{"id":"https://openalex.org/W1533683063","doi":"https://doi.org/10.1080/00268977200100771","title":"Reactive scattering of a supersonic alkali atom beam: K + Br2, BrCN, SnCl4, PCl3, CCl4, CH3I","display_name":"Reactive scattering of a supersonic alkali atom beam: K + Br2, BrCN, SnCl4, PCl3, CCl4, CH3I","publication_year":1972,"publication_date":"1972-04-01","ids":{"openalex":"https://openalex.org/W1533683063","doi":"https://doi.org/10.1080/00268977200100771","mag":"1533683063"},"language":"en","primary_location":{"id":"doi:10.1080/00268977200100771","doi":"https://doi.org/10.1080/00268977200100771","is_oa":false,"landing_page_url":"https://doi.org/10.1080/00268977200100771","pdf_url":null,"source":{"id":"https://openalex.org/S204809294","display_name":"Molecular Physics","issn_l":"0026-8976","issn":["0026-8976","1362-3028"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","jufo-1","norway-1","poland-70","russia-white-list-3"],"host_organization":"https://openalex.org/P4310320547","host_organization_name":"Taylor & Francis","host_organization_lineage":["https://openalex.org/P4310320547","https://openalex.org/P4310320449"],"host_organization_lineage_names":["Taylor & Francis","Informa"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Molecular Physics","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5072840858","display_name":"J. Christopher Whitehead","orcid":"https://orcid.org/0000-0001-6376-4479","observed_orcids":["https://orcid.org/0000-0001-6376-4479","https://orcid.org/0000-0003-1645-7286","https://orcid.org/0000-0002-1223-0001"]},"institutions":[{"id":"https://openalex.org/I241749","display_name":"University of Cambridge","ror":"https://ror.org/013meh722","country_code":"GB","type":"education","lineage":["https://openalex.org/I241749"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"J.C. Whitehead","raw_affiliation_strings":["Department of Theoretical Chemistry, Cambridge University, Cambridge, CB2 1EW"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Theoretical Chemistry, Cambridge University, Cambridge, CB2 1EW","institution_ids":["https://openalex.org/I241749"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5013386877","display_name":"D.R. Hardin","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I241749","display_name":"University of Cambridge","ror":"https://ror.org/013meh722","country_code":"GB","type":"education","lineage":["https://openalex.org/I241749"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"D.R. Hardin","raw_affiliation_strings":["Department of Theoretical Chemistry, Cambridge University, Cambridge, CB2 1EW; United States Churchill Scholar, Churchill College, Cambridge","Department of Theoretical Chemistry , Cambridge University , Cambridge, CB2 1EW","United States Churchill Scholar, Churchill College , Cambridge"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Theoretical Chemistry, Cambridge University, Cambridge, CB2 1EW; United States Churchill Scholar, Churchill College, Cambridge","institution_ids":["https://openalex.org/I241749"]},{"raw_affiliation_string":"Department of Theoretical Chemistry , Cambridge University , Cambridge, CB2 1EW","institution_ids":["https://openalex.org/I241749"]},{"raw_affiliation_string":"United States Churchill Scholar, Churchill College , Cambridge","institution_ids":["https://openalex.org/I241749"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5113522639","display_name":"R. Grice","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I241749","display_name":"University of Cambridge","ror":"https://ror.org/013meh722","country_code":"GB","type":"education","lineage":["https://openalex.org/I241749"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"R. Grice","raw_affiliation_strings":["Department of Theoretical Chemistry, Cambridge University, Cambridge, CB2 1EW"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Theoretical Chemistry, Cambridge University, Cambridge, CB2 