{"id":"https://openalex.org/W1600888481","doi":null,"title":"I. TOTAL SYNTHESIS OF (\u00b1) OVALICIN AND ITS ANALOGUES II. BIO-BASED POLYMERS FROM VEGETABLE OIL III. NEW SYNTHETIC METHODS OF DIACETYLENE FATTY ACIDS","display_name":"I. TOTAL SYNTHESIS OF (\u00b1) OVALICIN AND ITS ANALOGUES II. BIO-BASED POLYMERS FROM VEGETABLE OIL III. NEW SYNTHETIC METHODS OF DIACETYLENE FATTY ACIDS","publication_year":2008,"publication_date":"2008-01-01","ids":{"openalex":"https://openalex.org/W1600888481","mag":"1600888481"},"language":"en","primary_location":{"id":"pmh:oai:krex.k-state.edu:2097/735","doi":null,"is_oa":true,"landing_page_url":"http://hdl.handle.net/2097/735","pdf_url":"https://krex.k-state.edu/bitstreams/acd92325-dca4-4298-8976-7055aae98533/download","source":{"id":"https://openalex.org/S4306402339","display_name":"K-State Research Exchange (Kansas State University)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I189590672","host_organization_name":"Kansas State University","host_organization_lineage":["https://openalex.org/I189590672"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"Dissertation"},"volume":null,"type":"dissertation","is_traditional":true,"indexed_in":[],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://krex.k-state.edu/bitstreams/acd92325-dca4-4298-8976-7055aae98533/download","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5102370050","display_name":"Huiping Zhao","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":true,"raw_author_name":"Huiping Zhao","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":["https://openalex.org/A5102370050"],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":null,"has_fulltext":true,"cited_by_count":0,"citation_normalized_percentile":null,"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10661","display_name":"biodegradable polymer synthesis and properties","score":0.10750000178813934,"subfield":{"id":"https://openalex.org/subfields/2502","display_name":"Biomaterials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10661","display_name":"biodegradable polymer synthesis and properties","score":0.10750000178813934,"subfield":{"id":"https://openalex.org/subfields/2502","display_name":"Biomaterials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10013","display_name":"Asymmetric Synthesis and Catalysis","score":0.1006999984383583,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13859","display_name":"Organic Chemistry Synthesis Methods","score":0.08950000256299973,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/total-synthesis","display_name":"total synthesis","score":0.949999988079071},{"id":"https://openalex.org/keywords/angiogenesis","display_name":"angiogenesis","score":0.6119999885559082},{"id":"https://openalex.org/keywords/intramolecular-heck-reaction","display_name":"intramolecular Heck reaction","score":0.8769999742507935},{"id":"https://openalex.org/keywords/stereoisomers","display_name":"stereoisomers","score":0.7110000252723694},{"id":"https://openalex.org/keywords/regioisomers","display_name":"regioisomers","score":0.781000018119812},{"id":"https://openalex.org/keywords/antitrypanosomal-activity","display_name":"antitrypanosomal activity","score":0.9020000100135803},{"id":"https://openalex.org/keywords/bio-based-polymers","display_name":"bio-based polymers","score":0.9160000085830688},{"id":"https://openalex.org/keywords/triolein","display_name":"triolein","score":0.8849999904632568},{"id":"https://openalex.org/keywords/polyurethane","display_name":"polyurethane","score":0.8130000233650208},{"id":"https://openalex.org/keywords/polyurea","display_name":"polyurea","score":0.9950000047683716},{"id":"https://openalex.org/keywords/1-4-phenylene-diisocyanate","display_name":"1,4-phenylene diisocyanate","score":0.9390000104904175},{"id":"https://openalex.org/keywords/structure-property-relationships","display_name":"structure-property