{"id":"https://openalex.org/W1903185053","doi":"https://doi.org/10.1080/00268978300100901","title":"The HeI excited electron spectrum of phosphine: An experimental and theoretical study","display_name":"The HeI excited electron spectrum of phosphine: An experimental and theoretical study","publication_year":1983,"publication_date":"1983-04-20","ids":{"openalex":"https://openalex.org/W1903185053","doi":"https://doi.org/10.1080/00268978300100901","mag":"1903185053"},"language":"en","primary_location":{"id":"doi:10.1080/00268978300100901","doi":"https://doi.org/10.1080/00268978300100901","is_oa":false,"landing_page_url":"https://doi.org/10.1080/00268978300100901","pdf_url":null,"source":{"id":"https://openalex.org/S204809294","display_name":"Molecular Physics","issn_l":"0026-8976","issn":["0026-8976","1362-3028"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","jufo-1","norway-1","poland-70","russia-white-list-3"],"host_organization":"https://openalex.org/P4310320547","host_organization_name":"Taylor & Francis","host_organization_lineage":["https://openalex.org/P4310320547","https://openalex.org/P4310320449"],"host_organization_lineage_names":["Taylor & Francis","Informa"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Molecular Physics","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5011061613","display_name":"R. Maripuu","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I123387679","display_name":"Uppsala University","ror":"https://ror.org/048a87296","country_code":"SE","type":"education","lineage":["https://openalex.org/I123387679"]}],"countries":["SE"],"is_corresponding":false,"raw_author_name":"R. Maripuu","raw_affiliation_strings":["Institute of Physics, Uppsala University, Box 530, S-751 21, Uppsala"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute of Physics, Uppsala University, Box 530, S-751 21, Uppsala","institution_ids":["https://openalex.org/I123387679"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5046542999","display_name":"Ingrid Reineck","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I123387679","display_name":"Uppsala University","ror":"https://ror.org/048a87296","country_code":"SE","type":"education","lineage":["https://openalex.org/I123387679"]}],"countries":["SE"],"is_corresponding":false,"raw_author_name":"I. Reineck","raw_affiliation_strings":["Institute of Physics, Uppsala University, Box 530, S-751 21, Uppsala"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute of Physics, Uppsala University, Box 530, S-751 21, Uppsala","institution_ids":["https://openalex.org/I123387679"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5053665869","display_name":"Hans \u00c5gren","orcid":"https://orcid.org/0000-0002-1763-9383","observed_orcids":["https://orcid.org/0000-0002-1763-9383","https://orcid.org/0000-0003-0847-6700"]},"institutions":[{"id":"https://openalex.org/I123387679","display_name":"Uppsala University","ror":"https://ror.org/048a87296","country_code":"SE","type":"education","lineage":["https://openalex.org/I123387679"]},{"id":"https://openalex.org/I187531555","display_name":"Lund University","ror":"https://ror.org/012a77v79","country_code":"SE","type":"education","lineage":["https://openalex.org/I187531555"]}],"countries":["SE"],"is_corresponding":false,"raw_author_name":"H. \u00c5gren","raw_affiliation_strings":["Institute of Physics, Uppsala University, Box 530, S-751 21, Uppsala; Department of Physical Chemistry 2, Kemicentrum, S-220 07, Lund, Sweden","Department of Physical Chemistry 2, Kemicentrum , S-220 07, Lund, Sweden","Institute of Physics, Uppsala University , Box 530, S-751 21, Uppsala"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute of Physics, Uppsala University, Box 530, S-751 21, Uppsala; Department of Physical Chemistry 2, Kemicentrum, S-220 07, Lund, Sweden","institution_ids":["https://openalex.org/I123387679"]},{"raw_affiliation_string":"Department of Physical Chemistry 2, Kemicentrum , S-220 07, Lund, Sweden","institution_ids":["https://openalex.org/I187531555"]},{"raw_affiliation_string":"Institute of Physics, Uppsala University , Box 530, S-751 21, Uppsala","institution_ids":["https://openalex.org/I123387679"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5111393036","display_name":"Nianzu Wu","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I123387679","display_name":"Uppsala