{"id":"https://openalex.org/W125041920","doi":"https://doi.org/10.1007/bfb0116464","title":"Equilibrium and dynamic aspects of end-attached diblock and triblock copolymer chains","display_name":"Equilibrium and dynamic aspects of end-attached diblock and triblock copolymer chains","publication_year":2007,"publication_date":"2007-12-10","ids":{"openalex":"https://openalex.org/W125041920","doi":"https://doi.org/10.1007/bfb0116464","mag":"125041920"},"language":"en","primary_location":{"id":"doi:10.1007/bfb0116464","doi":"https://doi.org/10.1007/bfb0116464","is_oa":false,"landing_page_url":"https://doi.org/10.1007/bfb0116464","pdf_url":null,"source":{"id":"https://openalex.org/S4306463955","display_name":"Steinkopff eBooks","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"ebook platform"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Progress in Colloid & Polymer Science","raw_type":"book-chapter"},"volume":{"id":"https://openalex.org/W615106000","display_name":"Application of Scattering Methods to the Dynamics of Polymer Systems"},"type":"book-chapter","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5087965951","display_name":"Chris Toprakcioglu","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I241749","display_name":"University of Cambridge","ror":"https://ror.org/013meh722","country_code":"GB","type":"education","lineage":["https://openalex.org/I241749"]},{"id":"https://openalex.org/I3018370718","display_name":"Quadram Institute","ror":"https://ror.org/04td3ys19","country_code":"GB","type":"facility","lineage":["https://openalex.org/I2799693246","https://openalex.org/I3018370718","https://openalex.org/I4210087105"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"C. TOprakcioglu","raw_affiliation_strings":["Cavendish Laboratory, PCS, University of Cambridge, Madingley Road, CB3 0HE, Cambridge, England","Institute of Food Research, AFRC, Norwich, England"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Cavendish Laboratory, PCS, University of Cambridge, Madingley Road, CB3 0HE, Cambridge, England","institution_ids":["https://openalex.org/I241749"]},{"raw_affiliation_string":"Institute of Food Research, AFRC, Norwich, England","institution_ids":["https://openalex.org/I3018370718"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5025689163","display_name":"Liming Dai","orcid":"https://orcid.org/0000-0001-7536-160X","observed_orcids":["https://orcid.org/0000-0001-7536-160X"]},"institutions":[{"id":"https://openalex.org/I241749","display_name":"University of Cambridge","ror":"https://ror.org/013meh722","country_code":"GB","type":"education","lineage":["https://openalex.org/I241749"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"L. Dai","raw_affiliation_strings":["Cavendish Laboratory, PCS, University of Cambridge, Madingley Road, CB3 0HE, Cambridge, England"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Cavendish Laboratory, PCS, University of Cambridge, Madingley Road, CB3 0HE, Cambridge, England","institution_ids":["https://openalex.org/I241749"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5079813171","display_name":"M. Ali Ansarifar","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I241749","display_name":"University of Cambridge","ror":"https://ror.org/013meh722","country_code":"GB","type":"education","lineage":["https://openalex.org/I241749"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"M. A. Ansarifar","raw_affiliation_strings":["Cavendish Laboratory, PCS, University of Cambridge, Madingley Road, CB3 0HE, Cambridge, England"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Cavendish Laboratory, PCS, University of Cambridge, Madingley Road, CB3 0HE, Cambridge, England","institution_ids":["https://openalex.org/I241749"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5021817279","display_name":"Manfred Stamm","orcid":"https://orcid.org/0000-0001-9309-1172","observed_orcids":["https://orcid.org/0000-0001-9309-1172"]},"institutions":[{"id":"https://openalex.org/I4210095245","display_name":"Max Planck Institute for Polymer Research","ror":"https://ror.org/00sb7hc59","country_code":"DE","type":"facility","lineage":["https://openalex.org/I149899117","https://openalex.org/I4210095245"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"M. Stamm","raw_affiliation_strings":["Max-Planck Institute fur Polymerforschung, Mainz, FRG"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Max-Planck Institute fur Polymerforschung, Mainz, FRG","institution_ids":["https://openalex.org/I4210095245"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5025014125","display_name":"Hubert