{"id":"https://openalex.org/W1563201493","doi":"https://doi.org/10.1103/physrevb.26.4871","title":"Spin-state equilibria in the LCoO3 system from Co59 NMR","display_name":"Spin-state equilibria in the LCoO3 system from Co59 NMR","publication_year":1982,"publication_date":"1982-11-01","ids":{"openalex":"https://openalex.org/W1563201493","doi":"https://doi.org/10.1103/physrevb.26.4871","mag":"1563201493"},"language":"lv","primary_location":{"id":"doi:10.1103/physrevb.26.4871","doi":"https://doi.org/10.1103/physrevb.26.4871","is_oa":false,"landing_page_url":"https://doi.org/10.1103/physrevb.26.4871","pdf_url":null,"source":{"id":"https://openalex.org/S4210174675","display_name":"Physical review. B, Condensed matter","issn_l":"0163-1829","issn":["0163-1829","1095-3795"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","ki-jl-2"],"host_organization":"https://openalex.org/P4310320261","host_organization_name":"American Physical Society","host_organization_lineage":["https://openalex.org/P4310320261"],"host_organization_lineage_names":["American Physical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Physical Review B","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5021177990","display_name":"Monisha Bose","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I16019930","display_name":"Saha Institute of Nuclear Physics","ror":"https://ror.org/0491yz035","country_code":"IN","type":"facility","lineage":["https://openalex.org/I16019930"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"Monisha Bose","raw_affiliation_strings":["Saha Institute of Nuclear Physics, Calcutta-700 009, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Saha Institute of Nuclear Physics, Calcutta-700 009, India","institution_ids":["https://openalex.org/I16019930"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5057327256","display_name":"Amitabha Ghoshray","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I16019930","display_name":"Saha Institute of Nuclear Physics","ror":"https://ror.org/0491yz035","country_code":"IN","type":"facility","lineage":["https://openalex.org/I16019930"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"Amitabha Ghoshray","raw_affiliation_strings":["Saha Institute of Nuclear Physics, Calcutta-700 009, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Saha Institute of Nuclear Physics, Calcutta-700 009, India","institution_ids":["https://openalex.org/I16019930"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5077893490","display_name":"Anjali Basu","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I16019930","display_name":"Saha Institute of Nuclear Physics","ror":"https://ror.org/0491yz035","country_code":"IN","type":"facility","lineage":["https://openalex.org/I16019930"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"Anjali Basu","raw_affiliation_strings":["Saha Institute of Nuclear Physics, Calcutta-700 009, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Saha Institute of Nuclear Physics, Calcutta-700 009, India","institution_ids":["https://openalex.org/I16019930"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5085489146","display_name":"C. N. R. Rao","orcid":"https://orcid.org/0000-0003-4088-0615","observed_orcids":["https://orcid.org/0000-0003-4088-0615"]},"institutions":[{"id":"https://openalex.org/I16019930","display_name":"Saha Institute of Nuclear Physics","ror":"https://ror.org/0491yz035","country_code":"IN","type":"facility","lineage":["https://openalex.org/I16019930"]},{"id":"https://openalex.org/I59270414","display_name":"Indian Institute of Science Bangalore","ror":"https://ror.org/04dese585","country_code":"IN","type":"education","lineage":["https://openalex.org/I59270414"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"C. N. R. Rao","raw_affiliation_strings":["Saha Institute of Nuclear Physics, Calcutta-700 009, India","Solid State & Structural Chemistry Unit, Indian Institute of Science, Bangalore\u2010560 012, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Saha Institute of Nuclear Physics, Calcutta-700 009, India","institution_ids":["https://openalex.org/I16019930"]},{"raw_affiliation_string":"Solid State & Structural Chemistry Unit, Indian Institute of Science, Bangalore\u2010560 012, India","institution_ids":["https://openalex.org/I59270414"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":0.6681,"has_fulltext":false,"cited_by_count":17,"citation_normalized_percentile":{"value":0.58605608,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":94},"biblio":{"volume":"26","issue":"9","first_page":"4871","last_page":"4882"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10607","display_name":"Magnetic and transport properties of perovskites and related materials","score":0.8687000274658203,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10607","display_name":"Magnetic and transport properties of perovskites and related materials","score":0.8687000274658203,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10037","display_name":"Physics of Superconductivity and Magnetism","score":0.056699998676776886,"subfield":{"id":"https://openalex.org/subfields/3104","display_name":"Condensed Matter Physics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11682","display_name":"Advanced Condensed Matter Physics","score":0.021299999207258224,"subfield":{"id":"https://openalex.org/subfields/3104","display_name":"Condensed Matter Physics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/rare-earth-cobaltites","display_name":"rare earth cobaltites","score":0.8989999890327454},{"id":"https://openalex.org/keywords/59co-nmr","display_name":"59Co NMR","score":0.9520000219345093},{"id":"https://openalex.org/keywords/quadrupole-interaction","display_name":"quadrupole interaction","score":0.9020000100135803},{"id":"https://openalex.org/keywords/transferred-hyperfine-interaction","display_name":"transferred hyperfine interaction","score":0.8080000281333923},{"id":"https://openalex.org/keywords/nmr-line-shape","display_name":"NMR line shape","score":0.6589999794960022},{"id":"https://openalex.org/keywords/second-order-phase-transition","display_name":"second-order phase transition","score":0.6150000095367432},{"id":"https://openalex.org/keywords/prcoo3","display_name":"PrCoO3","score":0.746999979019165},{"id":"https://openalex.org/keywords/ndcoo3","display_name":"NdCoO3","score":0.996999979019165},{"id":"https://openalex.org/keywords/lacoo3","display_name":"LaCoO3","score":0.6769999861717224},{"id":"https://openalex.org/keywords/smcoo3","display_name":"SmCoO3","score":0.7200000286102295}],"concepts":[{"id":"https://openalex.org/C37243968","wikidata":"https://www.wikidata.org/wiki/Q648961","display_name":"Orthorhombic crystal system","level":3,"score":0.6816225051879883},{"id":"https://openalex.org/C182306322","wikidata":"https://www.wikidata.org/wiki/Q1779371","display_name":"Order (exchange)","level":2,"score":0.5601107478141785},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.5571507811546326},{"id":"https://openalex.org/C170751736","wikidata":"https://www.wikidata.org/wiki/Q503601","display_name":"Tetragonal crystal system","level":3,"score":0.5401626229286194},{"id":"https://openalex.org/C124712363","wikidata":"https://www.wikidata.org/wiki/Q188479","display_name":"Paramagnetism","level":2,"score":0.5107381343841553},{"id":"https://openalex.org/C131538251","wikidata":"https://www.wikidata.org/wiki/Q1413102","display_name":"Hyperfine structure","level":2,"score":0.47584936022758484},{"id":"https://openalex.org/C42704618","wikidata":"https://www.wikidata.org/wiki/Q910917","display_name":"Spin (aerodynamics)","level":2,"score":0.4741515517234802},{"id":"https://openalex.org/C26873012","wikidata":"https://www.wikidata.org/wiki/Q214781","display_name":"Condensed