University","ror":"https://ror.org/048a87296","country_code":"SE","type":"education","lineage":["https://openalex.org/I123387679"]},{"id":"https://openalex.org/I20231570","display_name":"Peking University","ror":"https://ror.org/02v51f717","country_code":"CN","type":"education","lineage":["https://openalex.org/I20231570"]}],"countries":["CN","SE"],"is_corresponding":false,"raw_author_name":"Wu Nian-Zu","raw_affiliation_strings":["Institute of Physics, Uppsala University, Box 530, S-751 21, Uppsala; Department of Chemistry, Peking University, Peking, China","Department of Chemistry , Peking University , Peking, China","Institute of Physics, Uppsala University , Box 530, S-751 21, Uppsala"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute of Physics, Uppsala University, Box 530, S-751 21, Uppsala; Department of Chemistry, Peking University, Peking, China","institution_ids":["https://openalex.org/I123387679","https://openalex.org/I20231570"]},{"raw_affiliation_string":"Department of Chemistry , Peking University , Peking, China","institution_ids":["https://openalex.org/I20231570"]},{"raw_affiliation_string":"Institute of Physics, Uppsala University , Box 530, S-751 21, Uppsala","institution_ids":["https://openalex.org/I123387679"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5043742155","display_name":"Ji Ming Rong","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I123387679","display_name":"Uppsala University","ror":"https://ror.org/048a87296","country_code":"SE","type":"education","lineage":["https://openalex.org/I123387679"]},{"id":"https://openalex.org/I126520041","display_name":"University of Science and Technology of China","ror":"https://ror.org/04c4dkn09","country_code":"CN","type":"education","lineage":["https://openalex.org/I126520041","https://openalex.org/I19820366"]}],"countries":["CN","SE"],"is_corresponding":false,"raw_author_name":"Ji Ming Rong","raw_affiliation_strings":["Institute of Physics, Uppsala University, Box 530, S-751 21, Uppsala; Department of Chemistry, China University of Science & Technology, Hefei City, Anhui Province, China","Department of Chemistry , China University of Science & Technology , Hefei City, Anhui Province, China","Institute of Physics, Uppsala University , Box 530, S-751 21, Uppsala"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute of Physics, Uppsala University, Box 530, S-751 21, Uppsala; Department of Chemistry, China University of Science & Technology, Hefei City, Anhui Province, China","institution_ids":["https://openalex.org/I123387679"]},{"raw_affiliation_string":"Department of Chemistry , China University of Science & Technology , Hefei City, Anhui Province, China","institution_ids":["https://openalex.org/I126520041"]},{"raw_affiliation_string":"Institute of Physics, Uppsala University , Box 530, S-751 21, Uppsala","institution_ids":["https://openalex.org/I123387679"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5055634577","display_name":"H. Veenhuizen","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I123387679","display_name":"Uppsala University","ror":"https://ror.org/048a87296","country_code":"SE","type":"education","lineage":["https://openalex.org/I123387679"]}],"countries":["SE"],"is_corresponding":false,"raw_author_name":"H. Veenhuizen","raw_affiliation_strings":["Institute of Physics, Uppsala University, Box 530, S-751 21, Uppsala"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute of Physics, Uppsala University, Box 530, S-751 21, Uppsala","institution_ids":["https://openalex.org/I123387679"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5076731344","display_name":"Salim H. Al-Shamma","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I12150220","display_name":"University of Mosul","ror":"https://ror.org/039cf4q47","country_code":"IQ","type":"education","lineage":["https://openalex.org/I12150220"]},{"id":"https://openalex.org/I123387679","display_name":"Uppsala University","ror":"https://ror.org/048a87296","country_code":"SE","type":"education","lineage":["https://openalex.org/I123387679"]}],"countries":["IQ","SE"],"is_corresponding":false,"raw_author_name":"S.H. Al-Shamma","raw_affiliation_strings":["Institute of Physics, Uppsala University, Box 530, S-751 21, Uppsala; Department of Physics and Mathematics, College of Education University of Mosul, Mosul, Iraq","Department of Physics and Mathematics , College of Education University of Mosul , Mosul, Iraq","Institute of Physics, Uppsala University , Box 530, S-751 