{"id":"https://openalex.org/W1661576376","doi":"https://doi.org/10.1103/physrevb.31.2545","title":"Symmetry and orientation of CH3 O on Cu(100)","display_name":"Symmetry and orientation of CH3 O on Cu(100)","publication_year":1985,"publication_date":"1985-02-15","ids":{"openalex":"https://openalex.org/W1661576376","doi":"https://doi.org/10.1103/physrevb.31.2545","mag":"1661576376","pmid":"https://pubmed.ncbi.nlm.nih.gov/9936084"},"language":"en","primary_location":{"id":"doi:10.1103/physrevb.31.2545","doi":"https://doi.org/10.1103/physrevb.31.2545","is_oa":false,"landing_page_url":"https://doi.org/10.1103/physrevb.31.2545","pdf_url":null,"source":{"id":"https://openalex.org/S4210174675","display_name":"Physical review. B, Condensed matter","issn_l":"0163-1829","issn":["0163-1829","1095-3795"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","ki-jl-2"],"host_organization":"https://openalex.org/P4310320261","host_organization_name":"American Physical Society","host_organization_lineage":["https://openalex.org/P4310320261"],"host_organization_lineage_names":["American Physical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Physical Review B","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5111548326","display_name":"R. Ryberg","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I66862912","display_name":"Chalmers University of Technology","ror":"https://ror.org/040wg7k59","country_code":"SE","type":"education","lineage":["https://openalex.org/I66862912"]}],"countries":["SE"],"is_corresponding":true,"raw_author_name":"R. Ryberg","raw_affiliation_strings":["Department of Physics, Chalmers University of Technology, S-412 96 G\u00f6teborg, Sweden"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Physics, Chalmers University of Technology, S-412 96 G\u00f6teborg, Sweden","institution_ids":["https://openalex.org/I66862912"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5111548326"],"corresponding_institution_ids":["https://openalex.org/I66862912"],"apc_list":null,"apc_paid":null,"fwci":5.7196,"has_fulltext":false,"cited_by_count":83,"citation_normalized_percentile":{"value":0.97096863,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":88,"max":93},"biblio":{"volume":"31","issue":"4","first_page":"2545","last_page":"2547"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12285","display_name":"Surface Chemistry and Catalysis","score":0.8393999934196472,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12285","display_name":"Surface Chemistry and Catalysis","score":0.8393999934196472,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11177","display_name":"Spectroscopy and Quantum Chemical Studies","score":0.09459999948740005,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10192","display_name":"Catalytic Processes in Materials Science","score":0.032999999821186066,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/ch3o","display_name":"CH3O","score":0.7009999752044678},{"id":"https://openalex.org/keywords/methoxy-radical","display_name":"methoxy radical","score":0.5809999704360962},{"id":"https://openalex.org/keywords/cu-100","display_name":"Cu(100)","score":0.8830000162124634},{"id":"https://openalex.org/keywords/chemisorption","display_name":"chemisorption","score":0.9079999923706055},{"id":"https://openalex.org/keywords/c-h-stretching-vibrations","display_name":"C-H stretching vibrations","score":0.7039999961853027},{"id":"https://openalex.org/keywords/molecular-orientation","display_name":"molecular orientation","score":0.7139999866485596},{"id":"https://openalex.org/keywords/symmetry-breaking","display_name":"symmetry breaking","score":0.671999990940094},{"id":"https://openalex.org/keywords/methanol-adsorption","display_name":"methanol adsorption","score":0.593999981880188},{"id":"https://openalex.org/keywords/thermal-desorption","display_name":"thermal desorption","score":0.7710000276565552},{"id":"https://openalex.org/keywords/dehydrogenation","display_name":"dehydrogenation","score":0.9129999876022339},{"id":"https://openalex.org/keywords/hydrogen-adsorption","display_name":"hydrogen adsorption","score":0.6610000133514404},{"id":"https://openalex.org/keywords/bending-modes","display_name":"bending modes","score":0.6510000228881836},{"id":"https://openalex.org/keywords/infrared-spectroscopy","display_name":"infrared spectroscopy","score":0.531000018119812}],"concepts":[{"id":"https://openalex.org/C33790079","wikidata":"https://www.wikidata.org/wiki/Q899417","display_name":"Chemisorption","level":3,"score":0.6187520623207092},{"id":"https://openalex.org/C153642686","wikidata":"https://www.wikidata.org/wiki/Q70906","display_name":"Infrared spectroscopy","level":2,"score":0.6014630198478699},{"id":"https://openalex.org/C119889771","wikidata":"https://www.wikidata.org/wiki/Q898262","display_name":"Dehydrogenation","level":3,"score":0.5023338794708252},{"id":"https://openalex.org/C4839761","wikidata":"https://www.wikidata.org/wiki/Q212111","display_name":"Spectral