{"id":"https://openalex.org/W133166143","doi":"https://doi.org/10.1103/physrevb.31.2240","title":"Vibrational and electronic properties ofM P15 polyphosphides: KP15 thin films","display_name":"Vibrational and electronic properties ofM P15 polyphosphides: KP15 thin films","publication_year":1985,"publication_date":"1985-02-15","ids":{"openalex":"https://openalex.org/W133166143","doi":"https://doi.org/10.1103/physrevb.31.2240","mag":"133166143","pmid":"https://pubmed.ncbi.nlm.nih.gov/9936030"},"language":"en","primary_location":{"id":"doi:10.1103/physrevb.31.2240","doi":"https://doi.org/10.1103/physrevb.31.2240","is_oa":false,"landing_page_url":"https://doi.org/10.1103/physrevb.31.2240","pdf_url":null,"source":{"id":"https://openalex.org/S4210174675","display_name":"Physical review. B, Condensed matter","issn_l":"0163-1829","issn":["0163-1829","1095-3795"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","ki-jl-2"],"host_organization":"https://openalex.org/P4310320261","host_organization_name":"American Physical Society","host_organization_lineage":["https://openalex.org/P4310320261"],"host_organization_lineage_names":["American Physical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Physical Review B","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5001199378","display_name":"Diego J. Olego","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"D. J. Olego","raw_affiliation_strings":["Stauffer Chemical Company, Eastern Research Center, Elmsford, New York 10523"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Stauffer Chemical Company, Eastern Research Center, Elmsford, New York 10523","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5112505078","display_name":"John A. Baumann","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"J. Baumann","raw_affiliation_strings":["Stauffer Chemical Company, Eastern Research Center, Elmsford, New York 10523"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Stauffer Chemical Company, Eastern Research Center, Elmsford, New York 10523","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5068786648","display_name":"R. Schachter","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"R. Schachter","raw_affiliation_strings":["Stauffer Chemical Company, Eastern Research Center, Elmsford, New York 10523"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Stauffer Chemical Company, Eastern Research Center, Elmsford, New York 10523","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5066349533","display_name":"C. Michel","orcid":"https://orcid.org/0000-0003-0606-725X","observed_orcids":["https://orcid.org/0000-0003-0606-725X"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"C. Michel","raw_affiliation_strings":["Stauffer Chemical Company, Eastern Research Center, Elmsford, New York 10523"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Stauffer Chemical Company, Eastern Research Center, Elmsford, New York 10523","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5043494719","display_name":"M. A. Kuck","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"M. Kuck","raw_affiliation_strings":["Stauffer Chemical Company, Eastern Research Center, Elmsford, New York 10523"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Stauffer Chemical Company, Eastern Research Center, Elmsford, New York 10523","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5058210999","display_name":"Susan W. Gersten","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"S. Gersten","raw_affiliation_strings":["Stauffer Chemical Company, Eastern Research Center, Elmsford, New York 10523"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Stauffer Chemical Company, Eastern Research Center, Elmsford, New York 10523","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5017997784","display_name":"Leslie G. Polgar","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"L. G. Polgar","raw_affiliation_strings":["Stauffer Chemical Company, Eastern Research Center, Elmsford, New York 10523"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Stauffer Chemical Company, Eastern Research Center, Elmsford, New York 10523","institution_ids":[]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5064779153","display_name":"P. M. Raccah","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I39422238","display_name":"University of Illinois Chicago","ror":"https://ror.org/02mpq6x41","country_code":"US","type":"education","lineage":["https://openalex.org/I39422238"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"P. M. Raccah","raw_affiliation_strings":["Stauffer Chemical Company, Eastern Research Center, Elmsford, New York 10523","Department of Physics, University of Illinois at Chicago, Chicago, Illinois 60680"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Stauffer Chemical