21, Uppsala"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute of Physics, Uppsala University, Box 530, S-751 21, Uppsala; Department of Physics and Mathematics, College of Education University of Mosul, Mosul, Iraq","institution_ids":["https://openalex.org/I12150220","https://openalex.org/I123387679"]},{"raw_affiliation_string":"Department of Physics and Mathematics , College of Education University of Mosul , Mosul, Iraq","institution_ids":["https://openalex.org/I12150220"]},{"raw_affiliation_string":"Institute of Physics, Uppsala University , Box 530, S-751 21, Uppsala","institution_ids":["https://openalex.org/I123387679"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5053756946","display_name":"Linn\u00e9a Karlsson","orcid":"https://orcid.org/0000-0002-4725-0176","observed_orcids":["https://orcid.org/0000-0002-4725-0176"]},"institutions":[{"id":"https://openalex.org/I123387679","display_name":"Uppsala University","ror":"https://ror.org/048a87296","country_code":"SE","type":"education","lineage":["https://openalex.org/I123387679"]}],"countries":["SE"],"is_corresponding":false,"raw_author_name":"L. Karlsson","raw_affiliation_strings":["Institute of Physics, Uppsala University, Box 530, S-751 21, Uppsala"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute of Physics, Uppsala University, Box 530, S-751 21, Uppsala","institution_ids":["https://openalex.org/I123387679"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5017996890","display_name":"Kai Siegbahn","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I123387679","display_name":"Uppsala University","ror":"https://ror.org/048a87296","country_code":"SE","type":"education","lineage":["https://openalex.org/I123387679"]}],"countries":["SE"],"is_corresponding":false,"raw_author_name":"K. Siegbahn","raw_affiliation_strings":["Institute of Physics, Uppsala University, Box 530, S-751 21, Uppsala"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute of Physics, Uppsala University, Box 530, S-751 21, Uppsala","institution_ids":["https://openalex.org/I123387679"]}]}],"institutions":[],"countries_distinct_count":3,"institutions_distinct_count":5,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":3.2812,"has_fulltext":false,"cited_by_count":42,"citation_normalized_percentile":{"value":0.91100634,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":88,"max":96},"biblio":{"volume":"48","issue":"6","first_page":"1255","last_page":"1267"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10523","display_name":"Atomic and Molecular Physics","score":0.5228999853134155,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10523","display_name":"Atomic and Molecular Physics","score":0.5228999853134155,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12967","display_name":"Molecular Spectroscopy and Structure","score":0.3589000105857849,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10002","display_name":"Advanced Chemical Physics Studies","score":0.06539999693632126,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/phosphine","display_name":"phosphine","score":0.9980000257492065},{"id":"https://openalex.org/keywords/vibrational-progressions","display_name":"vibrational progressions","score":0.7509999871253967},{"id":"https://openalex.org/keywords/inversion-barrier","display_name":"inversion barrier","score":0.6880000233650208},{"id":"https://openalex.org/keywords/ionic-states","display_name":"ionic states","score":0.7059999704360962},{"id":"https://openalex.org/keywords/franck-condon-factors","display_name":"Franck-Condon factors","score":0.8930000066757202},{"id":"https://openalex.org/keywords/casscf","display_name":"CASSCF","score":0.7269999980926514}],"concepts":[{"id":"https://openalex.org/C181500209","wikidata":"https://www.wikidata.org/wiki/Q215328","display_name":"Excited state","level":2,"score":0.800468921661377},{"id":"https://openalex.org/C184779094","wikidata":"https://www.wikidata.org/wiki/Q26383","display_name":"Atomic physics","level":1,"score":0.608599066734314},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6020828485488892},{"id":"https://openalex.org/C2182769","wikidata":"https://www.wikidata.org/wiki/Q62500","display_name":"Ionic bonding","level":3,"score":0.5866780281066895},{"id":"https://openalex.org/C109663097","wikidata":"https://www.wikidata.org/wiki/Q182453","display_name":"Adiabatic process","level":2,"score":0.5102801322937012},{"id":"https://openalex.org/C93282013","wikidata":"https://www.wikidata.org/wiki/Q420754","display_name":"Binding