{"id":"https://openalex.org/W154496253","doi":null,"title":"Nanocomposite Polymer Electrolyte Membranes: Methanol Crossover and Conductivity","display_name":"Nanocomposite Polymer Electrolyte Membranes: Methanol Crossover and Conductivity","publication_year":2005,"publication_date":"2005-01-01","ids":{"openalex":"https://openalex.org/W154496253","mag":"154496253"},"language":"en","primary_location":{"id":"mag:154496253","doi":null,"is_oa":false,"landing_page_url":"https://espace.library.uq.edu.au/view/UQ:12208/rodetal.pdf","pdf_url":null,"source":null,"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":null},"volume":null,"type":"article","is_traditional":true,"indexed_in":[],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5059307362","display_name":"Garnica Rodgriguez","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Garnica Rodgriguez","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5089574712","display_name":"Andrew L. Dicks","orcid":"https://orcid.org/0000-0002-2918-5614","observed_orcids":["https://orcid.org/0000-0002-2918-5614"]},"institutions":[{"id":"https://openalex.org/I165143802","display_name":"The University of Queensland","ror":"https://ror.org/00rqy9422","country_code":"AU","type":"education","lineage":["https://openalex.org/I165143802"]}],"countries":["AU"],"is_corresponding":false,"raw_author_name":"Andrew Dicks","raw_affiliation_strings":["University of Queensland"],"raw_orcid":"https://orcid.org/0000-0002-2918-5614","affiliations":[{"raw_affiliation_string":"University of Queensland","institution_ids":["https://openalex.org/I165143802"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5000363798","display_name":"Mikel Duke","orcid":"https://orcid.org/0000-0002-3383-0006","observed_orcids":["https://orcid.org/0000-0002-3383-0006"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Mikel Duke","raw_affiliation_strings":[],"raw_orcid":"https://orcid.org/0000-0002-3383-0006","affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5018311475","display_name":"Jo\u00e3o C. Diniz da Costa","orcid":"https://orcid.org/0000-0002-0450-2812","observed_orcids":["https://orcid.org/0000-0002-0450-2812"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Jo\u00e3o C. Diniz da Costa","raw_affiliation_strings":[],"raw_orcid":"https://orcid.org/0000-0002-0450-2812","affiliations":[]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.0,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":"201","last_page":"205"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10409","display_name":"Fuel Cells and Related Materials","score":1.0,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10409","display_name":"Fuel Cells and Related Materials","score":1.0,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10311","display_name":"Advancements in Solid Oxide Fuel Cells","score":0.0,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11362","display_name":"Membrane Separation and Gas Transport","score":0.0,"subfield":{"id":"https://openalex.org/subfields/1506","display_name":"Filtration and Separation"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/polymer-electrolyte-membranes","display_name":"polymer electrolyte membranes","score":0.8190000057220459},{"id":"https://openalex.org/keywords/nafion-117","display_name":"Nafion 117","score":0.8330000042915344},{"id":"https://openalex.org/keywords/methanol-crossover","display_name":"methanol crossover","score":0.9900000095367432},{"id":"https://openalex.org/keywords/proton-conductivity","display_name":"proton conductivity","score":0.7919999957084656},{"id":"https://openalex.org/keywords/direct-methanol-fuel-cells","display_name":"direct methanol fuel cells","score":0.7799999713897705},{"id":"https://openalex.org/keywords/in-situ-sol-gel","display_name":"in situ sol-gel","score":0.6990000009536743},{"id":"https://openalex.org/keywords/tetraethyl-orthosilicate","display_name":"tetraethoxysilane","score":0.8939999938011169},{"id":"https://openalex.org/keywords/aniline-polymerization","display_name":"aniline polymerization","score":0.9729999899864197},{"id":"https://openalex.org/keywords/membrane-modification","display_name":"membrane modification","score":0.7789999842643738}],"concepts":[{"id":"https://openalex.org/C2777580120","wikidata":"https://www.wikidata.org/wiki/Q417637","display_name":"Polyaniline","level":4,"score":0.892534613609314},{"id":"https://openalex.org/C2778665636","wikidata":"https://www.wikidata.org/wiki/Q412967","display_name":"Nafion","level":4,"score":0.8061842918395996},{"id":"https://openalex.org/C41625074","wikidata":"https://www.wikidata.org/wiki/Q176088","display_name":"Membrane","level":2,"score":0.7110048532485962},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.6048372983932495},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.5954408645629883},{"id":"https://openalex.org/C92880739","wikidata":"https://www.wikidata.org/wiki/Q2639556","display_name":"Nanocomposite","level":2,"score":0.5686010718345642},{"id":"https://openalex.org/C68801617","wikidata":"https://www.wikidata.org/wiki/Q162908","display_name":"Electrolyte","level":3,"score":0.5626869797706604},{"id":"https://openalex.org/C2778643723","wikidata":"https://www.wikidata.org/wiki/Q901910","display_name":"Direct