Company, Eastern Research Center, Elmsford, New York 10523","institution_ids":[]},{"raw_affiliation_string":"Department of Physics, University of Illinois at Chicago, Chicago, Illinois 60680","institution_ids":["https://openalex.org/I39422238"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":0.2738,"has_fulltext":false,"cited_by_count":6,"citation_normalized_percentile":{"value":0.45282017,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":93},"biblio":{"volume":"31","issue":"4","first_page":"2240","last_page":"2245"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10939","display_name":"Crystal Structures and Properties","score":0.17739999294281006,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10939","display_name":"Crystal Structures and Properties","score":0.17739999294281006,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10275","display_name":"2D Materials and Applications","score":0.16599999368190765,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11315","display_name":"Phase-change materials and chalcogenides","score":0.08500000089406967,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/thin-films","display_name":"thin films","score":0.7210000157356262},{"id":"https://openalex.org/keywords/raman-spectroscopy","display_name":"Raman spectroscopy","score":0.7429999709129333},{"id":"https://openalex.org/keywords/photoluminescence","display_name":"photoluminescence","score":1.0},{"id":"https://openalex.org/keywords/long-range-order","display_name":"long-range order","score":0.625},{"id":"https://openalex.org/keywords/structural-order-parameter","display_name":"structural order parameter","score":0.6129999756813049},{"id":"https://openalex.org/keywords/substrate-temperature","display_name":"substrate temperature","score":0.6970000267028809},{"id":"https://openalex.org/keywords/vapor-transport-deposition","display_name":"vapor transport deposition","score":0.7730000019073486},{"id":"https://openalex.org/keywords/amorphization","display_name":"amorphization","score":0.7609999775886536},{"id":"https://openalex.org/keywords/defect-states","display_name":"defect states","score":0.7089999914169312},{"id":"https://openalex.org/keywords/red-phosphorus","display_name":"red phosphorus","score":0.6230000257492065},{"id":"https://openalex.org/keywords/semiconductors","display_name":"semiconductors","score":0.44600000977516174},{"id":"https://openalex.org/keywords/structural-phase-transition","display_name":"structural phase transition","score":0.5289999842643738},{"id":"https://openalex.org/keywords/order-and-disorder","display_name":"order and disorder","score":0.5040000081062317}],"concepts":[{"id":"https://openalex.org/C40003534","wikidata":"https://www.wikidata.org/wiki/Q862228","display_name":"Raman spectroscopy","level":2,"score":0.7637889385223389},{"id":"https://openalex.org/C85080765","wikidata":"https://www.wikidata.org/wiki/Q614893","display_name":"Photoluminescence","level":2,"score":0.7380472421646118},{"id":"https://openalex.org/C182306322","wikidata":"https://www.wikidata.org/wiki/Q1779371","display_name":"Order (exchange)","level":2,"score":0.7215671539306641},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.5627296566963196},{"id":"https://openalex.org/C4839761","wikidata":"https://www.wikidata.org/wiki/Q212111","display_name":"Spectral line","level":2,"score":0.47069621086120605},{"id":"https://openalex.org/C24123453","wikidata":"https://www.wikidata.org/wiki/Q900121","display_name":"Molecular vibration","level":3,"score":0.4170178174972534},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.3998878598213196},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.3721463978290558},{"id":"https://openalex.org/C26873012","wikidata":"https://www.wikidata.org/wiki/Q214781","display_name":"Condensed matter physics","level":1,"score":0.3626488745212555},{"id":"https://openalex.org/C184779094","wikidata":"https://www.wikidata.org/wiki/Q26383","display_name":"Atomic physics","level":1,"score":0.3397711515426636},{"id":"https://openalex.org/C120665830","wikidata":"https://www.wikidata.org/wiki/Q14620","display_name":"Optics","level":1,"score":0.21839722990989685},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.12981009483337402},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.10128265619277954},{"id":"https://openalex.org/C162324750","wikidata":"https://www.wikidata.org/wiki/Q8134","display_name":"Economics","level":0,"score":0.0},{"id":"https://openalex.org/C10138342","wikidata":"https://www.wikidata.org/wiki/Q43015","display_name":"Finance","level":1,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1103/physrevb.31.2240","doi":"https://doi.org/10.1103/physrevb.31.2240","is_oa":false,"landing_page_url":"https://doi.org/10.1103/physrevb.31.2240","pdf_url":null,"source":{"id":"https://openalex.org/S4210174675","display_name":"Physical