relationships","score":0.625}],"concepts":[{"id":"https://openalex.org/C2777671527","wikidata":"https://www.wikidata.org/wiki/Q422802","display_name":"Diacetylene","level":4,"score":0.9624073505401611},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.5638604164123535},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.49208730459213257},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.44802555441856384},{"id":"https://openalex.org/C44228677","wikidata":"https://www.wikidata.org/wiki/Q181898","display_name":"Polymerization","level":3,"score":0.0992901623249054}],"mesh":[],"locations_count":2,"locations":[{"id":"pmh:oai:krex.k-state.edu:2097/735","doi":null,"is_oa":true,"landing_page_url":"http://hdl.handle.net/2097/735","pdf_url":"https://krex.k-state.edu/bitstreams/acd92325-dca4-4298-8976-7055aae98533/download","source":{"id":"https://openalex.org/S4306402339","display_name":"K-State Research Exchange (Kansas State University)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I189590672","host_organization_name":"Kansas State University","host_organization_lineage":["https://openalex.org/I189590672"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"Dissertation"},{"id":"mag:1600888481","doi":null,"is_oa":false,"landing_page_url":"http://krex.k-state.edu/dspace/bitstream/2097/735/1/HuipingZhao2008.pdf","pdf_url":null,"source":null,"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":null}],"best_oa_location":{"id":"pmh:oai:krex.k-state.edu:2097/735","doi":null,"is_oa":true,"landing_page_url":"http://hdl.handle.net/2097/735","pdf_url":"https://krex.k-state.edu/bitstreams/acd92325-dca4-4298-8976-7055aae98533/download","source":{"id":"https://openalex.org/S4306402339","display_name":"K-State Research Exchange (Kansas State University)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I189590672","host_organization_name":"Kansas State University","host_organization_lineage":["https://openalex.org/I189590672"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"Dissertation"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W1600888481.pdf","grobid_xml":"https://content.openalex.org/works/W1600888481.grobid-xml"},"referenced_works_count":81,"referenced_works":["https://openalex.org/W24279265","https://openalex.org/W72344367","https://openalex.org/W76631668","https://openalex.org/W105645453","https://openalex.org/W187153995","https://openalex.org/W643058936","https://openalex.org/W644776937","https://openalex.org/W1509909912","https://openalex.org/W1533699899","https://openalex.org/W1551154794","https://openalex.org/W1554067582","https://openalex.org/W1903082787","https://openalex.org/W1928034099","https://openalex.org/W1965582073","https://openalex.org/W1971049156","https://openalex.org/W1977791807","https://openalex.org/W1977853776","https://openalex.org/W1978732735","https://openalex.org/W1979499894","https://openalex.org/W1988288959","https://openalex.org/W1989024382","https://openalex.org/W1990920308","https://openalex.org/W1991586721","https://openalex.org/W1992581104","https://openalex.org/W1995212364","https://openalex.org/W1995783530","https://openalex.org/W1999239339","https://openalex.org/W2000000541","https://openalex.org/W2003705592","https://openalex.org/W2008750028","https://openalex.org/W2010178088","https://openalex.org/W2017157049","https://openalex.org/W2020698822","https://openalex.org/W2021347570","https://openalex.org/W2025104828","https://openalex.org/W2037288322","https://openalex.org/W2037355045","https://openalex.org/W2037861947","https://openalex.org/W2040077860","https://openalex.org/W2040766532","https://openalex.org/W2041019320","https://openalex.org/W2042603481","https://openalex.org/W2048402595","https://openalex.org/W2050284673","https://openalex.org/W2054201715","https://openalex.org/W2062866748","https://openalex.org/W2066291084","https://openalex.org/W2068736055","https://openalex.org/W2068876395","https://openalex.org/W2072300064","https://openalex.org/W2073457503","https://openalex.org/W2076521875","https://openalex.org/W2078279569","https://openalex.org/W2079009584","https://openalex.org/W2079196155","https://openalex.org/W2080373566","https://openalex.org/W2085785716","https://openalex.org/W2090930046","https://openalex.org/W2091553752","https://openalex.org/W2091602821","https://openalex.org/W2095784245","https://openalex.org/W2098387318","https://openalex.org/W2101948634","https://openalex.org/W2103438589","https://openalex.org/W2114122802","https://