R. Motschmann","orcid":"https://orcid.org/0000-0002-4491-4854","observed_orcids":["https://orcid.org/0000-0002-4491-4854"]},"institutions":[{"id":"https://openalex.org/I4210095245","display_name":"Max Planck Institute for Polymer Research","ror":"https://ror.org/00sb7hc59","country_code":"DE","type":"facility","lineage":["https://openalex.org/I149899117","https://openalex.org/I4210095245"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"H. Motschmann","raw_affiliation_strings":["Max-Planck Institute fur Polymerforschung, Mainz, FRG"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Max-Planck Institute fur Polymerforschung, Mainz, FRG","institution_ids":["https://openalex.org/I4210095245"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":3,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":6,"citation_normalized_percentile":{"value":0.05957447,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":94},"biblio":{"volume":null,"issue":null,"first_page":"83","last_page":"87"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10859","display_name":"Polymer Surface Interaction Studies","score":0.4343000054359436,"subfield":{"id":"https://openalex.org/subfields/2508","display_name":"Surfaces, Coatings and Films"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10859","display_name":"Polymer Surface Interaction Studies","score":0.4343000054359436,"subfield":{"id":"https://openalex.org/subfields/2508","display_name":"Surfaces, Coatings and Films"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11471","display_name":"Block Copolymer Self-Assembly","score":0.3441999852657318,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.18209999799728394,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/diblock-copolymers","display_name":"diblock copolymers","score":0.9190000295639038},{"id":"https://openalex.org/keywords/triblock-copolymers","display_name":"triblock copolymers","score":0.9990000128746033},{"id":"https://openalex.org/keywords/adsorption-kinetics","display_name":"adsorption kinetics","score":0.8460000157356262},{"id":"https://openalex.org/keywords/adsorbed-layers","display_name":"adsorbed layers","score":0.6800000071525574},{"id":"https://openalex.org/keywords/solid-liquid-interface","display_name":"solid-liquid interface","score":0.8920000195503235},{"id":"https://openalex.org/keywords/volume-fraction-profiles","display_name":"volume fraction profiles","score":0.777999997138977},{"id":"https://openalex.org/keywords/diffusion-controlled-adsorption","display_name":"diffusion-controlled adsorption","score":0.8109999895095825},{"id":"https://openalex.org/keywords/conformational-change","display_name":"conformational change","score":0.9129999876022339},{"id":"https://openalex.org/keywords/attractive-force","display_name":"attractive force","score":0.6019999980926514},{"id":"https://openalex.org/keywords/mica-surface","display_name":"mica surface","score":0.7870000004768372},{"id":"https://openalex.org/keywords/polymer-chain-dynamics","display_name":"polymer chain dynamics","score":0.5690000057220459}],"concepts":[{"id":"https://openalex.org/C15920480","wikidata":"https://www.wikidata.org/wiki/Q421281","display_name":"Copolymer","level":3,"score":0.8610515594482422},{"id":"https://openalex.org/C150394285","wikidata":"https://www.wikidata.org/wiki/Q180254","display_name":"Adsorption","level":2,"score":0.7129640579223633},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.6459994912147522},{"id":"https://openalex.org/C2777922577","wikidata":"https://www.wikidata.org/wiki/Q146243","display_name":"Polystyrene","level":3,"score":0.595183789730072},{"id":"https://openalex.org/C1816345","wikidata":"https://www.wikidata.org/wiki/Q1981942","display_name":"Neutron reflectometry","level":5,"score":0.590384840965271},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.5202411413192749},{"id":"https://openalex.org/C69357855","wikidata":"https://www.wikidata.org/wiki/Q163214","display_name":"Diffusion","level":2,"score":0.4541536867618561},{"id":"https://openalex.org/C204921945","wikidata":"https://www.wikidata.org/wiki/Q899689","display_name":"Side chain","level":3,"score":0.4421464800834656},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.43849095702171326},{"id":"https://openalex.org/C148898269","wikidata":"https://www.wikidata.org/wiki/Q1108792","display_name":"Kinetics","level":2,"score":0.4193370044231415},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.3633531928062439},{"id":"https://openalex.org/C159467904","wikidata":"https://www.wikidata.org/wiki/Q2001702","display_name":"Chemical