1EW","institution_ids":["https://openalex.org/I241749"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I241749"],"apc_list":null,"apc_paid":null,"fwci":6.236,"has_fulltext":false,"cited_by_count":31,"citation_normalized_percentile":{"value":0.97684887,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":null,"biblio":{"volume":"23","issue":"4","first_page":"787","last_page":"805"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12044","display_name":"Advanced Physical and Chemical Molecular Interactions","score":0.8291000127792358,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12044","display_name":"Advanced Physical and Chemical Molecular Interactions","score":0.8291000127792358,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10523","display_name":"Atomic and Molecular Physics","score":0.08380000293254852,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10002","display_name":"Advanced Chemical Physics Studies","score":0.051899999380111694,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/reactive-scattering","display_name":"reactive scattering","score":0.9100000262260437},{"id":"https://openalex.org/keywords/supersonic-atom-beam","display_name":"supersonic atom beam","score":0.7170000076293945},{"id":"https://openalex.org/keywords/angular-distributions","display_name":"angular distributions","score":0.6370000243186951},{"id":"https://openalex.org/keywords/total-reaction-cross-section","display_name":"total reaction cross section","score":0.8489999771118164},{"id":"https://openalex.org/keywords/br2","display_name":"Br2","score":0.675000011920929},{"id":"https://openalex.org/keywords/cyanogen-bromide","display_name":"cyanogen bromide","score":0.9959999918937683},{"id":"https://openalex.org/keywords/tin-iv-chloride","display_name":"tin(IV) chloride","score":0.9760000109672546},{"id":"https://openalex.org/keywords/phosphorus-trichloride","display_name":"phosphorus trichloride","score":1.0},{"id":"https://openalex.org/keywords/carbon-tetrachloride","display_name":"carbon tetrachloride","score":1.0},{"id":"https://openalex.org/keywords/methyl-iodide","display_name":"methyl iodide","score":0.9980000257492065}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7768361568450928},{"id":"https://openalex.org/C184779094","wikidata":"https://www.wikidata.org/wiki/Q26383","display_name":"Atomic physics","level":1,"score":0.733952522277832},{"id":"https://openalex.org/C191486275","wikidata":"https://www.wikidata.org/wiki/Q210028","display_name":"Scattering","level":2,"score":0.7038075923919678},{"id":"https://openalex.org/C54419926","wikidata":"https://www.wikidata.org/wiki/Q1246432","display_name":"Molecular beam","level":3,"score":0.5268146991729736},{"id":"https://openalex.org/C58312451","wikidata":"https://www.wikidata.org/wiki/Q4817200","display_name":"Atom (system on chip)","level":2,"score":0.5267103314399719},{"id":"https://openalex.org/C135889238","wikidata":"https://www.wikidata.org/wiki/Q46276","display_name":"Kinetic energy","level":2,"score":0.48594939708709717},{"id":"https://openalex.org/C52234038","wikidata":"https://www.wikidata.org/wiki/Q17128025","display_name":"Cross section (physics)","level":2,"score":0.4391452372074127},{"id":"https://openalex.org/C204323151","wikidata":"https://www.wikidata.org/wiki/Q905424","display_name":"Range (aeronautics)","level":2,"score":0.43220055103302},{"id":"https://openalex.org/C198091228","wikidata":"https://www.wikidata.org/wiki/Q19557","display_name":"Alkali metal","level":2,"score":0.4256644546985626},{"id":"https://openalex.org/C2777734200","wikidata":"https://www.wikidata.org/wiki/Q906605","display_name":"Crossed molecular beam","level":3,"score":0.41092920303344727},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.2946833372116089},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.20673230290412903},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.11578121781349182},{"id":"https://openalex.org/C120665830","wikidata":"https://www.wikidata.org/wiki/Q14620","display_name":"Optics","level":1,"score":0.09905463457107544},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.0},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.0},{"id":"https://openalex.org/C149635348","wikidata":"https://www.wikidata.org/wiki/Q193040","display_name":"Embedded