review. B, Condensed matter","issn_l":"0163-1829","issn":["0163-1829","1095-3795"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","ki-jl-2"],"host_organization":"https://openalex.org/P4310320261","host_organization_name":"American Physical Society","host_organization_lineage":["https://openalex.org/P4310320261"],"host_organization_lineage_names":["American Physical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Physical Review B","raw_type":"journal-article"},{"id":"pmid:9936030","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/9936030","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Physical review. B, Condensed matter","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":11,"referenced_works":["https://openalex.org/W1006076248","https://openalex.org/W1974502568","https://openalex.org/W2010405992","https://openalex.org/W2013995217","https://openalex.org/W2017076819","https://openalex.org/W2022481469","https://openalex.org/W2039099860","https://openalex.org/W2061905891","https://openalex.org/W2086278048","https://openalex.org/W2086724478","https://openalex.org/W2727858776"],"related_works":["https://openalex.org/W1679169920","https://openalex.org/W79593674","https://openalex.org/W2039099860","https://openalex.org/W2014581225","https://openalex.org/W2017076819","https://openalex.org/W2018044487","https://openalex.org/W2314831973","https://openalex.org/W2268541512","https://openalex.org/W2039162779","https://openalex.org/W2073162048"],"abstract_inverted_index":{"We":[0,252],"report":[1],"Raman":[2,88,150,217,256],"and":[3,62,101,106,152,182,188,215,275],"photoluminescence":[4,159,194,241],"investigations":[5],"of":[6,23,28,41,46,51,93,146,153,157,165,173,184,192,209,219,228,280,288],"${\\mathrm{KP}}_{15}$":[7,43,66,166,221,273],"thin":[8,67,222],"films.":[9],"This":[10],"novel":[11],"semiconductor":[12],"material":[13],"constitutes":[14],"a":[15,137,190,259],"model":[16],"system":[17,274],"in":[18,25,111,117,178,189,239,249],"which":[19],"to":[20,226,244,246,265],"investigate":[21],"effects":[22],"changes":[24],"the":[26,42,60,112,118,144,154,158,162,185,193,210,216,220,240,250,255,263,266,272,277,285,289],"degree":[27],"structural":[29,286],"order":[30,35,57,84,135,203],"when":[31],"more":[32],"than":[33],"one":[34],"parameter":[36],"is":[37,85,139,204,237],"involved.":[38],"The":[39,55,65,87,123,171],"structure":[40],"polyphosphides":[44],"consists":[45],"parallel":[47],"unidimensional":[48],"P":[49],"tubes":[50,279],"pentagonal":[52,281],"cross":[53,282],"section.":[54],"relevant":[56],"parameters":[58],"are":[59,114,127,224,284],"intratube":[61,102,149,186,201,211],"intertube":[63,96,125,174],"correlations.":[64],"films":[68,113,223],"were":[69],"deposited":[70],"at":[71,161,234],"different":[72],"substrate":[73],"temperatures":[74],"${T}_{S}$":[75],"by":[76,129,143],"vapor":[77],"transport":[78],"methods.":[79],"For":[80],"${T}_{S}$\\ensuremath{\\gtrsim}600":[81],"K,":[82,200],"long-range":[83,134,202],"present.":[86],"spectra":[89,218,242],"display":[90],"two":[91],"sets":[92],"sharp":[94,124,148],"modes:":[95],"vibrations":[97,103],"below":[98],"150":[99],"${\\mathrm{cm}}^{\\mathrm{\\ensuremath{-}}1}$":[100],"between":[104],"200":[105],"500":[107],"${\\mathrm{cm}}^{\\mathrm{\\ensuremath{-}}1}$.":[108],"Intertube":[109],"correlations":[110],"gradually":[115],"lost":[116],"temperature":[119],"range":[120],"600\\ensuremath{\\gtrsim}${T}_{S}$\\ensuremath{\\gtrsim}520":[121],"K.":[122],"modes":[126,151,187,212],"replaced":[128],"featureless":[130],"broad":[131],"bands.":[132],"However,":[133],"within":[136],"tube":[138],"preserved":[140],"as":[141],"indicated":[142],"retention":[145],"relative":[147],"spectral":[155],"position":[156],"bands":[160],"band-gap":[163],"energy":[164],"single":[167],"crystal":[168],"(\\ensuremath{\\sim}1.8":[169],"eV).":[170],"lack":[172],"correlation":[175],"manifests":[176],"itself":[177],"some":[179],"red":[180,230,291],"shifts":[181],"broadening":[183,208],"decrease":[191],"intensity":[195],"with":[196],"${T}_{S}$.":[197],"When":[198],"${T}_{S}$520":[199],"destroyed.":[205],"A":[206],"large":[207],"takes":[213,269],"place":[214,270],"similar":[225],"that":[227,258,276],"amorphous":[229,267,290],"phosphorus.":[231],"Only":[232],"emission":[233],"\\ensuremath{\\sim}1.45":[235],"eV":[236],"measured":[238],"corresponding":[243],"transitions":[245],"defect":[247],"states":[248],"gap.":[251],"conclude":[253],"from":[254,262],"data":[257],"continuous":[260],"transition":[261],"crystalline":[264],"state":[268],"for":[271],"phosphorus":[278,292],"section":[283],"units":[287],"network.":[293]},"counts_by_year":[{"year":2019,"cited_by_count":1}],"updated_date":"2026-11-09T13:22:03.289127","created_date":"2016-06-24T00:00:00"}