openalex.org/W2122026637","https://openalex.org/W2122305262","https://openalex.org/W2129100183","https://openalex.org/W2144512621","https://openalex.org/W2148060709","https://openalex.org/W2153482349","https://openalex.org/W2157982789","https://openalex.org/W2165621179","https://openalex.org/W2290609763","https://openalex.org/W2480986790","https://openalex.org/W2520185713","https://openalex.org/W2951087381","https://openalex.org/W2951793369","https://openalex.org/W2952471731","https://openalex.org/W2952730952","https://openalex.org/W3100666666"],"related_works":["https://openalex.org/W7001436787","https://openalex.org/W2995188517","https://openalex.org/W3026598304","https://openalex.org/W6964747541","https://openalex.org/W7071893383","https://openalex.org/W1602978756","https://openalex.org/W7145943932","https://openalex.org/W3140526942","https://openalex.org/W6903178523","https://openalex.org/W2278830707"],"abstract_inverted_index":{"I.":[0,225],"Ovalicin":[1],"is":[2],"a":[3,55,75],"natural":[4],"product":[5],"isolated":[6],"from":[7,117,136,173,211],"the":[8],"culture":[9],"of":[10,34,51,58,77,83,88,107,155,207],"fungus":[11],"Pseudorotium":[12],"ovalis":[13],"Stolk,":[14],"it":[15],"selectively":[16],"inhibit":[17],"type":[18],"2":[19],"methionine":[20],"amino-peptidase":[21],"(MetAP":[22],"2),":[23],"which":[24],"related":[25],"to":[26,74,90,101,148,195],"many":[27],"physiological":[28],"activities":[29,106],"such":[30],"as":[31],"angiogenesis.Total":[32],"synthesis":[33,82],"(\u00b1)":[35,229],"ovalicin,":[36],"its":[37,86,104],"C4(S*),":[38],"C4(S*)C5(S*)":[39],"stereo-isomers,":[40],"and":[41,71,85,95,103,111,122,127,131,151,163,168,176,200,223],"C5":[42],"regio-isomer":[43],"were":[44,114,134,142,158,171,189,221],"synthesized":[45,135],"via":[46],"an":[47],"intramolecular":[48],"Heck":[49],"reaction":[50],"(Z)-3-(t-butyldimethyl":[52],"silyloxy)-1-iodo-1,6-heptadiene":[53],"utilizing":[54],"catalytic":[56],"amount":[57],"palladium":[59],"acetate.Subsequent":[60],"epoxidation,":[61],"dihydroxylation,":[62],"methylation":[63],"(or":[64],"stereochemistry":[65],"inversion":[66],"before":[67],"or":[68],"after":[69],"methylation)":[70],"oxidation":[72],"led":[73,100],"variety":[76],"ketones,":[78],"key":[79],"intermediates":[80,113],"for":[81],"ovalicin":[84,102,109],"analogues.Introduction":[87],"side-chain":[89],"ketones":[91],"by":[92,160],"lithium":[93],"(Z)-6-methylhepta-2,5-dien-2-ide":[94],"following":[96],"functional":[97],"group":[98],"transformation":[99],"analogues.Anti-trypanosomal":[105],"various":[108],"analogues":[110],"synthetic":[112,205],"evaluated.II.Bio-based":[115],"polymers":[116,157],"vegetable":[118,212],"oils":[119,213],"are":[120],"renewable":[121],"environment-friendly":[123],"materials.Dihydroxylated,":[124],"trihydroxylate,":[125],"tetrahydroxylated":[126],"hexahydroxylated":[128],"triglycerides,":[129],"triamino":[130],"triisopropylamino":[132],"glycerides":[133],"model":[137],"triglyceride":[138],"glyceryl":[139],"trioleoate.These":[140],"monomers":[141],"cross-linked":[143],"with":[144],"1,":[145],"4-phenylene":[146],"diisocynate":[147],"make":[149],"polyurethanes":[150],"polyureas.The":[152],"physical":[153],"properties":[154,170,217],"these":[156,185],"examined":[159],"gel":[161],"content":[162],"swelling":[164],"value":[165],"measurements,":[166],"thermodynamic":[167],"viscoelastic":[169],"studied":[172],"TGA,":[174],"DSC":[175],"DMA":[177],"measurements.The":[178],"structure-property":[179],"relationship":[180],"was":[181,214],"discussed":[182],"based":[183],"on":[184,198,218],"measurements.III.Diacetylenic":[186],"fatty":[187,209],"acids":[188,210],"widely":[190],"applied":[191],"in":[192],"material":[193],"science":[194],"regulate":[196],"alignment":[197],"surface":[199,220],"stabilize":[201],"self-assembled":[202],"nanomaterials.A":[203],"novel":[204],"method":[206],"diacetylenic":[208],"developed.Its":[215],"self-assembling":[216],"alumina":[219],"measured":[222],"discussed.":[224],"TOTAL":[226],"SYNTHESIS":[227],"OF":[228],"OVALICIN":[230],"AND":[231],"ITS":[232],"ANALOGUES":[233]},"counts_by_year":[],"updated_date":"2026-11-08T12:12:28.789561","created_date":"2016-06-24T00:00:00"}