system","level":1,"score":0.0},{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1080/00268977200100771","doi":"https://doi.org/10.1080/00268977200100771","is_oa":false,"landing_page_url":"https://doi.org/10.1080/00268977200100771","pdf_url":null,"source":{"id":"https://openalex.org/S204809294","display_name":"Molecular Physics","issn_l":"0026-8976","issn":["0026-8976","1362-3028"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","jufo-1","norway-1","poland-70","russia-white-list-3"],"host_organization":"https://openalex.org/P4310320547","host_organization_name":"Taylor & Francis","host_organization_lineage":["https://openalex.org/P4310320547","https://openalex.org/P4310320449"],"host_organization_lineage_names":["Taylor & Francis","Informa"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Molecular Physics","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":29,"referenced_works":["https://openalex.org/W1485234960","https://openalex.org/W1490164232","https://openalex.org/W1523417784","https://openalex.org/W1578418415","https://openalex.org/W1677262061","https://openalex.org/W1892939355","https://openalex.org/W1967441190","https://openalex.org/W1976915963","https://openalex.org/W1999701886","https://openalex.org/W2005939892","https://openalex.org/W2013219597","https://openalex.org/W2013531327","https://openalex.org/W2021746218","https://openalex.org/W2027063983","https://openalex.org/W2038527810","https://openalex.org/W2041126752","https://openalex.org/W2052351726","https://openalex.org/W2053013170","https://openalex.org/W2055883930","https://openalex.org/W2056798560","https://openalex.org/W2072045550","https://openalex.org/W2082610929","https://openalex.org/W2110490954","https://openalex.org/W2135237683","https://openalex.org/W2169291943","https://openalex.org/W2215691651","https://openalex.org/W2798456356","https://openalex.org/W4243860725","https://openalex.org/W4253395999"],"related_works":["https://openalex.org/W1602070516","https://openalex.org/W2029290580","https://openalex.org/W1968794804","https://openalex.org/W4254294802","https://openalex.org/W4242901009","https://openalex.org/W2093513119","https://openalex.org/W2079689599","https://openalex.org/W2021746218","https://openalex.org/W4238997926","https://openalex.org/W2070392770"],"abstract_inverted_index":{"Angular":[0],"distribution":[1,37],"measurements":[2],"of":[3,6,15,120],"reactive":[4],"scattering":[5,67,85],"a":[7,13,114,140],"supersonic":[8],"potassium":[9],"atom":[10],"beam":[11],"by":[12,145],"series":[14],"molecules":[16],"are":[17,49],"reported":[18],"with":[19,53,69,88,113],"initial":[20],"kinetic":[21],"energy":[22,30,43],"(\u223c":[23],"5":[24],"kcal":[25],"mole-1)":[26],"above":[27],"the":[28,99,118,135],"thermal":[29,42,70],"range.":[31],"The":[32,83,102],"narrow":[33],"Laval":[34],"nozzle":[35],"velocity":[36,123,132],"gives":[38],"improved":[39],"resolution":[40],"over":[41],"measurements.":[44],"Total":[45],"reaction":[46,56,105,147],"cross":[47,57,106],"sections":[48,58],"found":[50],"to":[51,79,110,134],"decrease":[52],"energy.":[54],"Differential":[55],"for":[59,73],"Br2,":[60],"BrCN":[61,84],"and":[62,130],"CCl4":[63],"show":[64],"increased":[65],"forward":[66],"compared":[68],"energies":[71],"but":[72],"CH3I":[74],"there":[75],"is":[76,86,126],"no":[77],"change":[78],"within":[80],"experimental":[81],"error.":[82],"compatible":[87,112],"spectator-stripping":[89],"dynamics,":[90],"though":[91],"this":[92],"limit":[93],"has":[94],"not":[95,109],"been":[96],"reached":[97],"in":[98,117],"Br2":[100],"scattering.":[101],"SnCl4":[103],"differential":[104],"section":[107],"appears":[108],"be":[111],"single":[115],"peak":[116],"centre":[119],"mass":[121],"recoil":[122],"distribution.":[124],"It":[125],"suggested":[127],"that":[128],"high":[129],"low":[131],"contributions":[133],"intensity":[136],"may":[137],"arise":[138],"from":[139],"long-lived":[141],"collision":[142],"complex":[143],"dissociating":[144],"two":[146],"paths.":[148]},"counts_by_year":[],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2016-06-24T00:00:00"}