https://openalex.org/W2089178918","https://openalex.org/W2091541329","https://openalex.org/W2091926475","https://openalex.org/W2092435369","https://openalex.org/W2093477805","https://openalex.org/W2095217327","https://openalex.org/W2099033590","https://openalex.org/W2099452465","https://openalex.org/W2102262216","https://openalex.org/W2103391184","https://openalex.org/W2106301585","https://openalex.org/W2107356219","https://openalex.org/W2112841789","https://openalex.org/W2113372436","https://openalex.org/W2113977236","https://openalex.org/W2113989003","https://openalex.org/W2114015514","https://openalex.org/W2115230397","https://openalex.org/W2118480909","https://openalex.org/W2121798267","https://openalex.org/W2123755851","https://openalex.org/W2125485599","https://openalex.org/W2126753850","https://openalex.org/W2127431229","https://openalex.org/W2128583282","https://openalex.org/W2129774902","https://openalex.org/W2129900289","https://openalex.org/W2130002263","https://openalex.org/W2132082655","https://openalex.org/W2134207299","https://openalex.org/W2137046511","https://openalex.org/W2138149556","https://openalex.org/W2141260882","https://openalex.org/W2141993272","https://openalex.org/W2144084268","https://openalex.org/W2147519918","https://openalex.org/W2148414166","https://openalex.org/W2148905438","https://openalex.org/W2149501548","https://openalex.org/W2149888617","https://openalex.org/W2150956904","https://openalex.org/W2151790597","https://openalex.org/W2153145418","https://openalex.org/W2153354382","https://openalex.org/W2154439380","https://openalex.org/W2154540873","https://openalex.org/W2163303549","https://openalex.org/W2164258188","https://openalex.org/W2169683197","https://openalex.org/W2169873791","https://openalex.org/W2171586071","https://openalex.org/W2173171001","https://openalex.org/W2186160472","https://openalex.org/W2255476717","https://openalex.org/W2265482255","https://openalex.org/W2309071537","https://openalex.org/W2317404884","https://openalex.org/W2324147209","https://openalex.org/W2329919819","https://openalex.org/W2334168751","https://openalex.org/W2337785167","https://openalex.org/W2339374716","https://openalex.org/W2340378922","https://openalex.org/W2418520519","https://openalex.org/W2460599504","https://openalex.org/W2829353795","https://openalex.org/W2951924024","https://openalex.org/W2952127876","https://openalex.org/W4302085217"],"related_works":["https://openalex.org/W7101137379","https://openalex.org/W2126753850","https://openalex.org/W4387164926","https://openalex.org/W4245953163","https://openalex.org/W2113989003","https://openalex.org/W41597602","https://openalex.org/W2080122988","https://openalex.org/W2313516423","https://openalex.org/W2955570620","https://openalex.org/W2149501548"],"abstract_inverted_index":{"Photo-labile":[0],"organic":[1],"molecules":[2],"have":[3],"been":[4],"broadly":[5],"utilized":[6],"as":[7],"photoprotective":[8],"groups":[9],"(PPGs)":[10],"in":[11,21,67],"\u201ccaging":[12],"compounds\u201d.":[13],"Inactive":[14],"caged":[15],"analyte":[16,43],"can":[17],"be":[18],"easily":[19],"introduced":[20],"its":[22,52],"active":[23],"form":[24],"to":[25],"the":[26,33,42,79],"system":[27],"under":[28],"investigation":[29],"by":[30,71],"photolysis":[31],"of":[32,41,51,60,73,76,87,91],"PPG.":[34],"This":[35],"light":[36],"induced":[37],"manipulation":[38],"permits":[39],"release":[40,62],"and":[44,48,84,93,97],"allows":[45],"for":[46],"spatial":[47],"temporal":[49],"control":[50],"concentration.":[53],"Photocages":[54],"presented":[55,96],"within":[56],"utilize":[57],"specific":[58],"strategy":[59],"metal":[61,80],"that":[63],"relies":[64],"on":[65,78],"decrease":[66],"metal-ligand":[68],"interaction":[69],"triggered":[70],"delocalization":[72],"lone":[74],"pair":[75],"electrons":[77],"coordinating":[81],"nitrogen(s).":[82],"Synthesis":[83],"photochemical":[85],"properties":[86],"nitrobenzhydrol":[88],"based":[89],"photocages":[90],"Zn2+":[92],"Ni2+":[94],"are":[95],"discussed.":[98]},"counts_by_year":[],"updated_date":"2026-10-27T15:51:10.671819","created_date":"2016-06-24T00:00:00"}