matter physics","level":1,"score":0.455625057220459},{"id":"https://openalex.org/C39353612","wikidata":"https://www.wikidata.org/wiki/Q5283759","display_name":"Atmospheric temperature range","level":2,"score":0.43165671825408936},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.40765321254730225},{"id":"https://openalex.org/C44280652","wikidata":"https://www.wikidata.org/wiki/Q104837","display_name":"Phase (matter)","level":2,"score":0.37857553362846375},{"id":"https://openalex.org/C46141821","wikidata":"https://www.wikidata.org/wiki/Q209402","display_name":"Nuclear magnetic resonance","level":1,"score":0.3465883731842041},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.3316974639892578},{"id":"https://openalex.org/C184779094","wikidata":"https://www.wikidata.org/wiki/Q26383","display_name":"Atomic physics","level":1,"score":0.30026108026504517},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.20374590158462524},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.1988281011581421},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.12032163143157959},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.11538171768188477},{"id":"https://openalex.org/C162324750","wikidata":"https://www.wikidata.org/wiki/Q8134","display_name":"Economics","level":0,"score":0.0},{"id":"https://openalex.org/C10138342","wikidata":"https://www.wikidata.org/wiki/Q43015","display_name":"Finance","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1103/physrevb.26.4871","doi":"https://doi.org/10.1103/physrevb.26.4871","is_oa":false,"landing_page_url":"https://doi.org/10.1103/physrevb.26.4871","pdf_url":null,"source":{"id":"https://openalex.org/S4210174675","display_name":"Physical review. B, Condensed matter","issn_l":"0163-1829","issn":["0163-1829","1095-3795"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","ki-jl-2"],"host_organization":"https://openalex.org/P4310320261","host_organization_name":"American Physical Society","host_organization_lineage":["https://openalex.org/P4310320261"],"host_organization_lineage_names":["American Physical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Physical Review B","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":26,"referenced_works":["https://openalex.org/W1549497104","https://openalex.org/W1964457856","https://openalex.org/W1969490016","https://openalex.org/W1971386541","https://openalex.org/W1973931496","https://openalex.org/W1980857664","https://openalex.org/W1981474584","https://openalex.org/W2002234006","https://openalex.org/W2014182598","https://openalex.org/W2023555315","https://openalex.org/W2033599281","https://openalex.org/W2038110622","https://openalex.org/W2039480232","https://openalex.org/W2053469826","https://openalex.org/W2057686340","https://openalex.org/W2059524386","https://openalex.org/W2066897385","https://openalex.org/W2068991420","https://openalex.org/W2071075501","https://openalex.org/W2072625910","https://openalex.org/W2075861127","https://openalex.org/W2083415714","https://openalex.org/W2084361772","https://openalex.org/W2085988574","https://openalex.org/W2139107868","https://openalex.org/W4243524177"],"related_works":["https://openalex.org/W7005788548","https://openalex.org/W2085988574","https://openalex.org/W2074433836","https://openalex.org/W2059524386","https://openalex.org/W2022343040","https://openalex.org/W2053458954","https://openalex.org/W2015212485","https://openalex.org/W2316442677","https://openalex.org/W2090479728","https://openalex.org/W2048286909"],"abstract_inverted_index":{"Spin-state":[0],"equilibria":[1,266],"in":[2,35,55,229,245,254,267,282],"the":[3,21,30,36,49,52,70,86,90,98,111,117,125,153,156,159,200,230,261,264,283,291,295,298,328,340,360],"whole":[4],"set":[5],"of":[6,23,51,62,89,97,106,116,124,155,222,263,290,317],"$L\\mathrm{Co}{\\mathrm{O}}_{3}$