physics","level":1,"score":0.3591918349266052},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.2375042736530304},{"id":"https://openalex.org/C104015590","wikidata":"https://www.wikidata.org/wiki/Q1451740","display_name":"Neutron scattering","level":3,"score":0.21366560459136963},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.1980375349521637},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.18736985325813293},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.141747385263443},{"id":"https://openalex.org/C132841051","wikidata":"https://www.wikidata.org/wiki/Q4165337","display_name":"Small-angle neutron scattering","level":4,"score":0.12230011820793152},{"id":"https://openalex.org/C152568617","wikidata":"https://www.wikidata.org/wiki/Q2348","display_name":"Neutron","level":2,"score":0.10550683736801147},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1007/bfb0116464","doi":"https://doi.org/10.1007/bfb0116464","is_oa":false,"landing_page_url":"https://doi.org/10.1007/bfb0116464","pdf_url":null,"source":{"id":"https://openalex.org/S4306463955","display_name":"Steinkopff eBooks","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"ebook platform"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Progress in Colloid & Polymer Science","raw_type":"book-chapter"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":7,"referenced_works":["https://openalex.org/W1979025894","https://openalex.org/W2010308664","https://openalex.org/W2026308123","https://openalex.org/W2040904943","https://openalex.org/W2042597709","https://openalex.org/W2058889189","https://openalex.org/W2090235526"],"related_works":["https://openalex.org/W2023357936","https://openalex.org/W2039728529","https://openalex.org/W1985288691","https://openalex.org/W2006542405","https://openalex.org/W2075508109","https://openalex.org/W7051904565","https://openalex.org/W782223008","https://openalex.org/W2016838351","https://openalex.org/W2063767204","https://openalex.org/W1979025894"],"abstract_inverted_index":{"We":[0],"report":[1],"results":[2,68],"on":[3,62],"adsorbed":[4,26,81,125,145],"layers":[5],"of":[6,24,57,86,92,112,160,175,189,195,198],"polystyrene":[7],"(PS)-polyethylene":[8],"oxide":[9],"(PEO)":[10],"diblock":[11,28,59],"and":[12,101,180],"PEO-PS-PEO":[13,114],"triblock":[14,126,142],"copolymers":[15,29],"at":[16,30,88,95],"the":[17,25,31,32,54,80,84,89,113,117,124,173,193,196,201],"solid/liquid":[18],"interface.":[19],"The":[20,67,186],"volume":[21],"fraction":[22],"profiles":[23],"PS-PEO":[27,58],"quartz/toluene":[33],"interface":[34],"determined":[35],"by":[36,47,75,106,172],"neutron":[37],"reflectometry":[38],"are":[39,135],"consistent":[40],"with":[41,83,156,183],"a":[42,70,76,147,153,161],"parabolic":[43],"profile":[44],"as":[45],"predicted":[46],"theory.":[48],"Ellipsometry":[49],"was":[50],"used":[51],"to":[52,103,139],"investigate":[53],"adsorption":[55,98],"kinetics":[56],"copolymer":[60],"chains":[61,127,143,199],"SiO":[63],"2":[64],"from":[65],"toluene.":[66],"show":[69],"rapid":[71],"diffusion-controlled":[72],"process,":[73],"characterized":[74],"linear":[77],"increase":[78],"in":[79,136,146],"amount":[82],"square-root":[85],"time,":[87],"early":[90],"stages":[91],"adsorption,":[93],"while":[94],"late":[96],"times":[97],"is":[99,170],"slow":[100],"appears":[102],"be":[104],"governed":[105],"an":[107],"exponential":[108],"time":[109,187],"behavior.":[110],"Studies":[111],"copolymer,":[115],"using":[116],"surface-force":[118],"apparatus,":[119],"reveal":[120],"conformational":[121],"rearrangements":[122],"for":[123],"between":[128,200],"mica":[129],"surfaces.":[130,168,203],"When":[131],"two":[132,202],"such":[133],"surfaces":[134],"close":[137],"proximity":[138],"each":[140],"other,":[141],"originally":[144],"\u201cloop\u201d":[148],"conformation":[149,155],"may":[150],"open":[151],"into":[152],"\u201cbridge\u201d":[154],"both":[157],"PEO":[158],"blocks":[159],"given":[162],"chain":[163],"adsorbing":[164],"onto":[165],"opposing":[166],"mice":[167],"This":[169],"indicated":[171],"appearance":[174],"clearly":[176],"detectable":[177],"attractive":[178],"forces":[179,191],"their":[181],"evolution":[182,188],"compression-decompression":[184],"cycles.":[185],"these":[190],"reflects":[192],"dynamics":[194],"rearrangement":[197]},"counts_by_year":[{"year":2024,"cited_by_count":1}],"updated_date":"2026-10-10T09:11:00.788812","created_date":"2016-06-24T00:00:00"}