line","level":2,"score":0.47839534282684326},{"id":"https://openalex.org/C16345878","wikidata":"https://www.wikidata.org/wiki/Q107472979","display_name":"Orientation (vector space)","level":2,"score":0.4676705598831177},{"id":"https://openalex.org/C2779463800","wikidata":"https://www.wikidata.org/wiki/Q5062222","display_name":"Center (category theory)","level":2,"score":0.46346062421798706},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.4605954885482788},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.4600415825843811},{"id":"https://openalex.org/C2781059571","wikidata":"https://www.wikidata.org/wiki/Q3706001","display_name":"Thermal desorption","level":4,"score":0.4412175416946411},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.406801700592041},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.39247599244117737},{"id":"https://openalex.org/C150394285","wikidata":"https://www.wikidata.org/wiki/Q180254","display_name":"Adsorption","level":2,"score":0.38153141736984253},{"id":"https://openalex.org/C113196181","wikidata":"https://www.wikidata.org/wiki/Q485223","display_name":"Analytical Chemistry (journal)","level":2,"score":0.34349894523620605},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.31197071075439453},{"id":"https://openalex.org/C162711632","wikidata":"https://www.wikidata.org/wiki/Q905514","display_name":"Desorption","level":3,"score":0.2964966893196106},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.19604191184043884},{"id":"https://openalex.org/C2524010","wikidata":"https://www.wikidata.org/wiki/Q8087","display_name":"Geometry","level":1,"score":0.08882012963294983},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.07893159985542297},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.07173380255699158},{"id":"https://openalex.org/C33923547","wikidata":"https://www.wikidata.org/wiki/Q395","display_name":"Mathematics","level":0,"score":0.0},{"id":"https://openalex.org/C43617362","wikidata":"https://www.wikidata.org/wiki/Q170050","display_name":"Chromatography","level":1,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1103/physrevb.31.2545","doi":"https://doi.org/10.1103/physrevb.31.2545","is_oa":false,"landing_page_url":"https://doi.org/10.1103/physrevb.31.2545","pdf_url":null,"source":{"id":"https://openalex.org/S4210174675","display_name":"Physical review. B, Condensed matter","issn_l":"0163-1829","issn":["0163-1829","1095-3795"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","ki-jl-2"],"host_organization":"https://openalex.org/P4310320261","host_organization_name":"American Physical Society","host_organization_lineage":["https://openalex.org/P4310320261"],"host_organization_lineage_names":["American Physical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Physical Review B","raw_type":"journal-article"},{"id":"pmid:9936084","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/9936084","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Physical review. B, Condensed matter","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":11,"referenced_works":["https://openalex.org/W1965426310","https://openalex.org/W1969932372","https://openalex.org/W1988023846","https://openalex.org/W1995749654","https://openalex.org/W2011867810","https://openalex.org/W2035142413","https://openalex.org/W2038533771","https://openalex.org/W2057361235","https://openalex.org/W2059355416","https://openalex.org/W2072717968","https://openalex.org/W3023321095"],"related_works":["https://openalex.org/W1965426310","https://openalex.org/W2010852996","https://openalex.org/W2566893815","https://openalex.org/W4255863084","https://openalex.org/W2005198686","https://openalex.org/W2008274395","https://openalex.org/W2603499150","https://openalex.org/W2614657209","https://openalex.org/W1988288036","https://openalex.org/W2083579701"],"abstract_inverted_index":{"The":[0],"C-H":[1],"stretch":[2],"vibrational":[3],"modes":[4],"of":[5,27,38,70,78],"${\\mathrm{CH}}_{3}$O":[6,44,71],"chemisorbed":[7],"on":[8,60,82],"a":[9,79,87],"Cu(100)":[10],"surface":[11,85],"have":[12],"been":[13],"studied":[14],"using":[15],"infrared":[16,36],"spectroscopy.":[17],"Three":[18],"absorption":[19],"peaks":[20],"were":[21],"found":[22],"indicating":[23],"that":[24,42,54,67],"the":[25,28,35,43,51,55,61,68,76,83],"symmetry":[26],"${\\mathrm{CH}}_{3}$":[29],"group":[30,45],"is":[31,46],"broken.":[32],"Comparison":[33],"with":[34],"spectra":[37,65],"free":[39],"methanol":[40],"shows":[41],"rather":[47],"little":[48],"perturbed":[49],"by":[50],"chemisorption":[52],"and":[53],"molecules":[56],"definitely":[57],"are":[58],"tilted":[59],"surface.":[62],"Thermal":[63],"desorption":[64],"indicate":[66],"dehydrogenation":[69],"to":[72],"${\\mathrm{H}}_{2}$CO":[73],"goes":[74],"via":[75],"adsorption":[77],"hydrogen":[80],"atom":[81],"copper":[84],"during":[86],"low":[88],"frequency":[89],"bending":[90],"mode.":[91]},"counts_by_year":[{"year":2022,"cited_by_count":1},{"year":2015,"cited_by_count":1},{"year":2013,"cited_by_count":1}],"updated_date":"2026-11-09T13:22:03.289127","created_date":"2016-06-24T00:00:00"}