":[7,268,330],"(where":[8],"$L$":[9],"stands":[10],"for":[11,29,69,359],"a":[12,27,59,140,147,170,175,186,191,219,287,323,332,350],"rare-earth":[13,118,127,157,232],"metal":[14],"or":[15],"Y)":[16,207],"have":[17],"been":[18,67,227,243],"investigated":[19],"with":[20,139,190,224,251,355],"use":[22],"$^{59}\\mathrm{Co}$":[24,74],"NMR":[25,77],"as":[26],"probe":[28],"polycrystalline":[31],"samples":[32],"(except":[33],"Ce)":[34],"temperature":[37,57,149,163,253],"interval":[38],"110-550":[39],"K":[40],"and":[41,92,113,132,165,181,206,236,256,273,306,342],"frequency":[42],"range":[43],"3-":[44],"11.6":[45],"MHz.":[46],"Besides":[47],"confirming":[48],"coexistence":[50],"high-spin---low-spin":[53,276],"state":[54],"this":[56,302],"range,":[58],"quadrupolar":[60,93,137,160,188,210,336,353],"interaction":[61,109,138,161,172,189,211,354],"\\ensuremath{\\sim}0.1":[63],"-0.5":[64],"MHz":[65],"has":[66,226,242],"detected":[68],"first":[71,121],"time":[72],"from":[73,294],"NMR.":[75],"The":[76,120],"line":[78],"shape":[79],"is":[80],"found":[81],"to":[82,169,349],"depend":[83],"strongly":[84],"on":[85,152],"relative":[87],"magnitude":[88],"magnetic":[91],"interactions":[94],"present.":[95],"Analysis":[96],"powder":[99],"pattern":[100],"reveals":[101],"two":[102],"basically":[103],"different":[104],"types":[105],"transferred":[107],"hyperfine":[108],"between":[110],"lighter":[112,126,361],"heavier":[114,231,329],"members":[115,123,203],"series.":[119],"three":[122],"metals":[128],"La,":[129],"Pr":[130],"(rhombohedral),":[131],"Nd":[133],"(tetragonal),":[134],"exhibit":[135,184,208],"second-order":[136,177,187,352],"zero-asymmetry":[141],"parameter":[142,194],"at":[143,196,212,310],"lower":[144],"temperatures.":[145,214],"Above":[146],"critical":[148],"${T}_{S}$":[150],"(dependent":[151],"size":[154],"ion),":[158],"becomes":[162],"dependent":[164],"eventually":[166],"gives":[167],"rise":[168,348],"first-order":[171,209,335],"thus":[173],"indicating":[174],"possible":[176],"phase":[178],"change.":[179],"Sm":[180],"Eu":[182],"(orthorhombic)":[183],"also":[185],"nonzero":[192],"asymmetry":[193],"(($\\ensuremath{\\eta}\\ensuremath{\\sim}0.47$))":[195],"300":[197],"K,":[198],"while":[199],"orthorhombic":[201],"second-half":[202],"(Dy,...,":[204],"Lu":[205,235],"all":[213,318],"Normal":[215],"paramagnetic":[216],"behavior,":[217],"i.e.,":[218],"linear":[220],"variation":[221,241],"${K}_{\\mathrm{iso}}$":[223,249,358],"${T}^{\\ensuremath{-}1}$,":[225],"observed":[228,244],"cobaltites":[233],"(Er,...,":[234],"Y),":[237],"whereas":[238],"an":[239,356],"anomalous":[240,357],"(La,...,":[246],"Nd)Co${\\mathrm{O}}_{3}$.":[247],"Thus,":[248],"increases":[250],"increasing":[252],"PrCo${\\mathrm{O}}_{3}$":[255],"NdCo${\\mathrm{O}}_{3}$.":[257],"These":[258],"observations":[259],"corroborate":[260],"model":[262],"spin-state":[265],"originally":[269],"proposed":[270],"by":[271,286],"Raccah":[272],"Goodenough.":[274],"A":[275],"ratio,":[277],"$r=1$,":[278,311],"can":[279,313],"be":[280],"stabilized":[281],"perovskite":[284],"structure":[285],"cooperative":[288],"displacement":[289,316],"oxygen":[292,320],"atoms":[293,321],"high-spin":[296],"towards":[297,322],"low-spin":[299,307,324,343],"cation.":[300],"Where":[301,338],"ordering":[303],"into":[304],"high-":[305,341],"sublattices":[308],"occurs":[309],"one":[312],"anticipate":[314],"equivalent":[315],"near-neighbor":[319],"cobalt":[325],"ion.":[326],"Thus":[327],"exhibits":[331],"small":[333],"temperature-independent":[334],"interaction.":[337],"$r<1$,":[339],"states":[344],"are":[345],"disordered,":[346],"giving":[347],"temperature-dependent":[351],"$L\\mathrm{Co}{\\mathrm{O}}_{3}$.":[362]},"counts_by_year":[{"year":2020,"cited_by_count":1},{"year":2018,"cited_by_count":1},{"year":2013,"cited_by_count":1}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2016-06-24T00:00:00"}