{"id":"https://openalex.org/W1561967945","doi":"https://doi.org/10.1107/s1600536807017898","title":"1-(2-Bromo-1-methyl-1H-indol-3-ylcarbonyl)pyrrolidine","display_name":"1-(2-Bromo-1-methyl-1H-indol-3-ylcarbonyl)pyrrolidine","publication_year":2007,"publication_date":"2007-04-18","ids":{"openalex":"https://openalex.org/W1561967945","doi":"https://doi.org/10.1107/s1600536807017898","mag":"1561967945"},"language":"en","primary_location":{"id":"doi:10.1107/s1600536807017898","doi":"https://doi.org/10.1107/s1600536807017898","is_oa":false,"landing_page_url":"https://doi.org/10.1107/s1600536807017898","pdf_url":null,"source":{"id":"https://openalex.org/S146636433","display_name":"Acta Crystallographica Section E Structure Reports Online","issn_l":"1600-5368","issn":["1600-5368"],"is_oa":false,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj"],"host_organization":"https://openalex.org/P4310320555","host_organization_name":"International Union of Crystallography","host_organization_lineage":["https://openalex.org/P4310320555"],"host_organization_lineage_names":["International Union of Crystallography"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Acta Crystallographica Section E Structure Reports Online","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","doaj"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5023893398","display_name":"Jeanese C. Badenock","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I107672454","display_name":"Dartmouth College","ror":"https://ror.org/049s0rh22","country_code":"US","type":"education","lineage":["https://openalex.org/I107672454"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Jeanese C. Badenock","raw_affiliation_strings":["Department of Chemistry, Dartmouth College, Hanover, NH 03755-3564, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Dartmouth College, Hanover, NH 03755-3564, USA","institution_ids":["https://openalex.org/I107672454"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5090224288","display_name":"Heidi L. Fraser","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I107672454","display_name":"Dartmouth College","ror":"https://ror.org/049s0rh22","country_code":"US","type":"education","lineage":["https://openalex.org/I107672454"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Heidi L. Fraser","raw_affiliation_strings":["Department of Chemistry, Dartmouth College, Hanover, NH 03755-3564, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Dartmouth College, Hanover, NH 03755-3564, USA","institution_ids":["https://openalex.org/I107672454"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5049245360","display_name":"Gordon W. Gribble","orcid":"https://orcid.org/0000-0002-7573-0927","observed_orcids":["https://orcid.org/0000-0002-7573-0927"]},"institutions":[{"id":"https://openalex.org/I107672454","display_name":"Dartmouth College","ror":"https://ror.org/049s0rh22","country_code":"US","type":"education","lineage":["https://openalex.org/I107672454"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Gordon W. Gribble","raw_affiliation_strings":["Department of Chemistry, Dartmouth College, Hanover, NH 03755-3564, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Dartmouth College, Hanover, NH 03755-3564, USA","institution_ids":["https://openalex.org/I107672454"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5039577417","display_name":"Jerry P. Jasinski","orcid":"https://orcid.org/0000-0003-2302-1886","observed_orcids":["https://orcid.org/0000-0003-2302-1886"]},"institutions":[{"id":"https://openalex.org/I150638750","display_name":"Keene State College","ror":"https://ror.org/04c1gbz02","country_code":"US","type":"education","lineage":["https://openalex.org/I150638750"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Jerry P. Jasinski","raw_affiliation_strings":["Department of Chemistry, Keene State College, Keene NH 03435\u20132001 USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Keene State College, Keene NH 03435\u20132001 USA","institution_ids":["https://openalex.org/I150638750"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":500,"currency":"USD","value_usd":500},"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.05740132,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":"63","issue":"5","first_page":"o2474","last_page":"o2475"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10464","display_name":"Crystal structures of chemical compounds","score":0.9990000128746033,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10464","display_name":"Crystal structures of chemical compounds","score":0.9990000128746033,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10798","display_name":"Crystallography and molecular interactions","score":0.00019999999494757503,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12410","display_name":"Structural