{"id":"https://openalex.org/W1882899676","doi":"https://doi.org/10.1002/047084289x.rn00548","title":"\u03b1,\u03b1-Dibromotoluene","display_name":"\u03b1,\u03b1-Dibromotoluene","publication_year":2005,"publication_date":"2005-10-15","ids":{"openalex":"https://openalex.org/W1882899676","doi":"https://doi.org/10.1002/047084289x.rn00548","mag":"1882899676"},"language":"en","primary_location":{"id":"doi:10.1002/047084289x.rn00548","doi":"https://doi.org/10.1002/047084289x.rn00548","is_oa":false,"landing_page_url":"https://doi.org/10.1002/047084289x.rn00548","pdf_url":null,"source":{"id":"https://openalex.org/S4306464293","display_name":"Wiley eBooks","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"ebook platform"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Encyclopedia of Reagents for Organic Synthesis","raw_type":"reference-entry"},"volume":{"id":"https://openalex.org/W4212905075","display_name":"Encyclopedia of Reagents for Organic Synthesis"},"type":"reference-entry","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5027503793","display_name":"Nicholas J. Lawrence","orcid":"https://orcid.org/0000-0003-1129-2558","observed_orcids":["https://orcid.org/0000-0003-1129-2558"]},"institutions":[{"id":"https://openalex.org/I2613432","display_name":"University of South Florida","ror":"https://ror.org/032db5x82","country_code":"US","type":"education","lineage":["https://openalex.org/I2613432"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Nicholas J. Lawrence","raw_affiliation_strings":["University of South Florida-Tampa, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"University of South Florida-Tampa, USA","institution_ids":["https://openalex.org/I2613432"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5029342543","display_name":"Benjamin M. Greedy","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I2613432","display_name":"University of South Florida","ror":"https://ror.org/032db5x82","country_code":"US","type":"education","lineage":["https://openalex.org/I2613432"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Benjamin Greedy","raw_affiliation_strings":["University of South Florida-Tampa, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"University of South Florida-Tampa, USA","institution_ids":["https://openalex.org/I2613432"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I2613432"],"apc_list":null,"apc_paid":null,"fwci":null,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":null,"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11831","display_name":"Chemical Synthesis and Reactions","score":0.8115000128746033,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11831","display_name":"Chemical Synthesis and Reactions","score":0.8115000128746033,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13859","display_name":"Organic Chemistry Synthesis Methods","score":0.02889999933540821,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.022199999541044235,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/brominating-reagents","display_name":"brominating reagents","score":0.5519999861717224},{"id":"https://openalex.org/keywords/reagent-toxicity","display_name":"reagent toxicity","score":0.4490000009536743}],"concepts":[{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.2761017084121704}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/047084289x.rn00548","doi":"https://doi.org/10.1002/047084289x.rn00548","is_oa":false,"landing_page_url":"https://doi.org/10.1002/047084289x.rn00548","pdf_url":null,"source":{"id":"https://openalex.org/S4306464293","display_name":"Wiley eBooks","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"ebook platform"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Encyclopedia of Reagents for Organic Synthesis","raw_type":"reference-entry"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":32,"referenced_works":["https://openalex.org/W1538288268","https://openalex.org/W1977959883","https://openalex.org/W1987445928","https://openalex.org/W1990331562","https://openalex.org/W1993790782","https://openalex.org/W2004716911","https://openalex.org/W2015654814","https://openalex.org/W2026643273","https://openalex.org/W2026903724","https://openalex.org/W2031195995","https://openalex.org/W2033575477","https://openalex.org/W2046950527","https://openalex.org/W2058234981","https://openalex.org/W2063056752","https://openalex.org/W2065703540","https://openalex.org/W2078480335","https://openalex.org/W2084176613","https://openalex.org/W2087677900","https://openalex.org/W2111573045","https://openalex.org/W2315251456","https://openalex.org/W2317952529","https://openalex.org/W2325667628","https://openalex.org/W2474982455","https://openalex.org/W2949183658","https://openalex.org/W2949354161","https://openalex.org/W2950814850","https://openalex.org/W2951460210","https://openalex.org/W2951903981","https://openalex.org/W2952396026","https://openalex.org/W2952567971","https://openalex.org/W2953091523","https://openalex.org/W4253226055"],"related_works":["https://openalex.org/W2125185520","https://openalex.org/W4249597858","https://openalex.org/W2124840561","https://openalex.org/W1915083113","https://openalex.org/W1925741547","https://openalex.org/W2162780329","https://openalex.org/W1916697293","https://openalex.org/W1961402005","https://openalex.org/W4250172794","https://openalex.org/W4240840421"],"abstract_inverted_index":{"[618-31-5]\u00a0C7H6Br2\u00a0(MW":[0],"249.93)\r\n\r\n\r\n\r\n\r\n\r\nInChI\u2009=\u20091S/C7H6Br2/c8-7(9)6-4-2-1-3-5-6/h1-5,7H\r\n\r\n\r\n\r\nInChIKey\u2009=\u2009VCJZTATVUDMNLU-UHFFFAOYSA-N\r\n\r\n\r\n\r\n(reagent":[1],"used":[2],"for":[3],"the":[4,57],"introduction":[5],"of":[6],"a":[7,72],"benzylidene":[8],"group)\r\n\r\n\r\n\r\nAlternate":[9],"Name:\u2002":[10],"benzal":[11],"bromide.\r\n\r\n\r\n\r\nPhysical":[12],"Data:\u2002bp":[13],"154\u2013156":[14],"\u2009\u00b0C":[15],"at":[16,33],"31":[17],"mm":[18],"Hg,":[19],"d":[20],"1.845":[21],"g":[22],"cm\u22123.\r\n\r\n\r\n\r\nForm":[23],"Supplied":[24],"in:\u2002":[25],"colorless":[26],"liquid,":[27],"widely":[28],"available.\r\n\r\n\r\n\r\nHandling,":[29],"Storage,":[30],"and":[31,42,49,59,84],"Precautions:\u2002stable":[32],"room":[34],"temperature":[35],"in":[36,54,71],"closed":[37],"containers":[38],"under":[39],"normal":[40],"storage":[41],"handling":[43],"conditions.":[44],"Benzal":[45],"bromide":[46],"causes":[47],"burns":[48],"is":[50,79],"toxic":[51],"by":[52],"inhalation,":[53],"contact":[55],"with":[56,81],"skin,":[58],"if":[60],"swallowed.":[61],"The":[62],"reagent":[63],"should":[64],"be":[65],"handled":[66],"using":[67],"suitable":[68],"protective":[69],"equipment":[70],"well":[73],"ventilated":[74],"fume":[75],"hood.":[76],"This":[77],"compound":[78],"incompatible":[80],"strong":[82,85],"bases":[83],"oxidizing":[86],"agents.":[87]},"counts_by_year":[],"updated_date":"2026-11-05T12:25:35.769452","created_date":"2016-06-24T00:00:00"}