methanol fuel cell","level":4,"score":0.5327150225639343},{"id":"https://openalex.org/C131540310","wikidata":"https://www.wikidata.org/wiki/Q907564","display_name":"Conductivity","level":2,"score":0.5186478495597839},{"id":"https://openalex.org/C2779607525","wikidata":"https://www.wikidata.org/wiki/Q14982","display_name":"Methanol","level":2,"score":0.5119019746780396},{"id":"https://openalex.org/C175365462","wikidata":"https://www.wikidata.org/wiki/Q4206984","display_name":"Methanol fuel","level":3,"score":0.5021700859069824},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.48777347803115845},{"id":"https://openalex.org/C44228677","wikidata":"https://www.wikidata.org/wiki/Q181898","display_name":"Polymerization","level":3,"score":0.4469795823097229},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.424300879240036},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.24886956810951233},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.19166061282157898},{"id":"https://openalex.org/C52859227","wikidata":"https://www.wikidata.org/wiki/Q7877","display_name":"Electrochemistry","level":3,"score":0.163271963596344},{"id":"https://openalex.org/C17525397","wikidata":"https://www.wikidata.org/wiki/Q176140","display_name":"Electrode","level":2,"score":0.14942806959152222},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.140639066696167},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C89395315","wikidata":"https://www.wikidata.org/wiki/Q181232","display_name":"Anode","level":3,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"mag:154496253","doi":null,"is_oa":false,"landing_page_url":"https://espace.library.uq.edu.au/view/UQ:12208/rodetal.pdf","pdf_url":null,"source":null,"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":null}],"best_oa_location":null,"sustainable_development_goals":[{"score":0.75,"id":"https://metadata.un.org/sdg/7","display_name":"Affordable and clean energy"}],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":14,"referenced_works":["https://openalex.org/W32462205","https://openalex.org/W652444414","https://openalex.org/W2008916688","https://openalex.org/W2021695346","https://openalex.org/W2028621333","https://openalex.org/W2030569492","https://openalex.org/W2030729775","https://openalex.org/W2047139261","https://openalex.org/W2060276153","https://openalex.org/W2061014320","https://openalex.org/W2067388576","https://openalex.org/W2078117219","https://openalex.org/W2142100982","https://openalex.org/W2302461024"],"related_works":["https://openalex.org/W1512170180","https://openalex.org/W2089144458","https://openalex.org/W2603777539","https://openalex.org/W1503474360","https://openalex.org/W2170644345","https://openalex.org/W2067388576","https://openalex.org/W2618169890","https://openalex.org/W2093192421","https://openalex.org/W2765851775","https://openalex.org/W1972099492"],"abstract_inverted_index":{"Commercial":[0],"Nafion\u00ae":[1],"117":[2],"membranes":[3,36,54],"were":[4,25],"successfully":[5],"modified":[6,60],"by":[7],"in-situ":[8],"reactions":[9],"(sol-gel":[10],"of":[11,15,34,91,108,115],"TEOS":[12],"and/or":[13],"polymerization":[14],"aniline)":[16],"within":[17],"Nafion":[18,53],"structures.":[19],"Water-methanol":[20],"permeability":[21],"and":[22],"proton":[23],"conductivity":[24,70],"investigated":[26],"in":[27,43,101],"order":[28],"to":[29,55,81,86,111],"determine":[30],"the":[31,59,75,106,113],"potential":[32,107],"performance":[33,114],"these":[35],"for":[37,51,58,95],"DMFC":[38],"systems.":[39],"Silica-polyaniline":[40],"modification":[41],"resulted":[42],"84%":[44],"methanol":[45],"crossover":[46],"reduction,":[47],"from":[48,79],"2.45x10^-5":[49],"cm2.s^-1":[50,57],"conventional":[52],"3.71x10^-6":[56],"silica-polyaniline":[61],"composite":[62,97],"membrane":[63,77],"at":[64],"75":[65],"degrees":[66],"C.":[67],"In":[68],"addition,":[69],"was":[71,93],"not":[72],"hindered,":[73],"as":[74,84],"polyaniline-Nafion":[76],"increased":[78],"12.2":[80],"15":[82],"mS.cm^-1":[83],"compared":[85],"Nafion,":[87],"while":[88],"a":[89],"reduction":[90],"11%":[92],"observed":[94],"silica-polyaniline-Nafion":[96],"membrane.":[98],"The":[99],"results":[100],"this":[102],"work":[103],"strongly":[104],"suggest":[105],"polyaniline":[109],"nanocomposites":[110],"enhance":[112],"DMFCs.":[116]},"counts_by_year":[],"updated_date":"2026-09-22T06:50:58.402377","created_date":"2016-06-24T00:00:00"}