{"id":"https://openalex.org/W1857749463","doi":"https://doi.org/10.1039/c0py00151a","title":"Synthesis of hydrogels viaring-opening metathesispolymerization: factors affecting gelation","display_name":"Synthesis of hydrogels viaring-opening metathesispolymerization: factors affecting gelation","publication_year":2010,"publication_date":"2010-11-01","ids":{"openalex":"https://openalex.org/W1857749463","doi":"https://doi.org/10.1039/c0py00151a","mag":"1857749463"},"language":"en","primary_location":{"id":"doi:10.1039/c0py00151a","doi":"https://doi.org/10.1039/c0py00151a","is_oa":false,"landing_page_url":"https://doi.org/10.1039/c0py00151a","pdf_url":null,"source":{"id":"https://openalex.org/S187215728","display_name":"Polymer Chemistry","issn_l":"1759-9954","issn":["1759-9954","1759-9962"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-1","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Polym. Chem.","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://works.bepress.com/gregory_tew/19/download/","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5110209168","display_name":"Ahmad E. Madkour","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I24603500","display_name":"University of Massachusetts Amherst","ror":"https://ror.org/0072zz521","country_code":"US","type":"education","lineage":["https://openalex.org/I24603500"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Ahmad E. Madkour","raw_affiliation_strings":["Department of Polymer Science & Engineering, University of Massachusetts, 120 Governors Drive, Amherst, MA, USA","Department of Polymer Science and Engineering, University of Massachusetts, 120 Governors Drive,Amherst,USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Polymer Science & Engineering, University of Massachusetts, 120 Governors Drive, Amherst, MA, USA","institution_ids":["https://openalex.org/I24603500"]},{"raw_affiliation_string":"Department of Polymer Science and Engineering, University of Massachusetts, 120 Governors Drive,Amherst,USA","institution_ids":["https://openalex.org/I24603500"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5080856130","display_name":"Joshua M. Grolman","orcid":"https://orcid.org/0000-0001-5418-7235","observed_orcids":["https://orcid.org/0000-0001-5418-7235"]},"institutions":[{"id":"https://openalex.org/I24603500","display_name":"University of Massachusetts Amherst","ror":"https://ror.org/0072zz521","country_code":"US","type":"education","lineage":["https://openalex.org/I24603500"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Joshua M. Grolman","raw_affiliation_strings":["Department of Polymer Science & Engineering, University of Massachusetts, 120 Governors Drive, Amherst, MA, USA","Department of Polymer Science and Engineering, University of Massachusetts, 120 Governors Drive,Amherst,USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Polymer Science & Engineering, University of Massachusetts, 120 Governors Drive, Amherst, MA, USA","institution_ids":["https://openalex.org/I24603500"]},{"raw_affiliation_string":"Department of Polymer Science and Engineering, University of Massachusetts, 120 Governors Drive,Amherst,USA","institution_ids":["https://openalex.org/I24603500"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5086363084","display_name":"Gregory N. Tew","orcid":"https://orcid.org/0000-0003-3277-7925","observed_orcids":["https://orcid.org/0000-0003-3277-7925"]},"institutions":[{"id":"https://openalex.org/I24603500","display_name":"University of Massachusetts Amherst","ror":"https://ror.org/0072zz521","country_code":"US","type":"education","lineage":["https://openalex.org/I24603500"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Gregory N. Tew","raw_affiliation_strings":["Department of Polymer Science & Engineering, University of Massachusetts, 120 Governors Drive, Amherst, MA, USA","Department of Polymer Science and Engineering, University of Massachusetts, 120 Governors Drive,Amherst,USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Polymer Science & Engineering, University of Massachusetts, 120 Governors Drive, Amherst, MA, USA","institution_ids":["https://openalex.org/I24603500"]},{"raw_affiliation_string":"Department of Polymer Science and Engineering, University of Massachusetts, 120 Governors Drive,Amherst,USA","institution_ids":["https://openalex.org/I24603500"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5086363084"],"corresponding_institution_ids":["https://openalex.org/I24603500"],"apc_list":null,"apc_paid":null,"fwci":0.7433,"has_fulltext":true,"cited_by_count":19,"citation_normalized_percentile":{"value":0.66565173,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":98},"biblio":{"volume":"2","issue":"1","first_page":"114","last_page":"119"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10343","display_name":"Hydrogels: synthesis, properties, applications","score":0.8057000041007996,"subfield":{"id":"https://openalex.org/subfields/1313","display_name":"Molecular