{"id":"https://openalex.org/W167778445","doi":null,"title":"GAS PHASE STRUCTURE OF A FRIEDEL CRAFTS INTERMEDIATE:MICROWAVE SPECTRUM OF $CH_{3}F-BF_{3}$.","display_name":"GAS PHASE STRUCTURE OF A FRIEDEL CRAFTS INTERMEDIATE:MICROWAVE SPECTRUM OF $CH_{3}F-BF_{3}$.","publication_year":1996,"publication_date":"1996-01-01","ids":{"openalex":"https://openalex.org/W167778445","mag":"167778445"},"language":"en","primary_location":{"id":"pmh:oai:kb.osu.edu:1811/13638","doi":null,"is_oa":false,"landing_page_url":"http://hdl.handle.net/1811/13638","pdf_url":null,"source":{"id":"https://openalex.org/S4306402304","display_name":"The Knowledge Bank (The Ohio State University)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I52357470","host_organization_name":"The Ohio State University","host_organization_lineage":["https://openalex.org/I52357470"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":[],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5024631055","display_name":"James A. Phillips","orcid":"https://orcid.org/0000-0002-6697-7004","observed_orcids":["https://orcid.org/0000-0002-6697-7004"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"J. A. Phillips","raw_affiliation_strings":[],"raw_orcid":"https://orcid.org/0000-0002-6697-7004","affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5062166400","display_name":"Manjula R. Canagaratna","orcid":"https://orcid.org/0000-0002-8803-4007","observed_orcids":["https://orcid.org/0000-0002-8803-4007"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Manjula R. Canagaratna","raw_affiliation_strings":[],"raw_orcid":"https://orcid.org/0000-0002-8803-4007","affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5110098866","display_name":"M. E. Ott","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"M. E. Ott","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5091454001","display_name":"Kenneth R. Leopold","orcid":"https://orcid.org/0000-0003-0800-5458","observed_orcids":["https://orcid.org/0000-0003-0800-5458"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"K. R. Leopold","raw_affiliation_strings":[],"raw_orcid":"https://orcid.org/0000-0003-0800-5458","affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.01687075,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12967","display_name":"Molecular Spectroscopy and Structure","score":0.9994999766349792,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12967","display_name":"Molecular Spectroscopy and Structure","score":0.9994999766349792,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11111","display_name":"Spectroscopy and Laser Applications","score":0.00019999999494757503,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10798","display_name":"Crystallography and molecular interactions","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/rotational-spectra","display_name":"rotational spectrum","score":0.7020000219345093},{"id":"https://openalex.org/keywords/gas-phase-structure","display_name":"gas-phase molecular structure","score":0.6370000243186951},{"id":"https://openalex.org/keywords/boron-trifluoride","display_name":"boron trifluoride","score":0.7070000171661377},{"id":"https://openalex.org/keywords/fluoromethane","display_name":"methyl fluoride","score":0.7319999933242798},{"id":"https://openalex.org/keywords/intermolecular-complexes","display_name":"intermolecular complexes","score":0.593999981880188}],"concepts":[{"id":"https://openalex.org/C202224193","wikidata":"https://www.wikidata.org/wiki/Q649999","display_name":"Friedel\u2013Crafts reaction","level":3,"score":0.8009201884269714},{"id":"https://openalex.org/C44838205","wikidata":"https://www.wikidata.org/wiki/Q127995","display_name":"Microwave","level":2,"score":0.6579074859619141},{"id":"https://openalex.org/C44280652","wikidata":"https://www.wikidata.org/wiki/Q104837","display_name":"Phase (matter)","level":2,"score":0.5635051131248474},{"id":"https://openalex.org/C156778621","wikidata":"https://www.wikidata.org/wiki/Q1365748","display_name":"Spectrum (functional analysis)","level":2,"score":0.5231867432594299},{"id":"https://openalex.org/C3020013744","wikidata":"https://www.wikidata.org/wiki/Q104837","display_name":"Gas phase","level":2,"score":0.4657951593399048},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.41299593448638916},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.4014281630516052},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.2580905556678772},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.17963466048240662},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.10516467690467834},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"pmh:oai:kb.osu.edu:1811/13638","doi":null,"is_oa":false,"landing_page_url":"http://hdl.handle.net/1811/13638","pdf_url":null,"source":{"id":"https://openalex.org/S4306402304","display_name":"The Knowledge Bank (The Ohio State University)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I52357470","host_organization_name":"The Ohio State University","host_organization_lineage":["https://openalex.org/I52357470"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"article"},{"id":"mag:167778445","doi":null,"is_oa":false,"landing_page_url":"http://kb.osu.edu/dspace/handle/1811/13638","pdf_url":null,"source":null,"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":null}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2171947904","https://openalex.org/W3170983263","https://openalex.org/W403330751","https://openalex.org/W431832682","https://openalex.org/W2047525548","https://openalex.org/W2060948414","https://openalex.org/W2006843615","https://openalex.org/W2092436069","https://openalex.org/W1508915696","https://openalex.org/W1982385896"],"abstract_inverted_index":{"The":[0,33,63],"rotational":[1],"spectrum":[2,16],"of":[3,27,45,61,100,117],"$CH_{3}F-BF_{3}$":[4],"has":[5],"been":[6,31,104],"observed":[7,96],"via":[8],"pulsed-nozzle":[9],"Fourier":[10],"transform":[11],"microwave":[12],"spectroscopy.":[13],"A":[14],"dense":[15],"is":[17,68],"observed,":[18],"and":[19,90,114],"transition":[20],"arising":[21],"from":[22],"two":[23],"internal":[24],"rotor":[25],"states":[26],"the":[28,38,43,46,49,78,91,115,118],"complex":[29],"have":[30,103],"identified.":[32],"spectra":[34],"are":[35],"consistent":[36],"with":[37,57],"expected":[39,82],"geometry":[40],"in":[41,97,108],"which":[42],"flurine":[44],"$CH_{3}F$":[47],"approaches":[48],"$BF_{3}$":[50],"on":[51],"or":[52],"near":[53],"its":[54],"$C_{3}$":[55],"axis,":[56],"a":[58,72,84],"B-F-C":[59],"angle":[60],"$120^{\\\\circ}$.":[62],"intermolecular":[64],"B--F":[65],"bond":[66,88],"length":[67,89],"about":[69],"2.4":[70],"\\\\AA,":[71],"value":[73],"considerably":[74],"shorter":[75],"than":[76],"both":[77],"2.7":[79],"\\\\AA":[80,93],"distance":[81,94],"for":[83],"van":[85],"der":[86],"Waals":[87],"2.54":[92],"previously":[95],"HF-$BF_{3}$.":[98],"Complexes":[99],"this":[101,122],"type":[102],"invoked":[105],"as":[106],"intermediatea":[107],"solution":[109],"phase":[110],"Fridel-Crafts":[111],"alkylation":[112],"reactions,":[113],"relevance":[116],"current":[119],"observations":[120],"to":[121],"chemistry":[123],"will":[124],"be":[125],"discussed.":[126]},"counts_by_year":[],"updated_date":"2026-09-22T06:50:58.402377","created_date":"2016-06-24T00:00:00"}