energy","level":2,"score":0.47997379302978516},{"id":"https://openalex.org/C147120987","wikidata":"https://www.wikidata.org/wiki/Q2225","display_name":"Electron","level":2,"score":0.42424681782722473},{"id":"https://openalex.org/C69523127","wikidata":"https://www.wikidata.org/wiki/Q4480008","display_name":"Ground state","level":2,"score":0.419209748506546},{"id":"https://openalex.org/C41999313","wikidata":"https://www.wikidata.org/wiki/Q489328","display_name":"Molecular physics","level":1,"score":0.3203437626361847},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.20060324668884277},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.19070637226104736},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.0},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1080/00268978300100901","doi":"https://doi.org/10.1080/00268978300100901","is_oa":false,"landing_page_url":"https://doi.org/10.1080/00268978300100901","pdf_url":null,"source":{"id":"https://openalex.org/S204809294","display_name":"Molecular Physics","issn_l":"0026-8976","issn":["0026-8976","1362-3028"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","jufo-1","norway-1","poland-70","russia-white-list-3"],"host_organization":"https://openalex.org/P4310320547","host_organization_name":"Taylor & Francis","host_organization_lineage":["https://openalex.org/P4310320547","https://openalex.org/P4310320449"],"host_organization_lineage_names":["Taylor & Francis","Informa"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Molecular Physics","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":21,"referenced_works":["https://openalex.org/W1562257975","https://openalex.org/W1639539194","https://openalex.org/W1967358256","https://openalex.org/W1968035080","https://openalex.org/W1992927636","https://openalex.org/W1997274736","https://openalex.org/W1999144013","https://openalex.org/W2019574913","https://openalex.org/W2023444472","https://openalex.org/W2026473737","https://openalex.org/W2032711755","https://openalex.org/W2035780524","https://openalex.org/W2040624278","https://openalex.org/W2053337631","https://openalex.org/W2054879848","https://openalex.org/W2059058672","https://openalex.org/W2071222005","https://openalex.org/W2077106458","https://openalex.org/W2078100294","https://openalex.org/W2135112612","https://openalex.org/W2163896880"],"related_works":["https://openalex.org/W2092232485","https://openalex.org/W2032711755","https://openalex.org/W2464835304","https://openalex.org/W2078229466","https://openalex.org/W2069071385","https://openalex.org/W2068528618","https://openalex.org/W2066344303","https://openalex.org/W2071222005","https://openalex.org/W2087717363","https://openalex.org/W3170263427"],"abstract_inverted_index":{"The":[0,14,43,76,109],"HeI":[1],"excited":[2],"electron":[3,111],"spectrum":[4],"of":[5,45,72,86,114],"phosphine":[6],"(PH3)":[7],"has":[8,57],"been":[9,58],"recorded":[10],"with":[11,30],"high":[12],"resolution.":[13],"2":[15,27,52,118],"A":[16,53,119,123],"1":[17,54,120,122],"band":[18],"reveals":[19],"an":[20],"extensive":[21],"vibrational":[22,61],"progression":[23],"in":[24,48,91],"the":[25,34,49,73,84,87,101],"v":[26],"bending":[28],"mode":[29],"irregular":[31],"structure":[32],"at":[33],"low":[35],"binding":[36,112],"energy":[37,62,113],"side":[38],"due":[39],"to":[40,97,105,127],"hindered":[41],"inversion.":[42],"existence":[44],"a":[46,80],"barrier":[47,102],"PH3":[50],"+":[51],"ionic":[55,93],"state":[56,94],"confirmed":[59],"by":[60],"level":[63],"and":[64,83,100],"Franck-Condon":[65],"factor":[66],"calculations":[67,71],"based":[68],"on":[69],"CASSCF":[70],"total":[74],"energy.":[75],"equilibrium":[77],"angle":[78],"between":[79],"P-H":[81],"bond":[82],"plane":[85],"three":[88],"hydrogen":[89],"atoms":[90],"this":[92,115],"was":[95,125],"determined":[96],"be":[98,106,128],"15\u00b75\u00b0":[99],"against":[103],"inversion":[104],"160":[107],"meV.":[108],"adiabatic":[110],"transition":[116],"([Xtilde]":[117],"\u2190X":[121],"1)":[124],"found":[126],"9\u00b7868\u00b10\u00b7005":[129],"eV.":[130]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2022,"cited_by_count":1},{"year":2017,"cited_by_count":2},{"year":2016,"cited_by_count":1},{"year":2015,"cited_by_count":1},{"year":2014,"cited_by_count":1},{"year":2013,"cited_by_count":1}],"updated_date":"2026-11-12T12:28:57.059296","created_date":"2016-06-24T00:00:00"}