Medicine"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}},"topics":[{"id":"https://openalex.org/T10343","display_name":"Hydrogels: synthesis, properties, applications","score":0.8057000041007996,"subfield":{"id":"https://openalex.org/subfields/1313","display_name":"Molecular Medicine"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}},{"id":"https://openalex.org/T11549","display_name":"Synthetic Organic Chemistry Methods","score":0.17149999737739563,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.004900000058114529,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/hydrogels","display_name":"hydrogels","score":0.906000018119812},{"id":"https://openalex.org/keywords/ring-opening-metathesis-polymerization","display_name":"ring-opening metathesis polymerization","score":0.9990000128746033},{"id":"https://openalex.org/keywords/gelation","display_name":"gelation","score":0.753000020980835},{"id":"https://openalex.org/keywords/monomer-concentration","display_name":"monomer concentration","score":0.8939999938011169},{"id":"https://openalex.org/keywords/flory-stockmayer-theory","display_name":"Flory-Stockmayer theory","score":0.8849999904632568},{"id":"https://openalex.org/keywords/diamine-monomers","display_name":"diamine monomers","score":0.871999979019165},{"id":"https://openalex.org/keywords/swelling-power","display_name":"swelling power","score":0.5389999747276306},{"id":"https://openalex.org/keywords/gel-yield","display_name":"gel yield","score":0.7590000033378601},{"id":"https://openalex.org/keywords/molecular-weight-distribution","display_name":"molecular weight distribution","score":0.5479999780654907}],"concepts":[{"id":"https://openalex.org/C166940927","wikidata":"https://www.wikidata.org/wiki/Q178827","display_name":"Monomer","level":3,"score":0.8670206069946289},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.7383740544319153},{"id":"https://openalex.org/C15920480","wikidata":"https://www.wikidata.org/wiki/Q421281","display_name":"Copolymer","level":3,"score":0.6246511340141296},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.591023325920105},{"id":"https://openalex.org/C108586683","wikidata":"https://www.wikidata.org/wiki/Q17164826","display_name":"Self-healing hydrogels","level":2,"score":0.5661740899085999},{"id":"https://openalex.org/C158117686","wikidata":"https://www.wikidata.org/wiki/Q909693","display_name":"Molar mass distribution","level":3,"score":0.561014711856842},{"id":"https://openalex.org/C44228677","wikidata":"https://www.wikidata.org/wiki/Q181898","display_name":"Polymerization","level":3,"score":0.5438531041145325},{"id":"https://openalex.org/C134121241","wikidata":"https://www.wikidata.org/wiki/Q899301","display_name":"Yield (engineering)","level":2,"score":0.5405555963516235},{"id":"https://openalex.org/C2778540859","wikidata":"https://www.wikidata.org/wiki/Q152234","display_name":"Swelling","level":2,"score":0.4177636504173279},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.3242272436618805},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.2264670729637146},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.1942637860774994},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.1435168981552124},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.05940857529640198},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1039/c0py00151a","doi":"https://doi.org/10.1039/c0py00151a","is_oa":false,"landing_page_url":"https://doi.org/10.1039/c0py00151a","pdf_url":null,"source":{"id":"https://openalex.org/S187215728","display_name":"Polymer Chemistry","issn_l":"1759-9954","issn":["1759-9954","1759-9962"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-1","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Polym. Chem.","raw_type":"journal-article"},{"id":"pmh:oai:works.bepress.com:gregory_tew-1037","doi":null,"is_oa":true,"landing_page_url":"https://works.bepress.com/gregory_tew/19","pdf_url":"https://works.bepress.com/gregory_tew/19/download/","source":{"id":"https://openalex.org/S4306402240","display_name":"ScholarWorks@UMassAmherst (University of Massachusetts Amherst)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I24603500","host_organization_name":"University of Massachusetts Amherst","host_organization_lineage":["https://openalex.org/I24603500"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Gregory N. Tew","raw_type":"text"}],"best_oa_location":{"id":"pmh:oai:works.bepress.com:gregory_tew-1037","doi":null,"is_oa":true,"landing_page_url":"https://works.bepress.com/gregory_tew/19","pdf_url":"https://works.bepress.com/gregory_tew/19/download/","source":{"id":"https://openalex.org/S4306402240","display_name":"ScholarWorks@UMassAmherst (University of Massachusetts Amherst)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I24603500","host_organization_name":"University of Massachusetts Amherst","host_organization_lineage":["https://openalex.org/I24603500"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Gregory