and Chemical Analysis of Organic and Inorganic Compounds","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/pyrrolidine","display_name":"pyrrolidine","score":0.8349999785423279},{"id":"https://openalex.org/keywords/indole","display_name":"indole","score":0.6069999933242798},{"id":"https://openalex.org/keywords/amide-groups","display_name":"amide groups","score":0.7020000219345093},{"id":"https://openalex.org/keywords/twist-conformation","display_name":"twisted conformation","score":0.8989999890327454},{"id":"https://openalex.org/keywords/steric-hindrance","display_name":"steric hindrance","score":0.871999979019165},{"id":"https://openalex.org/keywords/bromine-substituents","display_name":"bromine substituents","score":0.7279999852180481}],"concepts":[{"id":"https://openalex.org/C2778851528","wikidata":"https://www.wikidata.org/wiki/Q408898","display_name":"Pyrrolidine","level":2,"score":0.9745341539382935},{"id":"https://openalex.org/C201194858","wikidata":"https://www.wikidata.org/wiki/Q898238","display_name":"Steric effects","level":2,"score":0.8529226779937744},{"id":"https://openalex.org/C2779400197","wikidata":"https://www.wikidata.org/wiki/Q242627","display_name":"Pyrrole","level":2,"score":0.7151406407356262},{"id":"https://openalex.org/C2780378348","wikidata":"https://www.wikidata.org/wiki/Q25351438","display_name":"Ring (chemistry)","level":2,"score":0.7122153639793396},{"id":"https://openalex.org/C2778439535","wikidata":"https://www.wikidata.org/wiki/Q188777","display_name":"Amide","level":2,"score":0.670540452003479},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6429468989372253},{"id":"https://openalex.org/C68381374","wikidata":"https://www.wikidata.org/wiki/Q258652","display_name":"Double bond","level":2,"score":0.4960106313228607},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.4931642413139343},{"id":"https://openalex.org/C2776196297","wikidata":"https://www.wikidata.org/wiki/Q17138781","display_name":"Twist","level":2,"score":0.4675185978412628},{"id":"https://openalex.org/C58312451","wikidata":"https://www.wikidata.org/wiki/Q4817200","display_name":"Atom (system on chip)","level":2,"score":0.43068695068359375},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.13792285323143005},{"id":"https://openalex.org/C33923547","wikidata":"https://www.wikidata.org/wiki/Q395","display_name":"Mathematics","level":0,"score":0.11457708477973938},{"id":"https://openalex.org/C149635348","wikidata":"https://www.wikidata.org/wiki/Q193040","display_name":"Embedded system","level":1,"score":0.0},{"id":"https://openalex.org/C2524010","wikidata":"https://www.wikidata.org/wiki/Q8087","display_name":"Geometry","level":1,"score":0.0},{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1107/s1600536807017898","doi":"https://doi.org/10.1107/s1600536807017898","is_oa":false,"landing_page_url":"https://doi.org/10.1107/s1600536807017898","pdf_url":null,"source":{"id":"https://openalex.org/S146636433","display_name":"Acta Crystallographica Section E Structure Reports Online","issn_l":"1600-5368","issn":["1600-5368"],"is_oa":false,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj"],"host_organization":"https://openalex.org/P4310320555","host_organization_name":"International Union of Crystallography","host_organization_lineage":["https://openalex.org/P4310320555"],"host_organization_lineage_names":["International Union of Crystallography"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Acta Crystallographica Section E Structure Reports Online","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":7,"referenced_works":["https://openalex.org/W2059020082","https://openalex.org/W2059401704","https://openalex.org/W2064068872","https://openalex.org/W2065500841","https://openalex.org/W2092192554","https://openalex.org/W2173268067","https://openalex.org/W2951601934"],"related_works":["https://openalex.org/W1971877804","https://openalex.org/W2034700165","https://openalex.org/W2065794784","https://openalex.org/W2227501376","https://openalex.org/W2068419413","https://openalex.org/W1800289632","https://openalex.org/W2033628233","https://openalex.org/W2551954840","https://openalex.org/W1977865282","https://openalex.org/W2420006534"],"abstract_inverted_index":{"In":[0],"the":[1,5,21,30],"title":[2],"compound,":[3],"C14H15BrN2O,":[4],"pyrrolidine":[6],"ring":[7],"adopts":[8],"a":[9],"twist":[10],"conformation.":[11],"The":[12],"amide":[13],"group":[14],"is":[15],"twisted":[16],"out":[17],"of":[18],"\u03c0-conjugation":[19],"with":[20],"pyrrole":[22],"double":[23],"bond":[24],"due":[25],"to":[26],"steric":[27],"hindrance":[28],"by":[29],"Br":[31],"atom.":[32]},"counts_by_year":[],"updated_date":"2026-09-12T09:15:50.089291","created_date":"2016-06-24T00:00:00"}