N. Tew","raw_type":"text"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G6640467856","display_name":null,"funder_award_id":"0531171","funder_id":"https://openalex.org/F4320337391","funder_display_name":"Division of Civil, Mechanical and Manufacturing Innovation"},{"id":"https://openalex.org/G8876996369","display_name":null,"funder_award_id":"N00014","funder_id":"https://openalex.org/F4320337345","funder_display_name":"Office of Naval Research"}],"funders":[{"id":"https://openalex.org/F4320309090","display_name":"Center for Hierarchical Manufacturing, National Science Foundation","ror":"https://ror.org/043trmd87"},{"id":"https://openalex.org/F4320337345","display_name":"Office of Naval Research","ror":"https://ror.org/00rk2pe57"},{"id":"https://openalex.org/F4320337391","display_name":"Division of Civil, Mechanical and Manufacturing Innovation","ror":"https://ror.org/028yd4c30"}],"has_content":{"grobid_xml":true,"pdf":true},"content_urls":{"pdf":"https://content.openalex.org/works/W1857749463.pdf","grobid_xml":"https://content.openalex.org/works/W1857749463.grobid-xml"},"referenced_works_count":39,"referenced_works":["https://openalex.org/W1017590137","https://openalex.org/W1505352099","https://openalex.org/W1963806250","https://openalex.org/W1964939867","https://openalex.org/W1969983423","https://openalex.org/W1973073627","https://openalex.org/W1975519913","https://openalex.org/W1975619431","https://openalex.org/W1976299639","https://openalex.org/W1987209504","https://openalex.org/W1991959367","https://openalex.org/W2007252698","https://openalex.org/W2014674896","https://openalex.org/W2021214942","https://openalex.org/W2024040838","https://openalex.org/W2027393703","https://openalex.org/W2028175598","https://openalex.org/W2029001936","https://openalex.org/W2035124258","https://openalex.org/W2035570276","https://openalex.org/W2037797074","https://openalex.org/W2038102046","https://openalex.org/W2049602523","https://openalex.org/W2070709503","https://openalex.org/W2077723437","https://openalex.org/W2083211769","https://openalex.org/W2084610464","https://openalex.org/W2090441326","https://openalex.org/W2092750072","https://openalex.org/W2096260396","https://openalex.org/W2104018884","https://openalex.org/W2113072880","https://openalex.org/W2124256332","https://openalex.org/W2144122182","https://openalex.org/W2150761023","https://openalex.org/W2165694975","https://openalex.org/W2314659927","https://openalex.org/W2335127529","https://openalex.org/W2593478407"],"related_works":["https://openalex.org/W2092492751","https://openalex.org/W2038713236","https://openalex.org/W4384023299","https://openalex.org/W2584741963","https://openalex.org/W2139857892","https://openalex.org/W2030434816","https://openalex.org/W1963933874","https://openalex.org/W2096260396","https://openalex.org/W2024339147","https://openalex.org/W2078605379"],"abstract_inverted_index":{"Ring-opening":[0],"metathesis":[1],"polymerization":[2],"(ROMP)":[3],"was":[4,126],"used":[5],"to":[6,44,55,64,93,99,142,145],"synthesize":[7],"hydrogels":[8],"via":[9],"copolymerization":[10],"of":[11,42,58,66,105,112,122,128,136],"a":[12,17],"diamine":[13],"monomer":[14,34,48,73,115],"3":[15],"and":[16,36,60,68,87,116],"novel":[18],"cross-linker":[19,43,54,98,134],"5":[20],"using":[21],"Grubbs'":[22],"third":[23],"generation":[24],"catalyst":[25],"as":[26],"initiator.":[27,45],"Reactions":[28],"were":[29,90,140],"performed":[30],"at":[31,37,52,132],"two":[32],"different":[33],"concentrations":[35],"various":[38],"initial":[39,53],"molar":[40,101],"ratios":[41,57],"At":[46],"low":[47],"concentration,":[49],"gelation":[50],"occurred":[51],"initiator":[56,100,130],"1.5":[59],"greater,":[61],"which":[62],"decreased":[63],"values":[65],"1.05":[67],"greater":[69],"when":[70],"increasing":[71],"the":[72,81,97,106,114,117,123,129],"concentration.":[74],"This":[75],"result":[76],"is":[77],"in":[78,150],"agreement":[79],"with":[80],"Flory\u2013Stockmayer":[82],"theory.":[83],"The":[84,119],"gel":[85],"yield":[86],"swelling":[88],"properties":[89],"also":[91],"found":[92,141],"be":[94],"dependent":[95],"on":[96],"ratios.":[102],"GPC":[103],"data":[104],"sol":[107,124],"fractions":[108],"showed":[109],"quantitative":[110],"consumption":[111],"both":[113],"cross-linker.":[118],"molecular":[120],"weight":[121,149],"fraction":[125],"independent":[127],"concentration":[131,135],"constant":[133],"2.5":[137],"mol%.":[138],"Gels":[139],"swell":[143],"up":[144],"72":[146],"times":[147],"their":[148],"0.9%":[151],"NaCl":[152],"solution.":[153]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":1},{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":1},{"year":2021,"cited_by_count":1},{"year":2019,"cited_by_count":2},{"year":2015,"cited_by_count":4},{"year":2014,"cited_by_count":1},{"year":2013,"cited_by_count":4}],"updated_date":"2026-09-22T06:50:58.402377","created_date":"2016-06-24T00:00:00"}